聚炳烯酰胺无固相冲洗液在复杂地层中的应用研究

根据多年对聚丙烯酰胺无固相冲洗液钻进技术在地质岩心钻探中的应用情况,进一步分析聚丙烯酰胺无固相冲洗液钻进所具有的技术优势,以及如何发挥其优势,利用聚丙烯酰胺无固相冲洗液钻进水敏地层及其它复杂地层,解决难以钻进的问题。同时,为进一步完善、选择适宜的钻井冲洗液提供一些可供借鉴的建议,使该技术的快速发展和地质岩心钻探钻进技术全面提高。     

高模数水玻璃钾基抑制冲洗液在蠕变坍塌地层中的应用

在青海埃坑南矿区钻遇含角砾石的断层泥地层,孔壁坍塌、掉块,卡钻事故时有发生,几乎无法继续钻进,使用水玻璃与相关钻井液处理剂配合使用制备水玻璃钾基抑制冲洗液,用来平衡地层压力保护孔壁,并且加大金刚石钻头及扩孔器外径,解决了钻孔坍塌、缩径以及卡钻等问题,使施工顺利进行,为后续施工提供了参考方法。     

内蒙古塔木素地区砂岩型铀矿床热活动与铀矿化之间关系

巴音戈壁盆塔木素地区砂岩型铀矿目的层普遍固结,矿体多层但连续性差,分布不规律,后生改造特征明显。本文通过野外露头调查、岩芯观察和微观分析,发现该地区普遍发育穿层脉状石膏或方解石、热液金属硫化物矿物、矿物重结晶与新生胶结物等,出现硫酸盐-金属硫化物共生矿物和S同位素分馏,指示存在后生热流体活动。通过对矿体、矿石特征及铀矿物成因的分析,初步认为热改造对成矿控制主要发生在层间氧化作用后期,温度升高造成碳酸钙和硫酸钙沉淀、重结晶,破坏含矿溶液中碳酸铀酰络合物的平衡,造成U的沉淀,促使铀矿化进一步富集。     

Compositions and Pressure–Temperature Conditions of Metamorphic Fluids Overprinting the Talate VMS Pb–Zn Deposit, Southern Altay, China

The Talate Pb-Zn deposit,located in the east of the NW-SE extending Devonian Kelan volcanic-sedimentary basin of the southern Altaides,occurs in the metamorphic rock series of the upper second lithological section of the lower Devonian lower Kangbutiebao Formation(D_1k_1~2).The Pb-Zn orebodies are stratiform and overprinted by late sulfide—quartz veins.Two distinct mineralization periods were identified:a submarine volcanic sedimentary exhalation period and a metamorphic hydrothermal mineralization period.The metamorphic overprinting period can be further divided into two stages:an early stage characterized by bedding-parallel lentoid quartz veins developed in the chlorite schist and leptite of the ore-bearing horizon,and a late stage represented by pyritechalcopyrite-quartz veins crosscutting chlorite schist and leptite or the massive Pb-Zn ores.Fluid inclusions in the early metamorphic quartz veins are mainly CO_2-H_2O-NaCI and carbonic(CO_2±CH_4±N_2) inclusions with minor aqueous inclusions.The CO_2-H_2O-NaCl inclusions have homogenization temperatures of 294-368℃,T_(m,CO2) of-62.6 to-60.5℃,T_(h,CO2) of 7.7 to 29.6℃(homogenized into liquid),and salinities of 5.5-7.4 wt%NaCl eqv.The carbonic inclusions have T_(m,CO2)of-60.1 to-58.5℃,and T_(h,Co2) of-4.2 to 20.6℃.Fluid inclusions in late sulfide quartz veins are also dominated by CO_2-H_2O-NaCl and CO_2±CH_4 inclusions.The CO_2-H_2O-NaCl inclusions have T_(b,tot) of142 to 360℃,T_(m,CO2)of-66.0 to-56.6℃,T_(h,CO2) of-6.0 to 29.4℃(homogenized into liquid) and salinities of 2.4-16.5 wt%NaCl eqv.The carbonic inclusions have T_(m,Co2)of-61.5 to-57.3℃,and T_(h,CO2) of-27.0to 28.7℃.The aqueous inclusions(L-V) have T_(m,ice) of-9.8 to-1.3℃ and T_(h,tot) of 205 to 412℃.The P-T trapping conditions of CO_2-rich fluid inclusions(100-370 MPa,250-368℃) are comparable with the late- to post-regional metamorphism conditions.The CO_2-rich fluids,possibly derived from regional metamorphism,were involved in the reworking and metal enrichment of the primary ores.Based on these results,the Talate Pb-Zn deposit is classified as a VMS deposit modified by metamorphic fluids.The massive Pb-Zn ores with banded and breccia structures were developed in the early period of submarine volcanic sedimentary exhalation associated with an extensional subduction-related back-arc basin,and the quartz veins bearing polymetallic sulfides were formed in the late period of metamorphic hydrothermal superimposition related to the Permian-Triassic continental collision.     

