河西走廊花海古湖泊全新世白云石的发现及其环境意义

通过对河西走廊花海古湖泊沉积物的X衍射分析发现,全新世期间有明显的白云石沉积.岩性、沉积过程、石膏以及Fe3+含量的变化表明,花海湖全新世白云石沉积环境以还原环境为主,即还原环境利于白云石的形成,为白云石的成因研究提供了新的证据.白云石作为碳酸盐矿物,可以反映湖水盐度,但并非直接指示了湖水的咸化.随着湖水盐度的进一步增加,在硫酸盐型湖泊中,白云石含量随盐度的增加而相应减少,表明利用白云石分析湖水盐度时需要结合其他矿物进行分析.结合石膏含量的变化,花海湖全新世时期白云石含量的变化可以揭示该区域湖水盐度的变化.在10.478.87 cal ka B.P.早全新世时期,湖水的盐度较高,气候由干向湿转变;8.87 cal ka B.P.时期,有大量石膏沉积,显示了湖水盐度的进一步升高,气候干旱;随后湖水相对淡化,气候湿润;5.50 cal ka B.P.至今,沉积出现间断,气候逐渐干旱.     

The role of gypsum and/or dolomite dissolution in tufa precipitation: lessons from the hydrochemistry of a carbonate–sulphate karst system

The precipitation of freshwater carbonates (tufa) along karstic rivers is enhanced by degassing of carbon dioxide (CO₂) downstream of karstic springs. However, in most karstic springs CO₂ degassing is not enough to force the precipitation of tufa sediments. Little is known about the role of dissolution of gypsum or dolomite in the hydrochemistry of these systems and how this affects the formation of tufa deposits. Here we present a monitoring study conducted over a year in Trabaque River (Spain). The river has typical karst hydrological dynamics with water sinking upstream and re‐emerging downstream of the canyon. Mixing of calcium–magnesium bicarbonate and calcium sulphate waters downstream of the sink enhances the dissolution of carbonates and potentially plays a positive role in the formation of tufa sediments. However, due to the common‐ion effect, dissolution of dolomite and/or gypsum causes precipitation of underground calcite cements as part of the incongruent dissolution of dolomite/dedolomitization process, which limits the precipitation of tufa sediments. Current precipitation of tufa is scant compared to previous Holocene tufa deposits, which likely precipitated from solutions with higher saturation indexes of calcite (SIcc values) than nowadays. Limited incongruent dissolution of dolomite/dedolomitization favours higher SIcc values. This circumstance occurs when waters with relatively high supersaturation of dolomite and low SO₄^2? composition sink in the upper sector of the canyon. In such a scenario, the process of mixing waters enhances the exclusive dissolution of limestones, preventing the precipitation of calcite within the aquifer and favouring the increase of SIcc values downstream of the springs. Such conditions were recorded during periods of high water level of the aquifers and during floods. This research shows that the common‐ion effect caused by the dissolution of gypsum and/or dolomite rocks can limit [or favour] the precipitation of tufa sediments depending on the occurrence [or not] of incongruent dissolution of dolomite/dedolomitization. Copyright © 2016 John Wiley & Sons, Ltd.     

浅层地震反射波法在石膏矿采空区调查中的应用

随着人们对地下矿产资源的过度开采,地下空间形成了较大区域的采空区。采空区出现后,其上覆岩层平衡条件被破坏,使得上覆岩层产生移动变形,直到破坏、塌落,导致地表建筑物变形、破坏,地表大面积下沉、凹陷,形成大面积的采空塌陷区。采空区的存在使矿山生产面临很大的安全问题。近年来,矿山采空区的危害越来越受到人们的重视,在采空区调查中,各种地球物理方法起到了重要的作用,国内外以往探测实践表明,较为常用的物探测量方法有:高密度电阻率法、瞬变电磁法、CSAMT法、浅层地震反射波法、放射性土壤氡气测量法等,但每种物探方法的应用均具有一定的条件,需要根据岩石物性特征、场地条件、探测深度、环境影响等因素选择合适的地球物理方法。地震反射波法具有抗干扰能力强、分辨率较高等优势,被较多应用于矿山采空区的调查中。该文以临沂市兰陵县某石膏矿采空区为例,采用浅层地震反射波法对该石膏矿采空区进行调查,通过对获得的地震剖面资料进行处理和解释,取得了较好的探测效果,其技术方法可为同类采空区的探测提供借鉴和指导。     

喀喇昆仑林济塘盆地铅锌矿床容矿地层的海相沉积环境：源于侏罗系灰岩微量元素和石膏硫同位素的约束

近年来,喀喇昆仑地区林济塘中生代沉积盆地内发现了火烧云超大型铅锌矿等众多铅锌矿床,以往对该地区的沉积环境以及其成矿相关性缺乏详细探讨。本文开展了林济塘盆地内侏罗系灰岩微量元素和石膏硫同位素分析,以揭示铅锌矿床容矿地层的沉积环境及其与成矿的相关性。研究发现,盆地内侏罗系灰岩中Ba、V、Ni、Cu、Co、Th、Co、Sr元素及比值特征显示其形成于海相,石膏硫同位素δ34S 值为14.89‰~20.63‰,与同期海水相一致。表明该盆地内铅锌矿床的容矿地层形成于干热气候条件下的海相沉积氧化环境。     

