Lead, zinc, and antimony contamination of the Rio Chilco-Rio Tupiza drainage system, Southern Bolivia

An intense, but localized rainfall event in February 2003, led to the severe erosion and failure of a tailings disposal impoundment at the Abarόa Antimony Mine in southern Bolivia. The failure released approximately 5,500 m³ of contaminated tailings into the Rio Chilco-Rio Tupiza drainage system. The impacts of the event on sediment quality are examined and compared to contamination resulting from historic mining operations in the headwaters of the basin. Of primary concern are contaminated floodplain soils located along downstream reaches of the Rio Tupiza which were found to contain lead (Pb), zinc (Zn), and antimony (Sb) concentrations that locally exceed Canadian, German, and Dutch guidelines for agricultural use. Spatial patterns in sediment-borne trace metal concentrations, combined with Pb isotopic data, indicate that Pb, Zn, and Sb are derived from three tributary basins draining the Abarόa, Chilcobija, and Tatasi-Portugalete mining districts. Downstream of each tributary, geographical patterns in trace metal concentrations reflect local geomorphic changes throughout the drainage system. Trace metal concentrations within the Rio Chilco decrease rapidly downstream as a result of dilution by uncontaminated sediments and storage of metal enriched particles (e.g., sulfide minerals) in the channel bed as a result of ongoing aggradation. Storage in the floodplains is limited. These processes significantly reduced the dispersal and, thus, the relative environmental affects of tailings eroded from the Abarόa Mine during the 2003 flood. In contrast, storage of Pb, Zn, and Sb in floodplains along the Rio Tupiza is significant, the majority of which is derived from historic mining operations, particularly mining within the Tatasi-Portugalete district.     

Vertical distribution and water solubility of phosphorus and heavy metals in sediments of the St. Lucie Estuary, South Florida, USA

Accumulation and distribution of heavy metals and phosphorus in sediments impact water quality. There has been an increasing concern regarding fish health in the St. Lucie Estuary, which is related to increased inputs of nutrients and metals in recent decades. To investigate vertical changes of contaminants (P, Cd, Cr, Co, Cu, Ni, Pb, Zn, and Mn) in sediments of the St. Lucie Estuary in South Florida, 117 layer samples from six of the 210 to 420 cm depth cores were analyzed for their total and water-soluble P and heavy metals, clay, total Fe, Al, K, Ca, Mg, Na, and pH. Principal component analysis (PCA) was used in two sets of analytical data (total and water-soluble contaminant concentrations) to document changes of contaminants in each core of sediments. The PCA of total contaminants and minerals resulted in two factors (principal components). The first and second factors accounted for 61.7 and 17.2 % of the total variation in all variables, and contrast indicators associated with contaminants of P, Cd, Co, Cr, Ni, Pb, Zn, and Mn and accumulation of Fe and Al oxides, respectively. The first factor could be used for overall assessment of P and heavy metal contamination, and was higher in the upper 45–90 cm than the lower depths of each core. The concentrations of P and heavy metals in the surface layers of sediments significantly increased, as compared with those in the sediments deeper than 45–90 cm. The PCA of water-soluble contaminants developed two factors. The second factor (Cu–P) was higher in the upper than the lower depths of the sediment, whereas the highest score of the first factor (Cd–Co–Cr–Ni–Pb–Zn–Mn) occurred below 100 cm. The water-soluble Cu and P concentrations were mainly dependent on their total concentrations in the sediments, whereas the water-soluble Cd, Co, Cr, Ni, Pb, Zn, and Mn concentrations were mainly controlled by pH.     

