燃烧加热污染空气对超燃冲压发动机性能影响研究

针对燃烧加热地面试验设备存在的工质污染问题,采用数值模拟方法研究了燃烧加热污染空气对氢燃料超燃冲压发动机性能的影响。以飞行马赫数Ma=6.5,当量油气比ER=0.6为计算基准状态,分别对纯净空气和污染空气来流下氢燃料超燃冲压发动机的整机流场和性能进行了对比计算分析。燃烧化学反应模拟采用了改进的H₂/O₂七组分八方程模型,湍流模型为标准的 k-ε模型,并采用直连式燃烧室试验数据进行了数值方法的验证。研究结果表明:(1)相对于纯净空气来流,污染空气来流下的超燃冲压发动机推力和比冲均有所下降。(2)采用酒精燃烧加热器的前提下,来流参数匹配静温、静压、马赫数时,发动机性能与纯净空气来流下的结果最为接近,而匹配总温、总压、马赫数时相差最大。(3)来流参数匹配总焓、静压、马赫数的前提下,采用氢燃烧加热器时发动机性能与纯净空气来流下的结果最为接近,而采用甲烷燃烧加热器时相差最大。      

东风带扰动影响西太平洋副热带高压短期东西向移动的热力强迫分析

利用NCEP/NCAR 1 000～10 hPa 2.5 °×2.5 °日平均再分析资料,分析2003年6月22—25日热带对流层上空东风带扰动影响西太平洋副热带高压（简称西太副高,下同）短期东西进退的热力强迫过程,并探讨了相应机制。结果表明:东风带扰动附近非绝热效应分布和强度的变化影响着西太副高东西向的运动;西太副高短期东西向移动有趋“冷”的趋势,即西太副高向非绝热加热减弱或者非绝热冷却增强方向移动;在西太副高突然东退前后,东风带扰动东、西侧的非绝热加热效应出现明显的变化,主要体现为东风带扰动东侧非绝热冷却效应增强和东风带扰动西侧非绝热冷却效应减弱东退的特征,而且在对流层300 hPa高度附近表现最为明显;在非绝热加热效应影响因子中,垂直输送项最为重要,其次为局地变化项,水平平流效应最不显著,因此,垂直输送作用和局地变化作用引起的非绝热效应的变化是影响西太副高突然东退的主要原因。      

北京市大兴区大气降尘环境磁学特征及其环境意义

应用环境磁学方法对北京市大兴区大气降尘环境磁学特征进行了系统研究,并通过与北京市朝阳区、兰州市大气降尘环境磁学特征的对比,对环境磁学在污染物来源解析及扩散条件研究中的应用机理进行了探讨。结果表明,大兴区大气降尘磁性矿物含量明显高于本区表土,人为源影响显著;降尘样品磁学特征主要受磁铁矿控制,并含有一定数量的磁赤铁矿,磁性矿物为准单畴和多畴颗粒;大兴区降尘样品的磁性矿物含量明显低于朝阳区,且样品颗粒相对较细,表明人口密度、车流量、城市发达度对大气污染程度存在显著影响;大兴区与兰州市大气降尘磁性矿物含量的季节变化差异表明,燃煤取暖对北京大气质量的影响显著减弱,燃煤锅炉改造是大气污染防治的重要措施之一。气象因素对大气颗粒物浓度变化有重要影响,降水、低气压和高风速利于大气颗粒物的清除和扩散,低气温对大气颗粒物污染的负面影响显著。     

Elements’ Geochemical Characteristics of PM10 and PM2.5 in Beijing During Winter and Spring

