华北克拉通南缘小秦岭地区花岗质浅色脉体锆石U-Pb年龄、稀土元素特征及其地质意义

小秦岭地区发育有大量古元古代晚期的花岗质浅色脉体, 这为理解同时期华北克拉通南缘的深熔作用和构造演化提供了重要的窗口。本文对小秦岭地区三条花岗质浅色脉体中的锆石开展了CL图像、LA-ICP-MS U-Pb年代学及稀土元素的研究。浅色脉体中的锆石具有深熔成因锆石的斑杂状、平面状或弱振荡环带的内部结构及较为自形的外部形态特征, 测得的锆石207Pb/206Pb年龄分别为(1867±13) Ma (MSWD=0.22, n=21)、(1849±17) Ma (MSWD=0.79)和(1828±15) Ma (MSWD=0.33, n=20), 代表了该区深熔作用发生的时间。与上述三组年龄相对应, 其锆石稀土元素配分曲线由具较弱负Eu异常(Eu/Eu*=0.12~0.81)的重稀土相对富集型, 转变为中等负Eu异常(Eu/Eu*=0.29~0.61)的近平坦重稀土型、再到显著负Eu异常(Eu/Eu*=0.15~0.54)的重稀土富集型, 结合锆石Ti温度计获取其结晶温度为574~708 °C, 表明地壳深熔作用的发生可能与高角闪岩相-麻粒岩相的退变质作用有关。结合前人的变质年代学数据可知, 小秦岭地区1.87~1.82 Ga的深熔作用应与~1.95 Ga时东、西部陆块碰撞造山所致增厚地壳的长期抬升和冷却过程有关。     

Extensional Setting of Hainan Island in Mesoproterozoic: Evidence from Granitic Intrusions in the Baoban Group

The Mesoproterozoic Baoban Group is the oldest basement in Hainan Island and has played an important role in Columbia (Nuna) supercontinent reconstructions. The Mesoproterozoic granitic intrusions in the Baoban Group are the most widely-exposed Precambrian magmatic rocks and are the key to understanding the tectonic settings of Hainan Island and its relationship with the South China Block and the Columbia supercontinent. New LA-ICP-MS zircon U-Pb dating on three mylonitic granite samples from the Tuwaishan and Baoban areas yield ages ranging from 1447 Ma to 1437 Ma, representing the absolute timing of the emplacement of the granitic intrusions. Combined with previously published geochronological data for rocks from the Baoban Group and regional mafic intrusions, it is concluded that the Baoban Group formed at 1460–1430 Ma, coeval with the emplacement of the granitic and mafic intrusions. New in-situ zircon Lu-Hf isotope analyses for the three mylonitic granite samples yielded positive εHf(t) values, ranging from +0.49 to +8.27, with model ages (TCDM) ranging from 2181 Ma to 1687 Ma, suggesting that the granitic intrusions originated from a mixed source of Paleoproterozoic crust with juvenile crust. New zircon trace element data show characteristics of high Th/U values of 0.24–1.50, steep slopes from LREE to HREE and negative Pr, Eu anomalies with positive Ce, Sm anomalies, representing typical magmatic zircons formed in continental crust. Compared with available magmatic and detrital zircon ages from Precambrian rocks in the Cathaysia Block, Yangtze Block and western Laurentia, it is inferred that Hainan Island was separated from both the Cathaysia Block and the Yangtze Block, instead being connected with western Laurentia in the Columbia supercontinent. Considering the decreasing tendency of basin deposition time along the western margin of Laurentia, it is proposed that Hainan Island was located to the north or northwest of the Belt-Purcell Supergroup, along the western margin of Laurentia, during the breakup of the Columbia supercontinent.     

