纳滤分离铝锂过程研究

本文探讨了纳滤分离Al~(3+)和Li~+的可行性,研究了含盐量和铝锂比对分离效率的影响,提出了从锂云母浸出液中分离回收锂的新方法。实验结果表明,纳滤膜对Al~(3+)和Li~+的截留率随含盐量的升高而降低,其中Li~+始终呈现负浓度梯度扩散的趋势,而Al~(3+)的截留率始终稳定在99%以上。当含盐量为45 g/L时,铝锂分离因子最高可达248.33,膜面相应Zeta电位的绝对值达到最大。随着溶液中铝锂比的变化,Al~(3+)和Li~+的截留率分别在不同铝锂比的条件下出现拐点,溶液的pH呈现先下降后上升最后下降的复杂趋势。本实验研究发现,DK膜能够在酸性环境下实现高效的铝锂分离和锂的浓缩,从而为锂云母浸出液中锂的提取提供新的思路。     

Post-earthquake economic resilience and recovery efficiency in the border areas of the Tibetan Plateau: A case study of areas affected by the Wenchuan Ms 8.0 Earthquake in Sichuan,China in 2008

Journal of Geographical Sciences - The border areas of the Tibetan Plateau and the neighboring mountainous areas have a high incidence of earthquakes with a magnitude greater than Ms 5.0, as well...     

Integrating spectral and non-spectral data to improve urban settlement mapping in a large Latin-American city

ABSTRACT

Information on urban settlements is crucial for sustainability planning and management. While remote sensing has been used to derive such information, its applicability can be compromised due to the complexity in the urban environment. In this study, we developed a remote sensing method to map land cover types in a large Latin-American city, which is well known for its mushrooming unplanned and informal settlements. After carefully considering the landscape complexity there, we designed a data fusion method combining multispectral imagery and non-spectral data for urban and land mapping. Specifically, we acquired a cloud-free Landsat-8 image and two non-spectral datasets, i.e., digital elevation models and road networks. Then, we implemented a set of experiments with different inputs to evaluate their merits in thematic mapping through a supervised protocol. We found that the map generated with the multispectral data alone had an overall accuracy of 73.3% but combining multispectral imagery and non-spectral data yielded a land cover map with 90.7% overall accuracy. Interestingly, the thermal infrared information helped substantially improve both the overall and categorical accuracies, particularly for the two urban classes. The two types of non-spectral data were critical in resolving several spectrally confused categories, thus considerably increasing the mapping accuracy. However, the panchromatic band with higher spatial resolution and its derived textural measurement only generated a marginal accuracy improvement. The novelties of our work are with the successful separation between the two major types of urban settlements in a complex environment using a carefully designed data fusion approach and the insight into the relative merits of the thermal infrared information and non-spectral data in helping resolve the issue of class ambiguity. These findings should be valuable in deriving accurate urban settlement information which can further advance the research on socio-ecological dynamics and urban sustainability.     

抗冻蛋白的研究及其在生物技术中的应用

抗冻蛋白能够与冰晶结合，降低冰点并抑制冰的重结晶，从而使生物体免于冰冻伤害。就不同类型的抗冻蛋白的结构、起源、功能和抗冻作用机制进行了全面的回顾，并对国内近年来抗冻蛋白在生物技术中的应用进行了综述。     

Thermal fronts and cross-frontal heat flux in the southern Huanghai Sea and the East China Sea

Synoptic features in/around thermal fronts and cross-frontal heat fluxes in the southern Huanghai./Yellow Sea and East China Sea （HES） were examined using the data collected from four airborne expendable bathythermograph surveys with horizontal approxmately 35 km and vertical 1 m（from the surface to 400 m deep） spacings. Since the fronts are strongly affected by HES current system, the synoptic thermal features in/around them represent the interaction of currents with surrounding water masses. These features can not be obtained from climatological data. The identified thermal features are listed as follows ： （ 1 ） multiple boundaries of cold water, asymmetric thermocline intrusion, locally-split front by homogeneous water of approxmately 18 ℃, and mergence of the front by the Taiwan Warm Current in/around summertime southern Cheju - Changjiang/Yangtze front and Tsushima front; （2） springtime frontal eddy-like feature around Tsushima front; （3） year-round cyclonic meandering and summertime temperature-inversion at the bottom of the surface mixed layer in Cheju - Tsushima front; and （4） multistructure of Kuroshio front. In the Kuroshio front the mean variance of vertical temperature gradient is an order of degree smaller than that in other HES fronts. The southern Cheju- Changjiang front and Cheju -Tsushima front are connected with each other in the summer with comparable cross-frontal temperature gradient. However, cross-frontal heat flux and lateral eddy diffusivity are stronger in the southern Cheju - Changjiang front. The cross-frontal heat exchange is the largest in the mixing zone between the modified Huanghai Sea bottom cold water and the Tsushima Warm Current, which is attributable to enhanced thermocline intrusions.     