From 2012 to 2013, heavy haze frequently hit Beijing in spring and winter. The fine atmospheric particulates can be inhaled by people, and remain in the respiratory tract and lung for quite a long time. The heavy metal elements in the particles are harmful, and even carcinogenic to human bodies. Therefore, it is necessary to master the geochemical characteristics and the temporal and spatial distribution of the heavy metal elements in atmospheric particles. The atmospheric particulates (TSP/PM₁₀/PM_2.5) were collected by using TH1500C intelligent medium volume (80~120 L/min) air samplers in the five functional areas and suburbs of Beijing, respectively in January 2013 (heating period) and April 2013 (non-heating period). The five functional areas were: building materials factory area, residential area, education area, business area and recreation area, each functional area having three sampling sites, and five in suburbs. The sampling height was 1.5 m above the ground and the distance of the sampling sites to roads exceeded 50 m so as to avoid excessive impact of vehicle exhaust emissions. These samples were analyzed by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS), Inductively Coupled Plasma Optical Emission Spectrometer(ICP-OES)and Atomic Fluorescence Spectrometer (AFS), by which 21 elements including Al, Fe, Mn, As, Hg, Cd, Cr were tested. Based on the comparisons of the concentration and element content variation of atmospheric particulates of these functional areas in and after the heating period, the spatial distribution of atmospheric particulates and the influence of coal combustion on the concentration and composition of atmospheric particulates were revealed. The elements sources of atmospheric particulates were also discussed by computing the enrichment factor of the elements, providing a scientific basis for the air contaminant treatment in Beijing. The results showed that the total concentration of the 21 elements of PM₁₀ and PM_2.5 in the functional areas of Beijing in winter was higher than that in spring, the most marked among them being the business area. In winter, the concentration of pollution elements in the building materials factory area and the business area in Beijing was extremely high, and the residential area, education area, recreation area and suburbs where people live were much better, among which the education area was the best. The concentration change of particulates in suburbs was quite smaller in winter and spring than that of the urban area. It also showed that the concentrations of Cd, Cr, As and Hg in PM₁₀ increased by 233%,306%,298%,141%,respectively and the increase in PM_2.5 was 442%、309%、310%、256%, respectively. These abovementioned elements show a tendency to accumulate mainly in PM_2.5 whose concentrations in winter were significantly higher than those in spring. It indicates that coal heating during winter makes great contributions to the polluting elements in atmosphere and the main polluting particulates are Cd, As and Hg.     

喜马拉雅造山带南北向裂谷的冷缩成因模型

长期以来,学者们普遍认为垂直于喜马拉雅造山带的南北向裂谷是东西向伸展的构造形迹。现代GPS观测数据却显示,喜马拉雅造山带东西位移(分)量很小,甚至为零。综合前人资料,喜马拉雅造山过程可划分为热造山(25~13Ma)及造山后(13Ma)冷却两个时期,热造山期具有受热膨胀,物质向外运移的特点,高喜马拉雅热隆挤出并触发各主要断裂(MCT、STD、GCT)活动,印度板块向北汇聚速率下降。造山后则表现为冷却收缩,前期构造-热活动停止或减弱,印度板块向北汇聚加速。研究认为,南北向裂谷与高喜马拉雅等冷却过程的东西向收缩。且被局限于东、西两个构造结之间有关。并据此建立了裂谷的冷缩成因模型,模型估值与地质事实很吻合。     

电离层人工调制激发的VLF波在磁层的传播特性及应用研究

电离层人工调制可以激发甚低频（VLF）波,其中向上传播进入磁层的VLF波,不但能够用来研究磁层中的各种物理现象,且具有人工沉降高能粒子,消除辐射带等实际用途.本文使用射线追踪方法,模拟电离层调制激发的VLF波在磁层的传播路径,分析激发纬度和调制频率对传播路径和传播特性的影响;并基于低频波的色散方程和波粒共振条件,分析VLF波传播路径上与磁层高能粒子的最低共振能及其分布.研究表明,VLF波通过在磁层来回反射向更高的L-shell传播,最终稳定在某一L-shell附近.以较低的调制频率或者从较高的纬度激发的VLF波能够传播到更高的L-shell,但是,当激发纬度过高时,低频波也可能不发生磁层反射而直接进入电离层和大气层.低频波在磁层的传播过程中,在较高的纬度或者较低的L-shell能够与较高能量的电子发生共振相互作用,在较高的L-shell并且低纬地区,能够与较低能量的电子发生共振相互作用.共振谐数越高,能发生波粒共振的电子能量越高.     

天然气水合物加热开采机理及数学模型

在目前已有的主要水合物开采方法研究的基础上,进一步研究了天然气水合物加热开采法的机理。研究认为,水合物是加热分解、热传导和含化学分解的液、气两相渗流流动,它们之间既相互独立,又相互联系。并将水合物区划分为分解区和未分解区,将分解区前缘作为可移动的分界面,分区建立了加热分解热传导数学模型及含分解化学反应的液、气两相渗流流...     

