Carbon dioxide on planetary bodies: Theoretical and experimental studies of molecular complexes

An absorption band at ∼4.26 μm wavelength attributed to the asymmetric stretching mode of CO in CO₂ has been found on two satellites of Jupiter and several satellites of Saturn. The wavelength of pure CO₂ ice determined in the laboratory is 4.2675 μm, indicating that the CO₂ on the satellites occurs either trapped in a host material, or in a chemical or physical complex with other materials, resulting in a blue shift of the wavelength of the band. In frequency units, the shifts in the satellite spectra range from 3.7 to 11.3 cm⁻¹. We have performed ab initio quantum chemical calculations of CO₂ molecules chemically complexed with one, two, and more H₂O molecules and molecules of CH₃OH to explore the possibility that the blue shift of the band is caused by chemical complexing of CO₂ with other volatile materials. Our computations of the harmonic and anharmonic vibrational frequencies using high levels of theory show a frequency shift to the blue by 5 cm⁻¹ from pure CO₂ to CO-H₂O, and an additional 5 cm⁻¹ from CO₂-H₂O to CO₂-2H₂O. Complexing with more than two H₂O molecules does not increase the blue shift. Complexes of CO₂ with one molecule of CH₃OH and with one CH₃OH plus one H₂O molecule produce smaller shifts than the CO₂-2H₂O complex. Laboratory studies of CO₂:H₂O in a solid N₂ matrix also show a blue shift of the asymmetric stretching mode.     

Discharge experiments simulating chemical evolution on the surface of Titan

Saturn's moon Titan has been considered as one of the few places in our Solar System, where atmospheric and surface conditions could have produced organic compounds essential as precursors for an evolution of life. The Cassini-Huygens mission has provided new data on Titan's atmosphere and surface, which enabled us to simulate the chemical processes occurring under these conditions. Possible lightning events on Titan cannot only produce higher hydrocarbons, but also allow surface water ice to participate in the reaction scenario, resulting in CHO, CHN, and CHON compounds including several molecules relevant for the formation of amino acids and nucleic acids.     

Unstable extension of Enceladus' lithosphere

Regions near Enceladus' equator, Sarandib and Diyar Planitia, contain extensive sets of parallel ridges and troughs that may be diagnostic of the region's formation conditions. We present photoclinometry profiles across these ridges and troughs, which indicate that they are periodic, low-slope features with dominant wavelengths of 3 to 4 km and amplitudes between 100 and 400 m. The morphology of these terrains is consistent with formation via unstable extension of the lithosphere. Our numerical modeling demonstrates that unstable extension can generate large-scale topography under Enceladus-like conditions. Comparison of our photoclinometry profiles with the dominant wavelengths produced by our numerical model permits estimation of the background heat flow at the time the Sarandib-Diyar province formed. We estimate heat flows of 110 to , suggesting that resurfacing of the planitiae was accompanied by strong, localized heating. The extension necessary to produce the ridges and troughs may have been caused by now-inactive diapirs, internal phase changes, or other mechanisms. Our heat flux estimates imply elastic thickness at the time of resurfacing of 0.4 to 1.4 km, which are sufficient to have allowed satellite reorientation if the province was underlain by a low-density region. It is therefore plausible that Enceladus has experienced multiple heating events, each leading to localized resurfacing and global reorientation.     

Polarization of Asteroid (387) Aquitania: The newest member of a class of large inversion angle asteroids

We present new imaging polarimetric observations of two Main Belt asteroids, (234) Barbara and (387) Aquitania, taken in the first half of 2008 using the Dual-Beam Imaging Polarimeter on the University of Hawaii 2.2 m telescope, located on Mauna Kea, Hawaii. Barbara had been previously shown to exhibit a very unusual polarization-phase curve by [Cellino, A., Belskaya, I.N., Bendjoya, Ph., di Martino, M., Gil Hutton, R., Muinonen, K., Tedesco, E.F., 2006. Icarus 180, 565-567]. Our observations confirm this result and add Aquitania to the growing class of large inversion angle objects. Interestingly, these asteroids show spinel features in their IR spectra suggesting a mineralogical origin to the phase angle-dependent polarimetric features. As spinel is associated with calcium-aluminum-rich inclusions and carbonaceous chondrites, these large inversion angle asteroids may represent some of the oldest surfaces in the Solar System. Circular as well as linear polarization measurements were obtained but circular polarization was not detected.     