模糊理论在公路边坡稳定性分析中的应用

边坡工程是一个复杂的系统工程。边坡的稳定与否直接关系到其防护工作的程度。因此,如何有效、合理地判断边坡的稳定性对整个工程的经济与社会效益极为重要。影响边坡稳定的因素众多,判断其稳定与否应考虑各因素的综合效果。论文运用模糊理论中的多因素综合评判模型对某高速公路边坡的稳定性进行研究。通过全面考虑影响因素,建立相应的评判因素集及单因素评判矩阵,运用专家评判法和判断矩阵法确定出各因素的权重。最后通过多层次模糊评判得到该边坡的稳定性评判结果。研究证明,该法在边坡稳定性分析评判中是切实可行的。     

Dissolved Trace Metal–Organic Complexes in the Lot–Garonne River System Determined Using the C18 Sep-Pak System

An 11-month observation of dissolved and particulate organic matter, chlorophyll a(Chl a), C18 Sep-Pak extractable hydrophobic dissolved organic matter (hDOM) fraction and associated dissolved trace metals (Cd, Cu, V, Co, Ni, Mo, U) was performed in the Lot–Garonne River system. This system includes the Riou Mort, the Lot River and the downstream reaches of the Garonne River and represents the fluvial transport path of trace metals between the major point source of polymetallic pollution, located in the Riou Mort watershed and the Gironde estuary. Spatial and temporal variations of dissolved and particulate organic carbon and Chl areflect the presence of different types of organic matter and their relation with the hDOM fraction. Maximum Chl a/POC ratios (up to 0.03), indicate intense phytoplankton production from March to May. In the Lot River (Temple), DOC and POC concentrations were clearly higher and mean Chl a concentration (2.8 mg g⁻¹) was about three times higher than those of the other sites. High Chl a/POC ratios suggest high phytoplankton activity with maxima in spring and late summer. In the Riou Mort River, very high POC concentrations of up to 40 (mean: 20) occurred, whereas Chl a concentrations were relatively low indicating low phytoplankton activity. High, strongly variable DOC and POC concentrations suggest important natural (Carboniferous soils, forests) or anthropogenic (e.g., former coal mines, waste areas, agriculture, sewage) carbon sources within the small Riou Mort watershed. Despite high DOC concentrations in the Riou Mort River, hDOM metal fractions were generally lower than those at the other sites. The general order of decreasing binding strength between metals and the organic hydrophobic phase (Cu, U > Co, Ni > V, Mo > Cd) at all four sites was in good agreement with the Irving–William series of transition element affinity towards organic ligands. Accordingly, the role of the hydrophobic phase in dissolved Cd transport appeared to be negligible, whereas the hDOM–Cu fraction strongly contributed to dissolved Cu transport.     

我国水资源承载力研究现状及展望

概要说明了我国水资源承载力的研究现状,阐述了水资源承载力的概念、内涵及影响因素,探讨了目前几种常用的水资源承载力评价方法,并对当前研究中存在的问题进行了初步分析,进而提出了我国水资源承载力的研究趋势。     

地震地质灾害空间预警评估定量化方法研究初探

建立“发育度”、“潜势度”、“危险度”、“危害度”等概念来描述地震地质灾害各影响因子、要素及可能的灾害危害程度,进而建立构成地震地质灾害层次分析的概念体系及地震地质灾害空间预警评估模型,将定性评估转化为定量评估进行初步研究。     

MODIS数据在广西生态环境监测及评价中的应用方法

利用MODIS数据广西遥感影像,用监督分类法做出了地物覆盖分类图,用主成分分析法做出了土壤侵蚀强度图和生态环境质量综合评价指数图。     

区域大气环境质量灰关联评价方法探讨

针对区域中大气环境质量的特点，采用对数主成分分析方法获得各环境指标的权重及各监测点的横向排名，再用适宜的灰度关联方法进行了评价。整个过程在MATLAB6．5中实现，计算简便易行，与传统的综合指数法相比较，其评价结果更符合客观实际。     

基于点重要度的地形LOD简化算法及精度

在分析、讨论目前关于3维地形模型简化与误差控制方法的基础上,提出了一种基于点重要度进行连续LOD模型简化的算法.并以5种典型地貌的实验数据作为运行实例,给出了点重要度与地貌类型之间的精度关系.这为今后连续LOD模型的合理建立提供了一种新思路和方法,也为模型的简化提供了科学依据.     

香港DTM快速建立的研究

本文论述了建立1：5000香港DTM的基本过程，总结了在DTM生产实践中的技术和管理上所取得的一些经验，对生产中各环节的实际问题提出一些建议，对提高所建立DTM的精度与可用性及提高工作效率，具有一定的意义，为以后各种比例尺的DTM生产提供参考。