粉煤灰与生石灰加固软土的室内试验研究

粉煤灰是一种工业废弃物,与生石灰一样均可用来加固软土地基。笔者进行了粉煤灰与生石灰加固土的室内配方试验,分别将水泥或生石灰与粉煤灰按照不同的比例干拌均匀后,再与不同含水量的软土人工拌和均匀,测定了不同龄期的无侧限抗压强度;分析了石灰加固土强度与生石灰掺入比和龄期的关系及其压缩系数、压缩模量等的变化。并进一步分析了粉煤灰的加固机理,旨在为其进一步的研究和工程应用提供参考。     

濮阳近50a风速变化特征及突变分析

利用线性分析方法,分析了濮阳近50 a平均风速、大风日数的变化特征,并利用滑动的t检验法分析了风速突变,结果显示:年平均风速以0.498(m/s)/10 a的倾向率减少,大风和扬沙日数分别以2.7 d/10 a和5.6 d/10 a的倾向率减少;平均风速,大风、扬沙日数在20世纪80年代初期发生突变。     

Geotechnical Properties of Low Calcium and High Calcium Fly Ash

In this paper, a comparative study has been made for physical and engineering properties of low calcium and high calcium Indian fly ash. The grain size distribution of fly ash is independent of lime content. Fly ash particles of size >75 μm are mostly irregular in shape whereas finer fractions are spherical for low calcium fly ash. For high calcium fly ash, chemical and mineralogical differences have been observed for different size fractions. Compared to low calcium fly ash, optimum moisture content is low and maximum dry density is high for high calcium fly ash. Optimum moisture content is directly proportional and maximum dry density is inversely proportional to the carbon content. The mode and duration of curing have significant effect on strength and stress–strain behavior of compacted fly ash. The gain in strength with time for high calcium fly ash is very high compared to that of low calcium fly ash due to presence of reactive minerals and glassy phase.     

Removal of Cu(Ⅱ) from Wastewater Using Acidified Sewage Sludge Ash

Sewage sludge ash (SSA), the waste generated in sewage sludge incineration, was obtained from Wuhan Sewage Treatment Plant and used as a low-cost sorbent for removing Cu(Ⅱ) from wastewaters. The sorbent was first modified with 5 % sulfuric acid to increase its sorption capacity. The specific surface area, porosity, cation-exchange capacity (CEC) and pHZPC of the sorbent were measured. Batch experiments were made to study the effect of contact time, solution pH value and temperature on sorption. Both Langmuir and Freundlich models well described the Cu(Ⅱ) sorption process, with correlation coefficient (R2) values of 0.993 4 and 0.989 9 respectively. And the sorption process follows the Lagergren first order kinetic model. The equilibrium sorption capacity of acidified SSA to Cu(Ⅱ) is estimated to be 7.78 mg/g under optimal conditions.     

The chemical composition including the Rare Earth Elements of the three major glass types of Europe and the Orient used in late antiquity and the Middle Ages

Sets of 20 soda ash glasses, 16 soda lime glasses and 23 wood ash glasses mainly from excavations in Europe (additional soda ash glasses from Egypt) were analysed on 61 chemical elements. Average SiO₂ is about 62% in soda glasses and 50% in wood ash glasses. The three groups of glasses contain on average 13% Na₂O, 18% Na₂O and 13% K₂O as fluxes to lower the melting temperature of quartz at their production. The starting materials beside quartz were halophytic plant ash for soda ash glass, trona (Na₃H(CO₃)₂·2H₂O) and lime (clamshells) for soda lime glass and beech ash for wood ash glass. Each of the three major glass types contains specific Rare Earth Element (REE) concentrations mainly contained in quartz and its intergrown minerals. 50 Paleozoic and Mesozoic sandstones from Central Europe represent the quartz composition. The REE pattern of these glasses apparently indicates major compositional stages of the Continental Earth's Crust. The boron to lithium and sodium to potassium ratios as in seawater suggest reactions of materials for soda glass with seawater. Negative Ce anomalies in the three glasses are caused by reactions of quartz with seawater.     

橡胶颗粒改良粉煤灰土的动力特性试验研究

对橡胶颗粒改良粉煤灰土的动强度、动模量、黏聚力和内摩擦角进行了动三轴试验研究,并将试验结果与粉煤灰土的动力特性加以对比,分析表明：粉煤灰土及橡胶颗粒改良粉煤灰土在同一围压下动强度均随破坏周数的增加而减小;在同一破坏周数下动强度随着围压的增加而增加;粉煤灰土的黏聚力为203.73 kPa,内摩擦角为11°;橡胶颗粒改良粉煤灰土的黏聚力为227.26 kPa,内摩擦角为17°,橡胶颗粒改良粉煤灰土的黏聚力增大了23.53 kPa,提高了11.55%;粉煤灰土的初始切线模量及平均动模量高于橡胶颗粒改良粉煤灰土的初始切线模量及平均动模量。研究表明,橡胶颗粒改良后的粉煤灰土具有动强度高、黏聚力和内摩擦角大的特点,从而说明橡胶颗粒改良后的粉煤灰土可以作为季冻区路基冷阻层材料     

From in-situ coal to fly ash: a study of coal mines and power plants from Indiana

This paper presents data on the properties of coal and fly ash from two coal mines and two power plants that burn single-source coal from two mines in Indiana. One mine is in the low-sulfur (<1%) Danville Coal Member of the Dugger Formation (Pennsylvanian) and the other mines the high-sulfur (>5%) Springfield Coal Member of the Petersburg Formation (Pennsylvanian). Both seams have comparable ash contents (11%). Coals sampled at the mines (both raw and washed fractions) were analyzed for proximate/ultimate/sulfur forms/heating value, major oxides, trace elements and petrographic composition. The properties of fly ash from these coals reflect the properties of the feed coal, as well as local combustion and post-combustion conditions. Sulfur and spinel content, and As, Pb and Zn concentrations of the fly ash are the parameters that most closely reflect the properties of the source coal.     

氢化物发生—原子荧光光谱法快速测定粉煤灰中微量硒

随着环境科学与人体健康研究的深入,硒作为人体必需的15种微量元素之一,尤为科技工作者所重视。硒属于一种稀散微量元素,主要用于电子和电器工业以及导弹,高空通讯设备等。在半导体﹑橡胶﹑石油工业中,硒也有着广泛的用途。人体硒水平偏低,可致老年期衰减速度加快,合理地补充硒可以预防和治疗心血管疾病,增强体液的免疫力,并能有效地防止肿瘤的扩展,起到预防和治疗癌症的作用。本文应用专属性强的AFS方法分析证实,对测定粉煤灰中的硒,具有简单快速﹑准确灵敏、取样量少、测定范围宽等优点。其加标回收率在:90.0%~101.0%之间,RSD为:3.36%~6.02%。     

初始中主应力系数对中密粉煤灰动模量阻尼比影响的试验研究

利用土工静力-动力液压三轴-扭转多功能剪切仪,开展了在三向非均等固结状态下的饱和中密粉煤灰循环扭剪试验。着重探讨了初始中主应力系数对饱和中密粉煤灰的动模量和阻尼比特性的影响。试验结果表明：初始中主应力系数对粉煤灰动剪切模量有一定的影响,对阻尼比没有影响。根据仪器量测系统的特点,采用了大小位移计联合测量角位移的方法,不仅能够提高测试精度,而且能够获得完整的动模量和阻尼比随动剪应变幅值的变化过程。