天然气水合物开采过程甲烷气泄漏海床基高密度电阻率法监测效果模拟与分析

为实现天然气水合物开采过程沉积物内甲烷气泄漏过程有效监测,设计了一种海床基原位电学监测方法。为界定该方法对不同模式泄露甲烷气的探测能力,以南海神狐海域天然气水合物试采区为研究区,构建相应地质及电阻率模型,模拟利用设计电学系统对其进行监测,计算得到不同采集参数的电阻率剖面,并对其进行对比分析。研究结果表明：海水层会在探测剖面上某深度区间内形成层状低阻异常带,对该深度区间有效电信号形成压制。将该异常带顶界深度定义为系统有效探测深度后,发现该深度受电极距直接影响,10 m极距偶极装置有效探测深度约为50 m。电学探测剖面对有效探测深度内分布的层状和团状甲烷气聚集区、慢速甲烷气泄露区、沿断层泄露的甲烷气区具有良好反映能力,数据处理得到的相对电阻率剖面与电学探测剖面相比能更好地反映甲烷气聚集区边界。该监测方法能够实时监测含气区空间变化。     

The diagenetic history of Oligocene-Miocene sandstones of the Austrian north Alpine foreland basin

Diagenesis is an essential tool to reconstruct the development of reservoir rocks. Diagenetic processes - precipitation and dissolution - have an influence on pore space. The present paper aims to study the diagenetic history of deep-marine sandstones of the Austrian Alpine Foreland Basin. To reach that goal, sediment petrology and diagenetic features of more than 110 sandstone samples from water- and gas-bearing sections from gas fields within the Oligocene-Miocene Puchkirchen Group and Hall Formation has been investigated. Special emphasis was put on samples in the vicinity of the gas-water contact (GWC). The sediment petrography of sandstones of Puchkirchen Group and Hall Formation is similar; hence their diagenesis proceeded the same way. In fact, primary mineralogy was controlled by paleo-geography with increasing transport distance and diverse detrital input.Sediment petrographically, investigated sandstones from the water-bearing horizon seemed quite comparable to the gas-bearing sediments. In general, they can be classified as feldspatic litharenites to litharenites and display porosities of up to 30% and permeabilities of up to 1300 mD. The carbon and oxygen isotopic composition of bulk carbonate cements from these sandstones range from−3.8 to +2.2 and from −7.5 to +0.2‰ [VPDB]. However, near the Gas-Water Contact (GWC) a horizon with low porosities (<3%) and permeabilities (<0.1 mD) is present. This zone is completely cemented with calcite, which has a blocky/homogenous morphology. A slight, but significant negative shift in δ18O isotopy (−2.5‰) is evident.During early diagenesis the first carbonate generations formed. First a fibrous calcite and afterwards a micritic calcite precipitated. Further siliciclastic minerals, such as quartz and feldspar (K-feldspar and minor plagioclase), exhibit corroded grains. Occasionally, clay minerals (illite; smectite, chlorite) formed as rims around detrital grains. Late diagenesis is indicated by the formation of a low permeable zone at the GWC.     

Continuous air rate measurement in flotation cells: Some fundamental considerations

A robust and reliable sensor to measure gas (air) superficial velocity (J_g) continuously in flotation systems is introduced. It is based on the sampling of bubbles by buoyancy with the accumulating air allowed to exit through an orifice. At steady state, pressure drop is measured and related to the J_g by prior calibration. The continuous device is readily automated and extended to a multi-unit set-up. The sensor and data collections are described. The governing gas flow equation and models of the dynamic response to air flow rate set point change and fluctuations in froth depth are derived. Model predictions are confirmed against plant data. By taking a moving average, the J_g remains valid in the face of typical plant disturbances.     

诸广花岗岩体放射性水异常的某些特征

本文以寻找铀矿为目的,在该岩体140Km~2面积上进行水化学普查,发现水异常370个,其特征为:若异常多且成片出现,则预示着有单个矿体规模不大的矿体群存在;条带状展布的水异常预示着存在方向相同的矿化带;阻水阻气构造带近旁之异常预示水源上方存在矿化;水温偏高之水异常与矿化关系密切;与矿化有关的多为铀—氡混合异常;大构造处之水异常并不表示此构造存在矿化,面往往是在其附近次一级构造中成矿.     

基于WebGIS的浙江省天然气调控应急保障气象服务系统

随着浙江省天然气供应规模的逐步扩大,应用领域的不断拓展,用WebGIS对天然气管线进行管理更显其优势。气象条件的变化与天然气供需有着密切的联系,本文基于WebGIS建立了浙江省天然气调控应急保障气象服务系统。对天然气管网数据进行了整理,并结合气象数据进行了分析和统一存储及管理。系统采用B／S架构,实现了天然气管道沿线实况监测、沿线天气预报、沿线气象历史资料查询、管网负荷预测、地图管理和操作、系统管理和维护等功能。探索了气象条件对燃气负荷的影响规律,能及时查询天然气沿线的天气实况和预报,为天然气调控应急保障提供了直观的气象服务和数据保障。     