平邑盆地古近纪官庄群沉积建造与膏岩富集规律

平邑盆地是蒙山断裂多期次活动的产物,盆地内沉积了厚约1700多米的新生代古近纪官庄群杂色-红色碎屑岩建造。将官庄群沉积建造、剖面类型,结合含膏岩系的沉积特点,可以划分为3个不同级别的沉积韵律,它们分别反映出含膏岩系在时间和空间上的变化趋势。蒙山断裂及盆地内次级断裂的阶段性活动,使盆地表现为升降运动,下降时成矿物质聚集、保存,相对稳定期是膏岩形成的有利期。     

钻孔充填压浆法在采空区治理中的应用——以湖南省邵东某石膏矿采空区为例

矿山开采形成的采空区往往会给地表建筑物带来破坏，对采空区的治理方法也有多种，针对湖南某石膏矿采空区的分布与埋藏特征及其工程地质条件，采用了钻孔充填压浆法进行了治理。实践证明钻孔充填压浆法对采空区的治理具有成本低，设备简单，技术可靠，效果明显，有进一步推广的意义。     

Correlating specific conductivity with total hardness in gypsum karst waters

Modern digital conductivity meters are readily portable, robust, cheap, and give precisely reproducible values of specific electrical conductivity (SpC, in µS cm^?1). Here we investigate the accuracy of their estimates of the amounts of gypsum dissolved in waters collected in gypsum karst terrains, expressed as total hardness (TH) in mg L^?1 of CaSO₄·2H₂O (GYP). Total dissolved solid concentrations (TDS) are also considered. Curves obtained with the program PHREEQC, for the dissolution of pure gypsum in water at 25 C, are compared with 574 comprehensive water chemical analyses selected from gypsum karst studies in Europe and the Americas. Principal common and foreign ions encountered are the BNC group (bicarbonates, nitrates, chlorides). It is found that GYP = 1·12^·SpC + 62 where BNC < 33% (Cl^? < 5%), with one standard error <5% for waters with SpC > 2400 µS cm^?1; GYP = 0·74^·SpC + 777 where BNC < 33% (5% ≤ Cl^? < 15%), with one standard error <10% for waters with SpC > 3100 µS cm^?1; GYP = 0·97^·SpC ? 209 where BNC < 33% and Cl^? ≥ 15%, with one standard error <10% for samples with SpC > 4300 µS cm^?1. There are similar results for the more complex waters found in gypsum karsts where much carbonate rock or salt is also present, to the limit of BNC < 50% for what may reasonably be defined as ‘gypsum waters’. Values of R² for linear correlations of different subsets of the water samples range from 0·69 to 0·96, the majority being >0·8. Copyright © 2006 John Wiley & Sons, Ltd.     

Geotechnical evaluation of Miocene gypsum from Sivas (Turkey)

Gypsum is widely distributed in Sivas (Turkey), occurring chiefly in the formations of Miocene age. The gypsum is generally of the alabastrine type with a little of the porphiroblast type and contains traces of clay minerals, anhydrite and calcite. It is a moderately strong rock in terms of its unconfined compressive strength which is related to the crystal size. Strength increases as the crystal size decreases. The strength of gypsum was reduced by approximately 55%, when the samples were kept in the water for 20 days. Most samples exhibit plastic–elastic–plastic deformation. The gypsum has a high modulus ratio, and is a moderately deformable rock. High lateral deformations and low vertical deformations are observed under the vertical stress conditions in accordance with the relationship between modulus ratio and strain.     

库车坳陷第三系盐膏质盖层特征及其对油气成藏的控制作用

库车坳陷的第三系盐膏质区域盖层具有厚度大、分布广、岩性致密、突破压力高、地层压力也很高的特点,属于封闭性特别强的区域盖层;在坳陷的成藏系统中,起着应变分隔带、流体压力屏障、油气成藏机制分界线的作用;在其上下出现了两种成藏模式-克拉苏模式和大宛齐模式。这套盖层是坳陷油气富集的最重要条件之一,也是我国最优良气田-克拉2大气田形成的最重要条件之一。在其下还会有更多的克拉2型的气田存在。     

最优尺度回归在储层孔隙度主控因素分析中的应用

本文以实测物性、粒度分析及铸体薄片鉴定为基础,结合对东濮凹陷濮卫地区沙二-沙四段储层孔隙度影响因素的分析,利用最优尺度回归方法,定量分析了储层孔隙度的主控因素。研究表明,最优尺度回归可以简便快捷地定量分析多因素对孔隙度的重要程度。分析结果显示各类影响因素重要性排序为:含油级别、层位、胶结物含量、储层与膏盐岩位置关系、压实减孔率及分选系数。成岩作用早期,分选性决定了储层的初始孔隙,压实作用是孔隙度减小的最主要的原因;成岩作用中后期,烃类充注是储层孔隙度得以保存的最主要的原因。