The petroleum generation potential and effective oil window of humic coals related to coal composition and age

A worldwide data set of more than 500 humic coals from the major coal-forming geological periods has been used to analyse the evolution in the remaining (Hydrogen Index, HI) and total (Quality Index, QI) generation potentials with increasing thermal maturity and the ‘effective oil window’ (‘oil expulsion window’). All samples describe HI and QI bands that are broad at low maturities and that gradually narrow with increasing maturity. The oil generation potential is completely exhausted at a vitrinite reflectance of 2.0–2.2%R_o or T_max of 500–510 °C. The initial large variation in the generation potential is related to the original depositional conditions, particularly the degree of marine influence and the formation of hydrogen-enriched vitrinite, as suggested by increased sulphur and hydrogen contents. During initial thermal maturation the HI increases to a maximum value, HI_max. Similarly, QI increases to a maximum value, QI_max. This increase in HI and QI is related to the formation of an additional generation potential in the coal structure. The decline in QI with further maturation is indicating onset of initial oil expulsion, which precedes efficient expulsion. Liquid petroleum generation from humic coals is thus a complex, three-phase process: (i) onset of petroleum generation, (ii) petroleum build-up in the coal, and (iii) initial oil expulsion followed by efficient oil expulsion (corresponding to the effective oil window). Efficient oil expulsion is indicated by a decline in the Bitumen Index (BI) when plotted against vitrinite reflectance or T_max. This means that in humic coals the vitrinite reflectance or T_max values at which onset of petroleum generation occurs cannot be used to establish the start of the effective oil window. The start of the effective oil window occurs within the vitrinite reflectance range 0.85–1.05%R_o or T_max range 440–455 °C and the oil window extends to 1.5–2.0%R_o or 470–510 °C. For general use, an effective oil window is proposed to occur from 0.85 to 1.7%R_o or from 440 to 490 °C. Specific ranges for HI_max and the effective oil window can be defined for Cenozoic, Jurassic, Permian, and Carboniferous coals. Cenozoic coals reach the highest HI_max values (220–370 mg HC/g TOC), and for the most oil-prone Cenozoic coals the effective oil window may possibly range from 0.65 to 2.0%R_o or 430 to 510 °C. In contrast, the most oil-prone Jurassic, Permian and Carboniferous coals reach the expulsion threshold at a vitrinite reflectance of 0.85–0.9%R_o or T_max of 440–445 °C.     

Hydrology and hydrogeology of Sakaryabaşı Karstic springs, Çifteler, Turkey

The Sakarya River is one of the largest rivers in Turkey and is fed mainly from Sakaryabaşı springs. The Sakaryabaşı springs are located in the Central Anatolia and issue from confined/semi-confined karst having a thermal component and therefore, having quite different hydrogeological characteristics as compared to the Taurus Karst region, a typical example of the Mediterranean type of karst. The karstic carbonate rocks that form the groundwater reservoir are overlain by a thick semi-pervious overburden of mainly clastics of Neogene age. Tectonics is the major factor controlling the occurrence of the karst springs in the area where topography is rather flat. This study aimed at explaining the occurrence and movement of the karst groundwater within the system by use of hydrogeological, chemical, and isotopic tools. Isotopic composition of the waters revealed that all waters in the region are of meteoric origin and the thermal component is due to deep circulation. The catchment area of the hydrogeological system extends to the south and groundwater movement is towards the outlets, which are in a depression along a major fault. The movement of the groundwater, based on analysis of remotely sensed images, is controlled mainly by structural elements.     