采空区输气管道弹性变形分析

近年来输气管道工程的大规模建设,其不可避免地要通过一些煤矿采空沉陷区和地质构造复杂区域。煤矿采空沉陷区的地表移动变形必然会使上覆的输气管道发生变形、甚至破坏,因此,分析与预测煤矿采空区地埋输气管道的安全性具有重要意义。本文以西气东输一线为例,依据弹性理论分析计算,当管道下伏分别为土体和岩体时,输气管道破坏时的岩土体垮塌宽度,并统计在垮塌影响范围一定的条件下,岩土体垮塌宽度与管道变形及最小曲率半径之间的规律。结果表明,管道的弯曲变形与垮塌宽度之间呈递增关系。     

天然气水合物和地热资源组合评价方法

近年来的研究表明,海洋中天然气水合物的成藏和分布受温度的影响较大,一些海域中的天然气水合物资源与地热资源同时存在且有一定的分布规律。在利用地热开采天然气水合物基础上把2种资源结合起来利用,将会对海洋天然气水合物的开发有重要意义。参考组合评价相关经验公式,基于该开采方法对天然气水合物和地热资源组合评价提出了相关的方法研究,并通过实例应用,丰富了该开采方法的可行性的论证,并对于2种资源的综合利用的靶区优选有一定的指导作用。     

The impact of hurricanes on sedimenting particulate matter in the semi-arid Bahía de La Paz,Gulf of California

From 2002 through 2004, time-series sediment trap samples were collected from a depth of 410 m in Cuenca Alfonso, Bahía de La Paz, on the SW coast of the Gulf of California. The instrument recorded the impact of the local passage of hurricanes “Ignacio” (24–26 August) and “Marty” (21–23 September) in 2003. These two events accounted for 82% of the total rainfall measured in 2003, equivalent to the annual average precipitation in years without hurricanes. Mean total mass fluxes (TMFs) of 2.88 and 3.58 g m⁻² d⁻¹ were measured during the week of each hurricane as well as the following week. This may have been enough to produce a lamina in the underlying sediment with characteristics peculiar to such events. The terrigenous component was particularly abundant, with notably higher concentrations of Fe, Sc, Co and Cs and REEs. In contrast, TMFs throughout 2002–2004 (excluding the hurricane periods) averaged only 0.73 g m⁻² d⁻¹ and had a larger marine biogenic component. The extraordinary elemental fluxes during the 29 days of hurricane-influenced sedimentation represented a great proportion of the totals over an entire “normal” year: Co (67.8%) >Sc (62.6) >Fe (59.6) >Cs (53.4)>Lu (51.5)>La (51.3)>Yb (51.0)>Ce (49.5) >Tb (48.4) >Sm (44.7)>Cr (36.5) >Ca (31.0)>Eu (25.4%). The terrigenous fraction was calculated using (a) TMF minus the sum of CaCO₃, biogenic silica and organic matter and (b) the ratio of Sc in the trap samples to the average in the Earth's crust. The latter was consistently smaller, but the two methods offered similar results following hurricanes (78% vs. 63%, respectively). For normal sedimentation, however, the difference method yielded values twice as large as the Sc method (58% vs. 30%) This suggests that the mineralogy of the terrigenous fraction may also vary, with unsorted dessert soil being carried to sea by the powerful flash floods associated with hurricanes. Eolian supply of particles, particularly Sc-free quartz grains, possibly from beyond the limited fluvial drainage basin, apparently dominates normal sedimentation.     

气态膜回收氰化物的研究

气态膜是一种新型的膜分离技术,适用于从水溶液中分离提取挥发性物质。本文对气态膜回收氰化物的迁移机理及各种影响因素进行了研究,结果表明：传质速率与料液浓度呈现线性递增关系;吸收液浓度、流速和料液浓度、流速在一定范围内影响传质速率;温度升高,传质加快;膜孔径及孔隙率增大,传质速率也随之增大。     

Material selection for the gas containment system of a compressed natural gas carrier fleet

In this work, the possible exploitation of fiber-reinforced composites in the context of maritime transportation of compressed natural gas (CNG) is investigated. In addition to a more conventional steel configuration, two different fiber materials, carbon and glass, are considered as construction materials for pressure vessels (PVs) to be stored on board ships, with thickness optimized by FEM analysis.The considered scenario is represented by the transportation of CNG from an offshore well to a terminal on shore. Fleets of ships carrying CNG in pressure vessels manufactured with the investigated materials are generated by means of a ship synthesis model (SSM) software and compared on the basis of technical and economical indicators.The choice of the construction material influences considerably the weight of the PVs, which represent a major item of total ship weight and reflects directly on the general transport performances in terms of resistance, seakeeping and reliability in the service. On the other hand, capital as well as operating expenditures are considerably affected by the choice. When exploring the design space, the ship synthesis model is able, at a preliminary stage of the design, to account for the various technical and economical aspects, their implications and relationships. Results are presented of computations carried out in a specific case, identified by the annual gas production and other characteristics of the well terminal and a cruising route for the ships. The comparison is carried out on the basis of the cost per transported unit of gas and of the percentage of success in the transportation process. The computations show that the choice of the PV material has a key influence on the results in terms of optimal number, dimensions and speed of the ships.