Intergranular diffusion rates from the analysis of garnet surfaces: Implications for metamorphic equilibration

Novel approaches to garnet analysis have been used to assess rates of intergranular diffusion between different matrix phases and garnet porphyroblasts in a regionally metamorphosed staurolite‐mica‐schist from the Barrovian‐type area in Scotland. X‐ray maps and chemical traverses of planar porphyroblast surfaces reveal chemical heterogeneity of the garnet grain boundary linked to the nature of the adjacent matrix phase. The garnet preserves evidence of low temperature retrograde exchange with matrix minerals and diffusion profiles documenting cation movement along the garnet boundaries. Garnet–quartz and garnet–plagioclase boundaries preserve evidence of sluggish Mg, Mn and Fe diffusion at comparable rates to volume diffusion in garnet, whereas diffusion along garnet–biotite interfaces is much more effective. Evidence of particularly slow Al transport, probably coupled to Fe³⁺ exchange, is locally preserved on garnet surfaces adjacent to Fe‐oxide phases. The Ca distribution on the garnet surface shows the most complex behaviour, with long‐wavelength heterogeneities apparently unrelated to the matrix grain boundaries. This implies that the Ca content of garnet is controlled by local availability and is thought likely to reflect disequilibrium established during garnet growth. Geochemical anomalies on the garnet surfaces are also linked to the location of triple junctions between the porphyroblasts and the matrix phases, and imply enhanced transport along these channels. The slow rates of intergranular diffusion and the characteristics of different boundary types may explain many features associated with the prograde growth of garnet porphyroblasts. Thus, minerals such as quartz, Fe‐oxides and plagioclase whose boundaries with garnet are characterized by slow intergranular diffusion rates appear to be preferentially trapped as inclusions within porphyroblasts. As such grain boundary diffusion rates may be a significant kinetic impediment to metamorphic equilibrium and garnet may struggle to maintain chemical and textural equilibrium during growth in pelites.     

Assessing the effectiveness of imperviousness on stormwater runoff in micro urban catchments by model simulation

Imperviousness, considered as a critical indicator of the hydrologic impacts of urbanization, has gained increasing attention both in the research field and in practice. However, the effectiveness of imperviousness on rainfall–runoff dynamics has not been fully determined in a fine spatiotemporal scale. In this study, 69 drainage subareas <1 ha of a typical residential catchment in Beijing were selected to evaluate the hydrologic impacts of imperviousness, under a typical storm event with a 3‐year return period. Two metrics, total impervious area (TIA) and effective impervious area (EIA), were identified to represent the impervious characteristics of the selected subareas. Three runoff variables, total runoff depth (TR), peak runoff depth (PR), and lag time (LT), were simulated by using a validated hydrologic model. Regression analyses were developed to explore the quantitative associations between imperviousness and runoff variables. Then, three scenarios were established to test the applicability of the results in considering the different infiltration conditions. Our results showed that runoff variables are significantly related to imperviousness. However, the hydrologic performances of TIA and EIA were scale dependent. Specifically, with finer spatial scale and the condition heavy rainfall, TIA rather than EIA was found to contribute more to TR and PR. EIA tended to have a greater impact on LT and showed a negative relationship. Moreover, the relative significance of TIA and EIA was maintained under the different infiltration conditions. These findings may provide potential implications for landscape and drainage design in urban areas, which help to mitigate the runoff risk. Copyright © 2015 John Wiley & Sons, Ltd.     

陕北风沙区含砾石工程堆积体坡面产流产沙试验

采用室内人工模拟降雨方法,研究了陕北风沙区含砾石工程堆积体边坡的产流产沙过程。结果表明:①砾石存在改变了坡面入渗速率,径流系数受入渗速率的影响,随砾石含量的增加先线性递减后线性递增,并在10%砾石含量处存在阈值;径流系数随降雨强度的增加线性递增。②含砾石堆积体坡面流速较纯土堆积体降低,且随雨强增大,砾石延缓径流流动的作用越显著;雨强对径流流速的影响随砾石含量增加持续减弱。③土壤剥蚀率在产流24~33 min后显著增加,砾石主要对显著增加后的平均剥蚀率产生影响。④雨强1.0 mm/min时,砾石存在促进降雨侵蚀,产沙量增大;雨强大于1.0 mm/min时,砾石具有显著的减沙效应。     

新疆乌恰萨热克铜矿北矿带库孜贡苏组沉积相、古流向、物源区及其找矿意义——来自砾石统计分析的证据

萨热克盆地库孜贡苏组是萨热克铜矿的赋矿层位,开展沉积相、物源区及古流向研究对隐伏铜矿的勘探具有重要意义。选取萨热克铜矿北矿带库孜贡苏组地表矿化最好的砾岩展开砾石统计分析,结果表明,偏斜度显示砾岩为冲积扇相沉积,砾石叠瓦状和砂岩斜层理产状统计显示古流向为北北东向;砾石成分主要为石英、石英砂岩、砂岩,石英岩等;粒度分布呈宽峰态或尖峰态;物源区为元古宇长城系阿克苏群变质岩剥蚀区;物源补给分为主河流补给和支河流补给2种方式。冲积扇相、古流向、物源区分析确定了矿体的范围、最优的勘探线布置方位和潜在的找矿靶区,具有很好的勘探意义。     

Unconsolidated sediment distribution patterns in the KwaZulu-Natal Bight,South Africa: the role of wave ravinement in separating relict versus active sediment populations

This paper examines the distribution of unconsolidated sediment in the KwaZulu-Natal Bight located along the east coast of South Africa. Results show that there is a general shelf-wide sediment distribution of coarser grain sizes between depths of 60 and 100?m, punctuated by a broad swathe of mud offshore of the Thukela River. Seasonal changes in sediment distribution patterns are small, being restricted to seaward fining on the inner shelf off the fluvial sources. Sediment distribution reflects a partitioning between sediment populations that are current- influenced and relict (palimpsest) populations associated with submerged shorelines. Wave ravinement during the deglacial transgression, the reworking of submerged shorelines during sea-level stillstands and, to a lesser extent, the Agulhas Current system, are the dominant controls on sediment distribution.     