NaCl 溶液闪蒸效率特性数值研究

盐水闪蒸技术广泛应用于海水淡化及海洋温差能发电,含盐质量分数、给盐液温度和闪蒸压力对闪蒸汽化率和热效率有很大影响。在质量分数为3.5%～20%、给盐液温度为30～95℃和闪蒸压力为1～30 kPa的范围内,对NaCl溶液闪蒸汽化率和热效率等闪蒸效率特性进行了定量计算研究,研究得到了盐水含盐质量分数、给盐液温度和闪蒸压力对闪蒸汽化率以及热效率影响的规律。结果表明,降低含盐质量分数,提高给盐液温度,降低闪蒸压力可提高闪蒸汽化率与热效率;含盐质量分数越高,造成的热损失越大,而提高给盐液温度会增大热损失。     

冷活性纤维素酶性质研究

对海洋嗜冷菌MB1所产冷活性纤维素酶的性质进行了研究。该酶最适反应温度为35℃,0℃时残余酶活约为20％,最适pH值为6．0,在pH5～7．5范围内酶活均较高。该酶对热敏感,50℃保温2h,残余酶活为15％;60℃时,酶完全失活。     

温度骤降对大黄鱼Larimichthys crocea鱼卵与仔鱼的影响

滨海电厂温排水停止排放以及季节更替、寒潮来袭等现象会引起海水温度降低,从而对鱼类等变温生物产生冷冲击效应。本研究通过模拟水温骤降情形,以孵化率、死亡率、畸形率等为指标,探讨了温度骤降对大黄鱼早期发育阶段(鱼卵和仔鱼)的冷冲击作用。研究发现,大黄鱼仔鱼(3日龄)对温度骤降的敏感性略高于鱼卵。在大黄鱼鱼卵和仔鱼的适温范围内,当水温由22 ℃骤降至19 ℃或16 ℃时,鱼卵的孵化率和死亡率无明显变化,而胚胎发育和仔鱼的生长发育均减缓,仔鱼的死亡率提高;水温超出适温范围,由22 ℃骤降至13 ℃或10 ℃时,对鱼卵和仔鱼造成致命的冷冲击伤害,48 h累积死亡率分别为84.6%~100%和72.1%~98.2%。由此推测:当水温骤降超出适温范围后,大黄鱼的早期发育阶段遭受致命的冷冲击伤害,从而影响种群补充和年龄结构。     

海岸波浪多次破碎波能耗散模型

在坡度很缓(接近或小于1∶100)的海岸,波浪在向海岸传播的过程中,可能经历多次破碎,而在两次波浪破碎之间将伴随着波浪恢复(波浪恢复到不破碎状态)。在现有海岸波高计算模型中,波浪破碎是通过波能耗散来模拟的,但所采用的波能耗散模型都不能自动考虑波浪出现多次破碎的过程,特别精确模拟这一过程中出现的波浪恢复。本文提出了解决这一问题的新的波能耗散模型,模型的建立是通过在Dally模型中重新建立稳定波能、饱和波高水深比和波能耗散系数,并引入了波浪恢复的判断条件实现的。该模型的波能耗散在波浪恢复区的值很小故能描述波浪恢复区的波浪运动。与实验结果的对比表明,新模型可以适合缓坡情况波浪多次破碎的波高模拟,而且对不同坡度的平坡和沙坝海岸(1∶100～1∶10)的破碎波模拟都可以给出与实验结果符合的结果,并且可以自动识别多次波浪破碎的存在和波浪恢复的发生。     

驯化水温及温升速率对三门湾三种虾蟹类热耐受性的影响

作者采用动态实验法与静态实验法相结合的方法,研究了三门湾脊尾白虾(Exopalaemon carinicauda)、口虾蛄(Oratosquilla oratoria)和日本(Charybdis japonica)在不同季节的基础水温即驯化水温(8~29℃)和温升速率(0.5~15.0℃/h)下的热耐受能力。结果表明,驯化水温和温升速率对各实验动物的热耐受性均有显著影响。实验动物的热耐受性与驯化水温总体上呈显著正相关,而温升速率对热耐受性的影响具有物种特异性,并受驯化水温制约;在不同驯化水温下,各实验动物的热耐受性随温升速率增大呈不同变化趋势。各实验动物的24 h高起始致死温度受驯化水温的影响显著,随着驯化水温从8℃升高到29℃,脊尾白虾、日本和口虾蛄的24hUILT50分别从24.2、34.6、24.9℃显著增大到35.3、37.4和34.4℃。结合3种实验动物的最大临界温度分析,它们的热耐受能力依次为:日本脊尾白虾口虾蛄。研究结果可为探究三门湾水域潜在的热污染状况及其生态环境效应提供科学依据。