Geophysical methods applied to fault characterization and earthquake potential assessment in the Lower Tagus Valley, Portugal

The study region is located in the Lower Tagus Valley, central Portugal, and includes a large portion of the densely populated area of Lisbon. It is characterized by a moderate seismicity with a diffuse pattern, with historical earthquakes causing many casualties, serious damage and economic losses. Occurrence of earthquakes in the area indicates the presence of seismogenic structures at depth that are deficiently known due to a thick Cenozoic sedimentary cover. The hidden character of many of the faults in the Lower Tagus Valley requires the use of indirect methodologies for their study. This paper focuses on the application of high-resolution seismic reflection method for the detection of near-surface faulting on two major tectonic structures that are hidden under the recent alluvial cover of the Tagus Valley, and that have been recognized on deep oil-industry seismic reflection profiles and/or inferred from the surface geology. These are a WNW–ESE-trending fault zone located within the Lower Tagus Cenozoic basin, across the Tagus River estuary (Porto Alto fault), and a NNE–SSW-trending reverse fault zone that borders the Cenozoic Basin at the W (Vila Franca de Xira–Lisbon fault). Vertical electrical soundings were also acquired over the seismic profiles and the refraction interpretation of the reflection data was carried out. According to the interpretation of the collected data, a complex fault pattern disrupts the near surface (first 400 m) at Porto Alto, affecting the Upper Neogene and (at least for one fault) the Quaternary, with a normal offset component. The consistency with the previous oil-industry profiles interpretation supports the location and geometry of this fault zone. Concerning the second structure, two major faults were detected north of Vila Franca de Xira, supporting the extension of the Vila Franca de Xira–Lisbon fault zone northwards. One of these faults presents a reverse geometry apparently displacing Holocene alluvium. Vertical offsets of the Holocene sediments detected in the studied geophysical data of Porto Alto and Vila Franca de Xira–Lisbon faults imply minimum slip rates of 0.15–0.30 mm/year, three times larger than previously inferred for active faults in the Lower Tagus Valley and maximum estimates of average return periods of 2000–5000 years for M 6.5–7 co-seismic ruptures.     

Water temperature behaviour in the River Loire since 1976 and 1881

Analysis of monthly mean river temperatures, recorded on an hourly basis in the middle reaches of the Loire since 1976, allows reconstruction by multiple linear regression of the annual, spring and summer water temperatures from equivalent information on air temperatures and river discharge. Since 1881, the average annual and summer temperatures of the Loire have risen by approximately 0.8?°C, this increase accelerating since the late 1980s due to the rise in air temperature and also to lower discharge rates. In addition, the thermal regime in the Orleans to Blois reach is considerably affected by the inflow of groundwater from the Calcaires de Beauce aquifer, as shown by the summer energy balance. To cite this article: F. Moatar, J. Gailhard, C. R. Geoscience 338 (2006).     

Impact of Flood Disasters on Taiwan in the Last Quarter Century

The increasing natural disasters, especially floods during the last quarter century, are raising the economic losses in Taiwan. The most severe hazard in Taiwan is flooding induced by typhoons and storms in summer and autumn. By comparing the rivers around the world, the ones in Taiwan have the steepest slopes, the largest discharge per unit drainage area, and the shortest time of concentrations. Rapid urbanization without proper land uses managements usually worsen the flood problems. Consequently, flood hazards mitigation has become the most essential task for Taiwan to deal with. Although the government keeps improving flood defense structures, the flood damage grows continuously. In this article, possible flood mitigation strategies are identified for coping with complex environmental and social decisions with flood risk involved.     

青藏高原植物形态和解剖适应性研究进展

与低海拔地区相比，青藏高原的太阳辐射、水分条件、氧分压、气温等环境条件都有明显差异，青藏高原的植物在细胞壁厚度、栅栏细胞层数、通气组织大小、异细胞数量和分布、表皮附属物类型等方面与低海拔地区的相比也有较大的不同。综述了在青藏高原特殊的生态条件下，植物在形态和解剖方面的适应性表现，分析了该领域目前的研究特点和存在的一些问题，并在全球环境变化背景下，对其发展前景进行了展望，指出了未来的发展趋势。     

Computation of Large Anisotropic Seismic Heterogeneities (CLASH)

