A review of the occurrence, form and origin of C-bearing species in the Khibiny Alkaline Igneous Complex, Kola Peninsula, NW Russia

The Khibiny Complex hosts a wide variety of carbon-bearing species that include both oxidized and reduced varieties. Oxidised varieties include carbonate minerals, especially in the carbonatite complex at the eastern end of the pluton, and Na-carbonate phases. Reduced varieties include abiogenic hydrocarbon gases, particularly methane and ethane, dispersed bitumens, solid organic substances and graphite. The majority of the carbon in the Khibiny Complex is hosted in either the carbonatite complex or within the so-called “Central Arch”. The Central Arch is a ring-shaped structure which separates khibinites (coarse-grained eudialite-bearing nepheline-syenites) in the outer part of the complex from lyavochorrites (medium-grained nepheline-syenites) and foyaites in the inner part. The Central Arch is petrologically diverse and hosts the major REE-enriched apatite–nepheline deposits for which the complex is best known. It also hosts zones with elevated hydrocarbon (dominantly methane) gas content and zones of hydrothermally deposited Na-carbonate mineralisation. The hydrocarbon gases are most likely the product of a series of post-magmatic abiogenic reactions. It is likely that the concentration of apatite-nepheline deposits, hydrocarbon gases and Na-carbonate mineralisation, is a function of long lived fluid percolation through the Central Arch. Fluid migration was facilitated by stress release during cooling and uplift of the Khibiny Complex. As a result, carbon with a mantle signature was concentrated into a narrow ring-shaped zone.     

焦磷酸根在即时合成阴离子粘土结构中的嵌入作用

污染物在矿物结构中的嵌入是固化、净化污染物的一种有前景的矿物学方法。焦磷酸根离子是工业废水中较难处理的工业磷污染源之一,研究新的除磷技术是水污染控制技术领域的重要课题之一。通过人工配制焦磷酸盐废水,初步研究镁一铝盐水解共沉淀法即时合成阴离子粘土去除焦磷酸根的效果、影响因素和焦磷酸根离子在阴离子粘土结构中的嵌入作用。研究结果表明,通过镁一铝盐水解共沉淀法即时合成阴离子粘土,焦磷酸根离子有效地嵌入阴离子粘土结构中,对焦磷酸根有非常好的去除效果。影响处理效果的主要因素是pH值和Mg／Al比值。pH值为9．0～10,Mg／Al比1：1～3：1时,都可以获得较好的去除效果。     

基于DDS的氦光泵磁力仪射频场智能调频研究

地磁场测量在基础地质研究、矿产资源勘查和军事探测等领域得到广泛应用,作为磁场测量核心之一的氦光泵磁力仪探头,其射频场调频精度是决定其磁测精度的重要影响因素。为实现易调节、高精度、高可靠性的调频信号,本文利用直接数字频率合成器(DDS)与微控制器(MCU)相结合方式,研究了磁力仪探头射频场智能精密调频技术,可灵活、实时、自动、精密地对磁力仪探头射频场进行调频。调频信号加载到氦光泵磁力仪系统的联调试验表明,磁力仪获得了稳定精密的磁共振信号,从而保证了磁力仪实现高精度的磁场测量。     

A reassessment of models for hydrocarbon generation in the Khibiny nepheline syenite complex, Kola Peninsula, Russia

Although hydrocarbon-bearing fluids have been known from the alkaline igneous rocks of the Khibiny intrusion for many years, their origin remains enigmatic. A recently proposed model of post-magmatic hydrocarbon (HC) generation through Fischer-Tropsch (FT) type reactions suggests the hydration of Fe-bearing phases and release of H₂ which reacts with magmatically derived CO₂ to form CH₄ and higher HCs. However, new petrographic, microthermometric, laser Raman, bulk gas and isotope data are presented and discussed in the context of previously published work in order to reassess models of HC generation. The gas phase is dominated by CH₄ with only minor proportions of higher hydrocarbons. No remnants of the proposed primary CO₂-rich fluid are found in the complex. The majority of the fluid inclusions are of secondary nature and trapped in healed microfractures. This indicates a high fluid flux after magma crystallisation. Entrapment conditions for fluid inclusions are 450–550 °C at 2.8–4.5 kbar. These temperatures are too high for hydrocarbon gas generation through the FT reaction. Chemical analyses of rims of Fe-rich phases suggest that they are not the result of alteration but instead represent changes in magma composition during crystallisation. Furthermore, there is no clear relationship between the presence of Fe-rich minerals and the abundance of fluid inclusion planes (FIPs) as reported elsewhere. δ¹³C values for methane range from − 22.4‰ to − 5.4‰, confirming a largely abiogenic origin for the gas. The presence of primary CH₄-dominated fluid inclusions and melt inclusions, which contain a methane-rich gas phase, indicates a magmatic origin of the HCs. An increase in methane content, together with a decrease in δ¹³C isotope values towards the intrusion margin suggests that magmatically derived abiogenic hydrocarbons may have mixed with biogenic hydrocarbons derived from the surrounding country rocks.     