西藏玉龙铜矿床成矿斑岩的厘定及地质意义

位于青藏高原东缘的玉龙铜矿是我国最大的斑岩铜矿之一,其形成一致认为与矿区中心产出的二长花岗质复式斑岩体有关,但成矿与复式岩体的确切关系并不清楚。本文通过详细的野外地质填图,特别是矿床8号勘探线12个钻孔的重新编录,在复式岩体中识别出一套花岗斑岩岩枝,岩枝中不规则状石英-钾长石脉广泛发育,同时还见有单向固结结构、粗晶及细晶结构,这些特征表明该岩浆中的流体曾经发生过饱和。同时结合矿床高品位(0.6%,质量分数)铜矿化紧密围绕花岗斑岩分布、含矿脉体自花岗斑岩向外围逐渐由高温石英-钾长石A脉过渡为中低温石英-硫化物脉、热液蚀变自花岗斑岩向外由高温钾硅酸盐化过渡为中低温石英-绢云母化的规律,最终确定这套花岗斑岩为玉龙矿床的成矿斑岩。玉龙铜矿成矿斑岩的厘定,较好地解释了矿床矿化类型及金属的分布规律,为进一步深入理解矿床形成过程提供了帮助。     

小兴安岭西北部霍龙门地区花岗质杂岩锆石U--Pb年龄、岩石地球化学特征及地质意义

小兴安岭西北部的霍龙门地区位于兴蒙造山带东段,该区出露的大面积花岗质杂岩为新开岭—科洛杂岩的重要组成部分。该花岗质杂岩主要由花岗质和花岗闪长质糜棱岩等组成,其中花岗质糜棱岩的SHRIMP锆石U--Pb定年结果为310.7±6.5 Ma,表明其原岩形成于晚石炭世。该杂岩的主量元素总体显示中、高钾钙碱性准铝质--过铝质系列岩石的特点;微量元素表现出Th、Zr、Hf、Nd、Rb、K明显富集,而Ba、Sr、Nb、P、Ti明显亏损;稀土元素具有明显的轻稀土元素富集、重稀土元素相对亏损的特征,有较明显的负Eu异常,轻、重稀土元素分馏程度较强。结合区域构造演化特点及花岗质杂岩的形成环境等,综合显示该杂岩的原岩应形成于晚古生代,于三叠纪时期发生明显的变质变形作用。     

高挂山—牛头寨地区小型环形影象构造分析及其找矿意义

高挂山—牛头寨地区,通过大比例尺航片解译,发现6个大小不等的小型环形影象信息。这些环形影象与岩浆活动、已知矿床、矿化点、重砂异常、物化探异常等的分布有着内在的联系。为预测找矿远景区和找隐伏矿床提供了影象依据。     

Petrographic, Chemical and B-Isotopic Insights into the Origin of Tourmaline-Rich Rocks and Boron Recycling in the Martinamor Antiform (Central Iberian Zone, Salamanca, Spain)

Tourmaline in the Martinamor antiform occurs in tourmalinites(rocks with >15–20% tourmaline by volume), clasticmetasedimentary rocks of the Upper Proterozoic Monterrubio formation,quartz veins, pre-Variscan orthogneisses and Variscan graniticrocks. Petrographic observations, back-scattered electron (BSE)images, and microprobe data document a multistaged developmentof tourmaline. Overall, variations in the Mg/(Mg + Fe) ratiosdecrease from tourmalinites (0·36–0·75),through veins (0·38–0·66) to granitic rocks(0·23–0·46), whereas Al increases in thesame order from 5·84–6·65 to 6·22–6·88apfu. The incorporation of Al into tourmaline is consistentwith combinations of ^xAl(NaR)_–1 and AlO(R(OH))_–1exchange vectors, where ^x represents X-site vacancy and R is(Mg + Fe²⁺ + Mn). Variations in ^x/(^x + Na) ratios are similarin all the types of tourmaline occurrences, from 0·10to 0·53, with low Ca-contents (mostly <0·10apfu). Based on field and textural criteria, two groups of tourmaline-richrocks are distinguished: (1) pre-Variscan tourmalinites (probablyCadomian), affected by both deformation and regional metamorphismduring the Variscan orogeny; (2) tourmalinites related to thesynkinematic granitic complex of Martinamor. Textural and geochemicaldata are consistent with a psammopelitic parentage for the protolithof the tourmalinites. Boron isotope analyses of tourmaline havea total range of ¹¹B values from –15·6 to 6·8;the lowest corresponding to granitic tourmalines (–15·6to –11·7) and the highest to veins (1·9to 6·8). Tourmalines from tourmalinites have intermediate¹¹B values of –8·0 to +2·0. The observedvariations in ¹¹B support an important crustal recycling ofboron in the Martinamor area, in which pre-Variscan tourmaliniteswere remobilized by a combination of mechanical and chemicalprocesses during Variscan deformation, metamorphism and anatexis,leading to the formation of multiple tourmaline-bearing veinsand a new stage of boron metasomatism. KEY WORDS: tourmalinites; metamorphic and granitic rocks; mineral chemistry; whole-rock chemistry; boron isotopes     