A general tomographic technique is designed in order (i) to operate in anisotropic media; (ii) to account for the uneven seismic sampling and (iii) to handle massive data sets in a reasonable computing time. One modus operandi to compute a 3-D body wave velocity model relies on surface wave phase velocity measurements. An intermediate step, shared by other approaches, consists in translating, for each period of a given mode branch, the phase velocities integrated along ray paths into local velocity perturbations. To this end, we develop a method, which accounts for the azimuthal anisotropy in its comprehensive form. The weakly non-linear forward problem allows to use a conjugate gradient optimization. The Earth's surface is regularly discretized and the partial derivatives are assigned to the individual grid points. Possible lack of lateral resolution, due to the inescapable uneven ray path coverage, is taken into account through the a priori covariances on parameters with laterally variable correlation lengths. This method allows to efficiently separate the 2ψ and the 4ψ anisotropic effects from the isotropic perturbations. Fundamental mode and overtone phase velocity maps, derived with real Rayleigh wave data sets, are presented and compared with previous maps. The isotropic models concur well with the results of Trampert & Woodhouse. Large 4ψ heterogeneities are located in the tectonically active regions and over the continental lithospheres such as North America, Antarctica or Australia. At various periods, a significant 4ψ signature is correlated with the Hawaii hotspot track. Finally, concurring with the conclusions of Trampert & Woodhouse, our phase velocity maps show that Rayleigh wave data sets do need both 2ψ and 4ψ anisotropic terms.     

迎接寒武系全球年代地层的新划分——2004年版“国际地层表”述评

评述了国际地层委员会最新公布的2 0 0 4年版“国际地层表”的寒武系部分,包括它的底界全球层型和点位的确定和存在的问题、寒武系当前的再划分情况、芙蓉统和排碧阶及其底界全球层型剖面和点位、寒武系的时代跨度。介绍了全球寒武系年代地层的研究方向和正在表决中的全球寒武系最新划分方案。讨论了与我国寒武系年代地层的划分和建立地方性、区域性年代地层系统的相关问题     

滇黔桂盆地及其邻区石炭纪至二叠纪层序地层格架及三级海平面变化的全球对比

属于被动大陆边缘裂谷盆地的滇黔桂盆地，自加里东运动之后，泥盆纪开始拉开，整个晚古生代延续发展。受同生断裂的控制，在深水盆地中发育大小不等的孤立碳酸盐台地，因而在滇黔桂盆地及其邻区形成特殊的“台-盆-丘-槽”的古地理格局。对不同古地理背景下的典型剖面进行三级层序划分并对其进行空间追索和对比，在滇黔桂盆地及其邻区的石炭纪和二叠纪地层中可以识别出12个三级层序，相当于晚古生代25个三级沉积层序(2-5Ma；SQ1至SQ25)中的SQ24至SQ25；以地层记录中的的两种相变面和两种穿时性为基本要素，可以建立研究区石炭系和二叠系的层序地层格架；层序地层格架反映了三级层序的基本特征：空间上相序的有序性和时间上环境变化的同步性。研究区的石炭系和二叠系，主要为一套碳酸盐岩地层，其中在连陆台地上发育3套煤系地层，它们分别组成石炭纪三级层序SQ15跨系的三级层序SQ19的HST以及二叠纪吴家坪期的三级层序SQ24；而且在连陆台地边缘和孤立台地上，于阳新世的茅口亚世以及乐平世的长兴期发育海绵生物礁，海绵生物礁分别构成了以下二叠系三级层序即阳新世的SQ22和SQ23以及长兴期的SQ25。3套煤系地层和两套海绵生物礁的发育，使研究区的石炭系和二叠系形成了一个与欧美地区完全不同的层序地层序列。在研究区石炭系和二叠系所识别出的12个三级层序中，石炭纪一二叠纪船山世地层可以划分出6个三级层序。这种划分与Busch等对北美相同层位的划分相似，也就是说该6个三级层序的形成时限大于10Ma；较长的形成时限可能反映了形成在联合古陆汇聚时期即全球构造相对稳定时期三级海平面变化的一个特性。因此，研究区的石炭系和二叠系所识别和划分出的12个三级层序，其数量比Ross和Ross(1985)对欧美地区石炭系和二叠系所划分出的50多个三级层序要少得多。