Photochemistry of methane-water ices

We report a study on the broadband ultraviolet photolysis of methane-water ice mixtures, at low methane concentrations and temperatures relevant to the icy satellites of the outer Solar System. The photochemistry of these mixtures is dominated by the action of hydroxyl radicals on methane and the resulting products. This implies that, given sufficient exposure time, the methane will eventually be completely oxidized to carbon dioxide. The presence of methane inhibits the formation of hydrogen peroxide by serving as a trap for hydroxyl radicals. The distribution of photochemical products is broadly similar to that previously conducted using ion and electron sources, with some differences possibly attributable to the difference in radiation source. The results are applicable to a variety of icy bodies in the Solar System. On Enceladus, where methane mixed with water is measured in the plumes, methane in the surface ices is subject to oxidation and will eventually be converted to CO₂. The CH stretch feature detected in the VIMS spectra of the Enceladus surface ice suggests that methane is currently being supplied to the surface ice, likely from re-condensation of the plume gas.     

Spectroscopy of K-complex asteroids: Parent bodies of carbonaceous meteorites?

This is the first focused study of non-Eos K asteroids. We have observed a total of 30 K-complex objects (12 K-2 Sk- and 13 Xk-type asteroids (from the Bus taxonomy), plus 3 K-candidates from previous work) and we present an analysis of their spectral properties from 0.4 to 2.5 μm. We targeted these asteroids because their previous observations are spectrally similar enough to suggest a possible compositional relationship. All objects have exhibited spectral redness in the visible wavelengths and minor absorptions near 1 micron. If, as suggested, K-complex asteroids (including K, Xk, and Sk) are the parent bodies of carbonaceous meteorites, knowledge of K-asteroid properties and distribution is essential to our understanding of the cosmochemical importance of some of the most primitive meteorite materials in our collection. This paper presents initial results of our analysis of telescopic data, with supporting analysis of laboratory measurements of meteorite analogs. Our results indicate that K-complex asteroids are distinct from other main belt asteroid types (S, B, C, F, and G). They do not appear to be a subset of these other types. K asteroids nearly span the range of band center positions and geometric albedos exhibited by the carbonaceous chondrites (CO, CM, CV, CH, CK, CR, and CI). We find that B-, C-, F- and G-type asteroids tend to be darker than meteorites, and can have band centers longer than any of the chondrites measured here. This could indicate that K-complex asteroids are better spectral analogues for the majority of our carbonaceous meteorites than the traditional B-, C-, F- and G-matches suggested in the literature. This paper present first results of our ongoing survey to determine K-type mineralogy, meteorite linkages, and significance to the geology of the asteroid regions.     

Submillimeter photometry and lightcurves of Ceres and other large asteroids

Photometry and thermal lightcurves of six large asteroids (1-Ceres, 2-Pallas, 3-Juno, 12-Victoria, 85-Io and 511-Davida) have been observed at 870 μm (345 GHz) using the MPIfR 19-Channel Bolometer of the Heinrich-Hertz Submillimeter Telescope. Only Ceres displayed a lightcurve with an amplitude (∼50%, peak to peak) that was significantly greater than the uncertainty in the observations. When thermal fluxes and brightness temperatures are corrected for heliocentric distance and albedo, there is a significant relation with the sub-solar latitude of the asteroid, or the local season of the asteroid. No such trend can be found between observations with solar phase angle. These results are evidence that most of the submillimeter thermal radiation is emitted from below the diurnal thermal wave. Comparing the observed trend with model output suggests that the submillimeter radiation from all the asteroids we observed is best modeled by surface material with low thermal inertia (<15 J m⁻² s^−0.5 K⁻¹, consistent with mid-infrared observations of large main-belt asteroids) and a refractive index closer to unity relative to densities inferred from radar experiments, implying a veneer of material over the asteroid surface with a density less than 1000 kg m⁻³. More data with better signal-to-noise and aspect coverage could improve these models and constrain physical properties of asteroid surface materials. This would also allow asteroids to be used as calibration sources with accurately known and stable, broadband fluxes at long wavelengths.     

