Mobility of heavy metals as a function of pH of samples from an overbank sediment profile contaminated by mining activities

Parts of the flood plains north of the Harz Mountains are contaminated with heavy metals, such as Pb, Cu, Zn and Cd derived from mining, which has been carried out in the Harz Mts. since the Middle Ages. It is important to know the mobility of the heavy metals in these overbank sediments in order to estimate the danger to the environment arising from this source. This paper deals with the effect of pH on heavy-metal mobility, using a constant-pH method. The investigations were carried out on an overbank sediment profile near Salzgitter Bad, north of the Harz Mts. The mobility of the heavy metals in the overbank sediment profile is described as a function of pH and depth. Besides the mobile heavy-metal fraction at a certain pH, the buffering capacity of the sediment at this pH must be taken into consideration. The different layers of the overbank sediment profile show distinct differences in buffering capacity and a natural pH harrier could be identified in the upper part of the profile. Therefore, to avoid increasing heavy-metal mobility the natural layering of the overbank sediment profile should not be disturbed. Two different kinds of desorption experiments at constant pH are also discussed, as well as the conversion of the heavy-metal species in the ore minerals into the species in the sediment.     

Heavy metal retention in secondary precipitates from a mine rock dump and underlying soil, Dalarna, Sweden

This study investigates the retention of heavy metals in secondary precipitates from a sulfidic mine rock dump and underlying podzolic soils by means of mineralogical and chemical extraction methods. The rock dump, which is at least 50 years old, consists of a 5–10-cm-thick leached zone and an underlying 110–115-cm-thick accumulation zone. Optical microscopy and electron microprobe analyses confirm that pyrrhotite weathering has proceeded much further in the leached horizon relative to the accumulation horizon. The weathering of sulfides in the leached zone has resulted in the migration of most heavy metals to the accumulation zone or underlying soils, where they are retained in more stable phases such as secondary ferric minerals, including goethite and jarosite. Some metals are temporarily retained in hydrated ferrous sulfates (e.g., melanterite, rozenite). Received: 28 October 1996 · Accepted: 24 February 1997     

Electrokinetic remediation of metal contaminated glacial tills

This paper presents the results of an experimental investigation which studied the feasibility of using the electrokinetic process to remediate contaminated clays of glacial origin, otherwise known as glacial tills. An overview of the electrokinetic phenomena, as well as previously performed laboratory and field investigations, is first presented. The methodology of the electrokinetic experiments which were conducted to investigate the removal of metals from a glacial till is then described. A total of 16 experiments were conducted using glacial till samples obtained from a project site near Chicago. Sodium and calcium were used as the surrogate cationic metallic contaminants. These experiments demonstrated that ion transport during the electrokinetic process occurs due to both electro-osmosis and electromigration, but that due to electromigration is significantly higher than that due to electro-osmosis. Unlike other clays such as kaolinite, the glacial till used for this investigation possessed high buffering capacity because of its high carbonate content which prevented the acid front migration from the anode to the cathode during the electrokinetic process. The ion removal efficiency of the electrokinetic process was found to increase when: (1) the voltage gradient applied to the soil was increased, (2) the initial concentration of the contaminants was increased, and (3) the duration of the treatment process was increased. The ion removal efficiency was also greater for smaller ions which possess less ionic charge and when the ions existed independently in the soil as compared to when they coexisted. This investigation suggests that the electrokinetic process has significant potential for remediating glacial tills contaminated with metals. However, the properties of Na and Ca are not representative of contaminants, such as heavy metals, so further investigations are needed.     

云宵县5月暴雨客观预报模型

采用文献[1]提出的技术模型，研制了云宵县5月暴雨预报方法，建立了4个因子结构简单而天气学意义明了的客观预报模型。经2000～2003年试用，这种基于场量因子的预报模型，未漏报，严格评定的准确率为67％，明显优于主观预报。     

磁学方法在环境污染研究中的应用

环境磁学方法问世20多年来，因其快速、灵敏、经济、无破坏性和信息量大的特点，在环境研究中得到广泛的应用。磁学方法可用于传统的污染分析技术（化学）之前的预研究，而后者一般耗费大量人力、物力和时间；它也可以作为环境污染评估的代用指标。近年来，随着世界环境污染问题的日益严重和倍受关注，磁学方法被广泛地应用于环境污染研究。欧洲环境磁学专家在重建污染历史、监测现代环境污染、追踪与分离污染源等方面，开展了大量的工作，并积累了一定的经验。介绍了磁学方法用于污染研究的显著特点、主要用途、野外工作方法以及相关仪器；展示了在大气、土壤、潮滩、河流、湖泊以及海洋等不同环境系统中，利用磁手段研究污染的成果和最新进展；对 于一些难点、热点问题，如磁性机理的研究、多源污染的分离、强烈多变的人类活动对获取有意义磁讯号的影响等，做了相应的分析和总结。     

2003年7月上旬张家界特大暴雨山洪分析

对造成 2 0 0 3年 7月 8～ 1 0日张家界特大暴雨山洪的主要影响系统、物理量诊断场资料、多普勒雷达回波资料及自动气象站要素进行了分析 ,并重点分析了张家界特定的地形条件对降水的增幅作用及暴雨的夜发特征 ,为湘西北的暴雨山洪预报提供了一些有益的启示。     

一次强暴雨形成的动力机制

分析了1998年7月武汉强暴雨的天气演变特征，并从理论上探讨了强暴雨形成的动力机制。结果表明：低空急流先于暴雨生成，暴雨最强时低空急流也最强；高空急流入口区右侧及低空急流左侧非热成风梯度的存在，使得中尺度不稳定波的波振幅出现空间不稳定现象，高空急流右侧不稳定波的波振幅和低空急流左侧不稳定波的波振幅向暴雨区增加，暴雨区恰为这两支波叠加后振幅最大的区域，高低空急流耦合下的非热成风、中尺度对流-对称不稳定可能是这类强暴雨产生的动力原因之一。     

98.7湖北特大暴雨的天气分析与降水模拟

1998年7月20～23日，湖北省南部发生了一次持续性特大暴雨过程，采用双向嵌套的非静力中尺度数值模式(MM5)对这次强暴雨过程进行初步模拟试验。结果表明，粗、细网格均能较好地模拟出雨带的走向和变动以及武汉地区的暴雨中心，尤其是嵌套域(细网格)模拟的降水强度比粗网格有明显改进，和实际观测结果更接近；另外，对引发这次特大暴雨的对流层低层的中尺度系统也能够很好地模拟出来。     

2002年6月13日重庆区域大暴雨分析

通过对重庆西部“6 1 3”区域大暴雨的分析 ,发现此次天气过程是一次典型的高原涡与西南涡耦合 ,结合地面弱冷空气条件下产生的 ,同时对ECMWF和T2 1 3数值预报产品进行了简要的分析 ,发现ECMWF和T2 1 3的形势预报能力都比较好 ,但T2 1 3的部分物理量要素和降水量预报能力还有待提高。     

1997年7月19日影响北京地区的暴雨个例分析

针对在实际业务预报中经常遇到的北京地区降水的两种特殊性(明显天气系统移来时，北京地区降水明显比周围偏多或偏少)，选取一个实例利用中尺度非静力模式(MM5)对降水比周围偏多情况进行了高分辨率数值模拟和敏感性试验。结果表明，该模式比较成功地模拟了此次天气过程及其相关的中尺度系统的发生发展，凝结潜热对天气过程的发生发展有重要作用，而地形在天气过程中也起着主要作用，低层潜在不稳定能量的储备和输送是暴雨发生不可缺少的条件。