西秦岭北缘新阳—元龙韧性剪切带中花岗质糜棱岩黑云母40Ar 39Ar年龄及地质意义

西秦岭北缘新阳-元龙大型韧性剪切带是分划西秦岭造山带与祁连造山带的区域主构造边界,通过对其物质组成和构造特征的研究,结合两侧不同(洋-陆)构造环境下各类地质体的研究成果,重点对剪切带内花岗质糜棱岩中黑云母单矿物进行了~(40)Ar-~(39)Ar定年研究.在新阳镇和元龙北剪切带中分别获得(347.95±2.17)Ma (MSWD＝1.89)和(351.70±1.72)Ma (MSWD＝0.80)的坪年龄,分析确定其应为黑云母的冷却年龄,表明变形时代应在早石炭世早期之前;反映了最晚在早石炭世早期,该剪切带已横切秦岭与祁连造山带并发生强烈的右行走滑构造拼贴作用.     

闽西南玮埔岩体和赣南菖蒲混合岩锆石La ICPMS U-Pb年代学

闽西玮埔岩体和赣南菖蒲混合岩位于武夷山构造带南部地区。对NNE向展布的闽西玮埔岩体两个样品进行了锆石LaICPMS U-Pb 测年,获得的年龄为447.1±4.7Ma和440.8±3.4Ma,证明这个岩体不是原来认为的印支期花岗岩,而属于加里东岩体。赣南菖蒲混合岩发育于罗浮岩体的北侧,早期将罗浮岩体归于燕山早期岩体。对混合岩进行的锆石LaICPMS U-Pb 测年,获得的年龄为445.9±3.8Ma,确定这个岩体为加里东期。这些新的高精度年龄学数据为武夷山加里东构造运动时限和性质提供了精确约束。     

黑龙江铁力兴安一带斑岩型钼矿资源潜力预测

黑龙江省铁力市兴安地区发育晚三叠世-早侏罗世的细粒二长花岗斑岩的U-Pb锆石LA-ICPMS年龄为195～201Ma,钼矿(化)体产于斑岩体的顶部或外接触带的中细粒似斑状二长花岗岩中,斑岩体的岩石学、矿化及围岩蚀变、地球化学异常特征,均显示出斑岩型矿床的特征.另外,在花岗质火山-侵入杂岩体中也见钼矿化,其异常模式虽显示出中温火山热液有关的特征,但从区域成矿演化特征来看,可能与晚三叠世-早侏罗世细粒二长花岗斑岩具有统一的构造-岩浆-成矿体系,具"同源不同环境、部位和同位、不同成矿期次"的特征.     

江西冷水坑矿床含矿花岗斑岩的Sr-Nd及锆石Hf-O同位素研究

江西冷水坑铅锌矿床是武夷成矿带北段的典型矿床,矿区内含矿花岗斑岩锆石U-Pb年龄为（162.0±2.0）Ma,岩浆分异程度较高,具有高SiO₂（69.46%~75.52%）、高K₂O（K₂O/Na₂O>3.22）、强过铝质（ASI=1.20~1.96）的特征。岩体发育较明显的Eu负异常,富集强不相容元素Rb、Th、U,而亏损高场强元素Ba、Sr、Nb、Ta、P、Ti。全岩同位素测试结果显示,冷水坑含矿花岗斑岩具有极高的⁸⁷Sr/⁸⁶Sr初始比值（0.74005~0.76518）与低的ε_Nd值（-11.48~-10.78）,锆石Hf-O同位素测定值变化范围较小,¹⁷⁶Hf/¹⁷⁷Hf介于0.282317~0.282460,具有负的ε_Hf（t）值（-12.39~-7.62）和相对较高的δ¹⁸O值（7.23‰~8.81‰）,指示岩浆主要来自于成熟地壳,可能起源于北武夷地区变质基底,源岩为基底变质岩,这可能与古太平洋板块俯冲形成的挤压背景下的地壳熔融有关。