粗砂砾石地层中高压旋喷桩隔水帷幕施工技术

太原万达广场A2区商住楼基坑工程部分区域为粗砂砾石地层,基坑隔水帷幕中深层搅拌桩无法有效使用。提出了在粗砂砾石地层采用高压旋喷桩隔水帷幕的施工技术方案,采用双套管锚杆钻机引孔、单管高压喷射工艺进行施工,成功实施了这一工程。经检查,喷射注浆体相互咬合良好,有效桩径内水泥含量均匀无夹块现象,隔水帷幕止水效果良好。     

黔中乌当盆地阶地沉积特征及其对盆地演化的指示

黔中乌当盆地是贵州省山间盆地的典型代表,四级河流阶地清晰地记录了新构造运动中区域地壳抬升和盆地演化。通过阶地沉积物砾组统计、粒度分析、光释光（OSL）测年,探讨盆地的发育和演化。结果显示,阶地砾石排列指示盆地水系古流向与现代河流基本一致,砾石磨圆度变化大,分选较差,岩性继承了区域地层。砾石组合特征反映了构造抬升期盆地内强烈的冲刷剥蚀。漫滩沉积物粒度表明盆地在稳定阶段河流水动力整体呈增大趋势。T4和T3发育阶段区域以冲刷剥蚀为主并塑造了盆地雏形。T2阶地沉积特征及测年结果（177.4 ka~87.6 ka）表明中更新世末期持续数万年的沉积夷平作用使盆地基本成型。T1阶地形成时代约25ka,指示了黔中地区最近一次构造抬升和盆地的最终定型。     

Geomorphological evidence from the Lleyn Peninsula constraining models of the magnitude and rate of isostatic rebound during deglaciation of the Irish Sea Basin

A stepped series of sand and gravel terraces on the Lleyn peninsula of North Wales is used to test the magnitude and rate of isostatic depression required by the recently proposed glacimarine model of deglaciation of the Irish Sea Basin. A relative sea-level fall of 70 m is required while the ice remained pinned at the north Lleyn coast. Even taking the maximum known rate of isostatic uplift, the margin would have to remain stationary for 1400 years. It seems more reasonable to interpret the Lleyn terraces, and similar features around the Irish Sea Basin, as glacifluvial and glacilacustrine.     

The determination of potential difference by the joint application of measured and synthetical gravity data: a case study in Hungary

In an elementary approach every geometrical height difference between the staff points of a levelling line should have a corresponding average g value for the determination of potential difference in the Earth’s gravity field. In practice this condition requires as many gravity data as the number of staff points if linear variation of g is assumed between them. Because of the expensive fieldwork, the necessary data should be supplied from different sources. This study proposes an alternative solution, which is proved at a test bed located in the Mecsek Mountains, Southwest Hungary, where a detailed gravity survey, as dense as the staff point density (~1 point/34 m), is available along a 4.3-km-long levelling line. In the first part of the paper the effect of point density of gravity data on the accuracy of potential difference is investigated. The average g value is simply derived from two neighbouring g measurements along the levelling line, which are incrementally decimated in the consecutive turns of processing. The results show that the error of the potential difference between the endpoints of the line exceeds 0.1 mm in terms of length unit if the sampling distance is greater than 2 km. Thereafter, a suitable method for the densification of the decimated g measurements is provided. It is based on forward gravity modelling utilising a high-resolution digital terrain model, the normal gravity and the complete Bouguer anomalies. The test shows that the error is only in the order of 10⁻³mm even if the sampling distance of g measurements is 4 km. As a component of the error sources of levelling, the ambiguity of the levelled height difference which is the Euclidean distance between the inclined equipotential surfaces is also investigated. Although its effect accumulated along the test line is almost zero, it reaches 0.15 mm in a 1-km-long intermediate section of the line.     

Explicit stress–strain equations for modeling frictional materials

In this paper, a comprehensive study on simulating the shearing behavior of frictional materials is performed. A set of two explicit equations, describing the relationship among the shear stress ratio and the distortional strain and the volumetric strain, are formulated independently. The equations contain three stress parameters and three strain parameters and another parameter representing the nonuniformity of stress and strain during softening. All the parameters have clear physical significance and can be determined experimentally. It is demonstrated that the proposed equations have the capacity of simulating the complicated shearing behavior of many types of frictional materials including geomaterials. The proposed equations are used to simulate the stress–strain behavior for 27 frictional materials with 98 tests. These materials include soft and stiff clays in both reconstituted and structured states, silicon sands and calcareous sands, silts, compacted fill materials, volcanic soils, decomposed granite soils, cemented soils (both artificially and naturally cemented), partially saturated soils, ballast, rocks, reinforced soils, tire chips, sugar, wheat, and rapeseed. It has been demonstrated that the proposed explicit constitutive equations have the capacity to capture accurately the shearing behavior of frictional materials both qualitatively and quantitatively. A study on model parameters has been performed.