Formation of mountains on Io: Variable volcanism and thermal stresses

Thermal stresses are potentially important drivers of Io's tectonics and mountain building. It has been hypothesized that sustained local or regional shut down of heat-pipe volcanism on Io could lead to deep crustal heating and large compressive stresses [McKinnon, W.B., Schenk, P.M., Dombard, A.J., 2001. Geology 29, 103-106]. Such large stresses would then be relieved by thrust faulting and uplifting of crustal blocks, producing mountains like those observed on Io. Here we analyze the tectonic consequences of the heat-pipe model in detail, considering both the initial thermal stress state of a basalt or peridotite crust created by heat-pipe volcanism, and relative roles of subsidence stresses (due to burial of preexisting layers) and thermal stresses arising from variable volcanism and changes in crustal (∼lithosphere) thickness. We limit the magnitude of the potential subsidence stresses in our study, because the magnitude of subsidence stresses can be quite large, if not dominant. Results indicate that for a fixed crustal thickness, the region of failure and faulting moves closer to the surface as eruption rate decreases and time increases. When the crust melts at its base as volcanism decreases (as might occur under steady state tidal heating), resulting in crustal thinning, the region of failure is brought even closer to the surface. Naturally, when compressive, subsidence stresses are included, the vertical extent of crust in brittle failure thickens to include most of the lithosphere. In contrast, increases in eruption rate cause the extent of the region in compressional failure to decrease and be driven very deep in the crust (in the absence of sufficient subsidence stress). Therefore, regions of declining volcanism are more likely to produce mountains, whereas regions of extensive or increasing volcanism are less likely to do so. This is consistent with the observation of a global anticorrelation between mountains and volcanic centers on Io. Finally, we find that the choice of crustal composition/rheology (dry basalt vs. dry peridotite) has little effect on our results implying that basalt, peridotite and komatiite are all similarly “stiff” in the Io environment.     

New insights on the binary Asteroid 121 Hermione

We report on the results of a 6-month photometric study of the main-belt binary C-type Asteroid 121 Hermione, performed during its 2007 opposition. We took advantage of the rare observational opportunity afforded by one of the annual equinoxes of Hermione occurring close to its opposition in June 2007. The equinox provides an edge-on aspect for an Earth-based observer, which is well suited to a thorough study of Hermione’s physical characteristics. The catalog of observations carried out with small telescopes is presented in this work, together with new adaptive optics (AO) imaging obtained between 2005 and 2008 with the Yepun 8-m VLT telescope and the 10-m Keck telescope. The most striking result is confirmation that Hermione is a bifurcated and elongated body, as suggested by Marchis, et al. [Marchis, F., Hestroffer, D., Descamps, P., Berthier, J., Laver, C., de Pater, I., 2005. Icarus 178, 450-464]. A new effective diameter of 187 ± 6 km was calculated from the combination of AO, photometric and thermal observations. The new diameter is some 10% smaller than the hitherto accepted radiometric diameter based on IRAS data. The reason for the discrepancy is that IRAS viewed the system almost pole-on. New thermal observations with the Spitzer Space Telescope agree with the diameter derived from AO and lightcurve observations. On the basis of the new AO astrometric observations of the small 32-km diameter satellite we have refined the orbit solution and derived a new value of the bulk density of Hermione of 1.4 + 0.5/−0.2 g cm⁻³. We infer a macroscopic porosity of ∼33 + 5/−20%.     

Eclipsing binary Trojan asteroid Patroclus: Thermal inertia from Spitzer observations

We present mid-infrared observations of the binary L5-Trojan system (617) Patroclus-Menoetius before, during, and after two shadowing events, using the Infrared Spectrograph (IRS) on board the Spitzer Space Telescope. For the first time, we effectively observe changes in asteroid surface temperature in real time, allowing the thermal inertia to be determined very directly. A new detailed binary thermophysical model is presented which accounts for the system’s known mutual orbit, arbitrary component shapes, and thermal conduction in the presence of eclipses.We obtain two local thermal-inertia values, representative of the respective shadowed areas: and . The average thermal inertia is estimated to be , potentially with significant surface heterogeneity. This first thermal-inertia measurement for a Trojan asteroid indicates a surface covered in fine regolith. Independently, we establish the presence of fine-grained (<a few μm) silicates on the surface, based on emissivity features near 10 and similar to those previously found on other Trojans.We also report V-band observations and report a lightcurve with complete rotational coverage. The lightcurve has a low amplitude of peak-to-peak, implying a roughly spherical shape for both components, and is single-periodic with a period equal to the period of the mutual orbit, indicating that the system is fully synchronized.The diameters of Patroclus and Menoetius are 106±11 and , respectively, in agreement with previous findings. Taken together with the system’s known total mass, this implies a bulk mass density of , significantly below the mass density of L4-Trojan asteroid (624) Hektor and suggesting a bulk composition dominated by water ice.All known physical properties of Patroclus, arguably the best studied Trojan asteroid, are consistent with those expected in icy objects with devolatilized surface (extinct comets), consistent with what might be implied by recent dynamical modeling in the framework of the Nice Model.