Research on thermal shock resistance of mullite-bauxite-silicon carbide castable refractory

Effects of different silicon carbide contents on thermal shock resistance properties of mullite-bauxite castable refractory were analyzed respectively by taking the mullite,bauxite as main raw materials and taking calcium aluminate cement as a binding system.After 24 h curing in mould and another 24 h curing at 110℃ after demoulding,the samples were heated at 1000,1300 and 1500℃for 3 h in air,respectively.The bulk density,thermal expansion coefficient and thermal shock resistance were examined.The results showed that there was a great effect of content of SiC on bulk density,thermal expansion coefficient and thermal shock resistance of mullite-bauxite castable.Under the experimental conditions,the castable performed the best thermal shock resistance when w(SiC)=5%-10%.     

Relationship Between the Western Pacific Subtropical High and the Subtropical East Asian Diabatic Heating During South China Heavy Rains in June 2005

Based on the daily NCEP/NCAR reanalysis data, the position variation of the western Pacific subtropical high (WPSH) in June 2005 and its relation to the diabatic heating in the subtropical East Asia are analyzed using the complete vertical vorticity equation. The results show that the position variation of the WPSH is indeed associated with the diabatic heating in the subtropical East Asian areas. In comparison with June climatology, stronger heating on the north side of the WPSH and relatively weak ITCZ (intertropical convergence zone) convection on the south side of the WPSH occurred in June 2005. Along with the northward movement of the WPSH, the convective latent heating extended northward from the south side of the WPSH. The heating to the west of the WPSH was generally greater than that inside the WPSH, and each significant enhancement of the heating field corresponded to a subsequent westward extension of the WPSH. In the mid troposphere, the vertical variation of heating on the north of the WPSH was greater than the climatology, which is unfavorable for the northward movement of the WPSH. On the other hand, the vertical variation of heating south of the WPSH was largely smaller than the climatology, which is favorable for the anomalous increase of anticyclonic vorticity, leading to the southward retreat of the WPSH. Before the westward extension of the WPSH in late June 2005, the vertical variation of heating rates to (in) the west (east) of the WPSH was largely higher (lower) than the climatology, which is in favor of the increase of anticyclonic (cyclonic) vorticity to (in) the west (east) of the WPSH, inducing the subsequent westward extension of the WPSH. Similar features appeared in the lower troposphere. In a word, the heating on the north-south, east-west of the WPSH worked together, resulting in the WPSH extending more southward and westward in June 2005, which is favorable to the maintenance of the rainbelt in South China.     

Application of organic petrology and geochemistry to coal waste studies

Coal wastes produced during mining activities are commonly deposited in nearby dumps. These wastes mostly composed of minerals and variable amounts (usually 20-30%) of organic matter start to weather immediately after deposition. Oxidation of the organic matter can lead to self heating and self combustion as a result of organic and mineral matter transformations. The degree of alteration depends on the properties of the wastes, i.e., the maceral and microlithotype composition of the organic matter and its rank.Alteration of wastes also depends on the heating history, i.e., the rate of heating, final heating temperature, duration of heating, and the degree of air access. Although air is probably necessary to initiate and drive the heating processes, these usually take place under relatively oxygen depleted conditions. With slow heating, color of organic matter particles changes, irregular cracks and oxidation rims develop around edges and cracks, and bitumen is expelled. As a result, massive and detritic isotropic and strongly altered organic matter forms. On the other hand, higher heating rates cause the formation of devolatilization pores, oxidation rims around these pores and along cracks, vitrinite-bands-mantling particles, and bitumen expulsions.Organic compounds generated from the wastes include n-alkanes, iso-alkanes, alkylcyclohexanes, acyclic isoprenoids, mainly pristane, phytane and, in some cases, farnesane, sesquiterpanes, tri- and tetracyclic diterpanes, tri- and pentacyclic triterpanes, and steranes, polycyclic aromatic hydrocarbons (mostly with two- to five rings, rarely six rings), and phenols. The compounds formed change during the heating history. The fact that phenols are found in dumps where heating has not yet been completed, but are absent in those where heating ceased previously suggests the presence of water washing. The organic compounds formed may migrate within the dumps. However, when they migrate out of the dumps, they become a hazard to environment.This paper is a review on transformations of organic matter (both maceral composition and reflectance and chemical composition) in coal wastes deposited in coal waste dumps. Immediately after deposition the wastes are exposed to weathering conditions and sometimes undergo self heating processes.