Probabilities of occurrence of great earthquakes in the Himalaya

Long-term conditional probabilities of occurrence of great earthquakes along the Himalaya plate boundary seismic zone have been estimated. The chance of occurrence of at least one great earthquake along this seismic zone over a period of 100 years (beginning the year 1999) is estimated to be about 0.89. The 100-year probability of such an earthquake occurring in the Kashmir seismic gap is about 0.27, in the central seismic gap about 0.52 and in the Assam gap about 0.21. The 25-year probabilities of their occurrence in these gaps are 0.07, 0.17, and 0.05 respectively. These probability estimates may be used profitably to assess the seismic hazard in the Himalaya and the adjoining Ganga plains.     

四川彭州葛仙山巨型冰川漂砾的发现及意义

四川彭州市葛仙山巨型冰川漂砾距四川盆地边缘地带约３～４ｋｍ,规模巨大（约６ｋｍ×２５ｋｍ×０３ｋｍ）,是目前世界上发现的罕见巨型冰川漂砾。现有资料研究结果表明,葛仙山巨型漂砾是早更新世青藏大冰盖冰流的搬运作用所形成的。是青藏大冰盖存在的有力证据之一,也是全球泛大冰盖形成的重要历史见证。同时对众多相关边缘学科的重大基础理论问题的研究,提供了新的思路、途径和方法     

大埋深条件下降雨入渗补给的初步分析

运用SWAP模型对太行山山前平原--河北省栾城县田间土壤水分运动进行了数值模拟.从土水势及土壤含水量等方面,初步分析了降雨灌溉入渗补给条件下土壤水分运动的规律.通过分析和讨论,探求了大埋深条件下降雨入渗过程,初步揭示了降雨入渗对地下水位变化的影响.     

高温熔融研制岩石标准玻璃方法初步研究:以玄武岩为例

探索了利用高温炉合成玄武岩玻璃制作原位微区主微量元素含量分析的标准物质的实验条件.选取玄武岩标准物质GBW07105(GSR-3)进行高温熔融、淬火实验研究,获得玄武岩玻璃,为合成其他地质样品微区分析标准参考物质的研制提供了参考方法.用激光剥蚀-四极杆等离子体质谱(LA-Q-ICPMS)对样品微区46个主元素和微量元素...     

高温熔融研制钾长石玻璃标准物质初探

激光剥蚀多接收等离子体质谱(LA-MC-ICPMS)是进行原位微区分析微量元素和同位素的重要技术之一,标准样品与样品之间的基体匹配是解决影响该技术准确分析的基体效应和分馏效应的首选方案。长石(特别是长石微区)的Pb同位素组成是示踪岩石形成和演化历史的重要途径,而LA-MC-ICPMS技术则是进行长石Pb同位素原位微区分析的关键技术,然而目前国内外尚没有合适的长石Pb同位素分析标准。文章研究探讨了利用高温炉进行原位微区分析钾长石中Pb同位素组成所用外部标准物质合成条件,结果表明,常规的74μm(200目)碎样无法得到均一的钾长石玻璃,需要将初始钾长石粉末研磨至1300目以下;高温炉合成温度为1680℃;熔融时间为2 h;采用液氮方式淬火。制成的钾长石玻璃除表面具有轻微的不均一性外,内部的Pb同位素比值为1.90779±0.00009(208Pb/206Pb,2s),0.75899±0.00004(207Pb/206Pb,2s),20.909±0.002(206Pb/204Pb,2s),15.871±0.002(207 Pb/204 Pb,2s)和39.888±0.005(208 Pb/204 Pb,2s),相应的相对标准偏差(RSD)分别为0.007%、0.008%、0.016%、0.016%和0.021%。表明利用本研究方法合成的钾长石玻璃可作为潜在的钾长石中Pb同位素组成原位微区分析外部校准物质。     

山东省胶南市七宝山铅矿区地质矿产特征综合研究

胶南七宝山位于胶东半岛东部地区,区域上属于胶南-威海造山带.山东省地质调查院在此开展普查工作,并通过激电测深、土壤测量、钻孔取芯,以及化学和光谱等分析方法,得出铅矿矿体赋存于断裂构造中,属岩浆热液充填型.矿体主要呈脉状、凸镜状,宽1～3 m,长70～200 m,主要矿体走向近南北,多倾向东.矿石有用化学成分主要为Pb、Ag、CaF2、Cu,Pb含量一般为1.36%～3.96%(平均3.11%),矿体平均厚度3.13m.