Numerical study of the oxidation process of dimethylsulfide in the marine atmosphere

A box model, involving simple heterogeneous reaction processes associated with the production of non-sea-salt sulfate (nss-SO ₄ ^2– ) particles, is used to investigate the oxidation processes of dimethylsulfide (DMS or CH₃SCH₃) in the marine atmosphere. The model is applied to chemical reactions in the atmospheric surface mixing layer, at intervals of 15 degrees latitude between 60° N and 60° S. Given that the addition reaction of the hydroxyl radical (OH) to the sulfur atom in the DMS molecule is faster at lower temperature than at higher temperature and that it is the predominant pathway for the production of methanesulfonic acid (MSA or CH₃SO₃H), the results can well explain both the increasing tendency of the molar ratio of MSA to nss-SO ₄ ^2– toward higher latitudes and the uniform distribution with latitude of sulfur dioxide (SO₂). The predicted production rate of MSA increases with increasing latitude due to the elevated rate constant of the addition reaction at lower temperature. Since latitudinal distributions of OH concentration and DMS reaction rate with OH are opposite, a uniform production rate of SO₂ is realized over the globe. The primary sink of DMS in unpolluted air is caused by the reaction with OH. Reaction of DMS with the nitrate radical (NO₃) also reduces DMS concentration but it is less important compared with that of OH. Concentrations of SO₂, MSA, and nss-SO ₄ ^2– are almost independent of NO _x concentration and radiation field. If dimethylsulfoxide (DMSO or CH₃S(O)CH₃) is produced by the addition reaction and further converted to sulfuric acid (H₂SO₄) in an aqueous solution of cloud droplets, the oxidation process of DMSO might be important for the production of aerosol particles containing nss-SO ₄ ^2– at high latitudes.     

多源异构日志综合分析技术研究与实践

多源异构日志分析技术是目前国内外网络安全领域的研究热点.首先,提出了一种包括聚焦分析、统计分析和因果关联分析在内的多源异构日志综合分析模型,引入重要度评价方法对日志信息进行聚焦分析,并通过实例加以说明;然后探讨了多源日志因果关联分析算法;最后利用网络实例数据,对所提出的综合分析模型和算法进行了验证.结果表明该模型和算法是可行的和有效的.     

Simple analytical Green's functions for ray perturbations in layered media

The total Green's function for two-point boundary-value problems can be related to the propagator for initial-value problems. A very simple expression for the Green's function is obtained when the unperturbed medium may be described by material with a constant gradient in quadratic slowness. The derivation requires a correct understanding of assumptions made in the propagator solution. Expressions are also obtained for Green's function in multilayered media.     

Exploring space–time paths in physical and social closeness spaces: a space–time GIS approach

Exploring the evolution of people’s social interactions along with their changing physical locations can help to achieve a better understanding of the processes that generate the relationships between physical distance and social interactions, which can benefit broad fields of study related to social networks. However, few studies have examined the evolving relationships between physical movements and social closeness evolution. This is partially related to the shortage of longitudinal data in both physical locations and social interactions and the lack of an exploratory analysis environment capable of effectively investigating such a process over space and time. With the increasing availability of sociospatiotemporal data in recent years, it is now feasible to examine the relationships between physical separation and social interactions at the individual level in a space–time context. This research was intended to offer a spatiotemporal exploratory analysis approach to address this challenge. The first step was to propose the concept of a social closeness space–time path, which is an extension of the space–time path concept in time geography, to represent evolving human relationships in a social closeness space. A space–time geographical information system (GIS) prototype was then designed to support the representation and analysis of space–time paths in both physical and social closeness spaces. Finally, the effectiveness of the proposed concept and design in gaining insight into the impact of physical migration on online social closeness was demonstrated through an empirical study. The contributions of this study include an extension of the time–geographic framework from physical space to social closeness space, the development of a multirepresentation approach in a GIS to integrate an individual’s space–time paths in both physical and social closeness spaces, and an exploratory analysis of the evolving relationships between physical separation and social closeness over time.     

Crack nucleation in saturated porous media

Crack nucleation has been the subject of important contributions in the last two last decades. However, it seems that few attention has been granted to the case of saturated porous media. This is the question addressed in the present paper which is devoted to nucleation in traction mode. From a physical point of view, nucleation is a sudden phenomenon, so that the material response is both adiabatic and undrained. In the spirit of the variational approach, the nucleated crack is viewed as the final state of a region of space in which the material undergoes a full damage process. In traction mode, the opening of a saturated crack in undrained condition induces a drop of fluid pressure. In case of low fluid compressibility, the presence of the fluid delays the brittle failure usually associated with nucleation, as long as the fluid pressure remains above the saturation vapor pressure. Nucleation is therefore possible only if a partial vaporization of the fluid takes place.     

基于非均质地层参数表征的颗粒流模型构建

非均质地层参数的获取与表征方法是浅层地质体改造的重要依据。基于非均质地层的地质建模,表征具有随机不确定性和模糊不确定性的土体表观参数和物理力学参数。利用 Weibull 分布统计描述局部地层信息,并应用Diamond-Square分形插值方法,结合差分盒子维计算非均质地层分形维数,进一步合理演算整体地层参数。采用PFC3D数值模拟软件,结合马尔科夫链蒙特卡洛方法采样数据,对非均质地层块石颗粒及土颗粒进行建模。通过非均质地层模拟结果,发现其破坏过程与应力应变曲线要比均质土体复杂得多,由于块石大颗粒的含量、分布特性对土样力学性质影响显著。本文建模方法有助于非均质地层参数表征研究。     

温庄尾矿库堆坝模型试验及坝体稳定性分析

以温庄尾矿库为工程背景,通过室内堆坝模型试验,获得到了在坝体堆积过程中尾矿颗粒在库内沉积分布特征、浸润线的变化规律等基础资料。在此基础上,以多孔介质有效应力理论为依据,建立了多孔介质流-固耦合数学模型,利用有限元软件ABAQUS对该库尾矿坝的应力场与渗流场进行了分析,获得了坝体内的应力场及孔隙压力的分布规律,研究成果可为尾矿库的设计、施工和安全生产提供技术支撑。