Raman Micro-Spectroscopic Study of Sulfate Ion in the System Na2SO4 – H2O

This work aims to quantify sulfate ion concentrations in the system Na₂SO₄-H₂O using Raman micro-spectroscopy.Raman spectra of sodium sulfate solutions with known concentrations were collected at ambient temperature（293 K） and in the 500 cm^₁-4000 cm^-1 spectral region.The results indicate that the intensity of the SO₄^2- band increases with increasing concentrations of sulfate ion.A linear correlation was found between the concentration of SO₄^2-（c） and parameter I₁,which represents the ratio of the area of the SO₄^2- band to that of the O-H stretching band of water（A_s/A_w）:I₁=-0.00102+0.01538 c.Furthermore,we deconvoluted the O-H stretching band of water(2800 cm^-1-3800 cm^-1) at 3232 and 3430 cm^-1 into two sub-Gaussian bands,and then defined Raman intensity of the two sub-bands as A_Bi(3232 cm^-1) and A_B2(3430 cm^-1),defined the full width of half maximum（FWHM） of the two sub-bands as W_B1(3232 cm^-1) and W_B2(3430 cm^-1).A linear correlation between the concentration of SO₄^2-（c） and parameter I₂,which represents the ratio of Raman intensity of SO₄^2-（A_s）(in 981 cm^-1) to(A_B1+A_B2),was also established:I₂=-0.0111+0.3653 c.However,no correlations were found between concentration of SO₄^2-（c） and FWHM ratios,which includes the ratio of FWHM of SO₄^2-（W_s） to W_B1 W_B2 and W_B1+B2(the sum of W_B1 and W_B2),suggesting that FWHM is not suitable for quantitative studies of sulfate solutions with Raman spectroscopy.A comparison of Raman spectroscopic studies of mixed Na₂SO₄ and NaCI solutions with a constant SO₄^2- concentration and variable CI^- concentrations suggest that the I\ parameter is affected by CI^-,whereas the I₂ parameter was not.Therefore,even if the solution is not purely Na₂SO₄-H₂O,SO₄^2- concentrations can still be calculated from the Raman spectra if the H₂O band is deconvoluted into two sub-bands,making this method potentially applicable to analysis of natural fluid inclusions.     

新疆独山子泥火山沉积物及孔隙水的地球化学特征与流体来源

对陆地泥火山流体来源及其向地表渗漏过程中的改造作用开展研究,有利于加深理解泥火山释放甲烷的碳排放过程。新疆准噶尔盆地南缘独山子泥火山柱状沉积物和地表沉积物的矿物和元素组成,以及沉积物孔隙水离子组成等的分析结果显示,泥火山沉积物孔隙水Na+和Cl–间具有很好的正相关性,具有比海水高的Na+/Cl–和Li+/Cl–值、低的K+/Cl–和Mg2+/Cl–。泥火山沉积物与围岩相比,富集伊利石、绿泥石和方解石,缺少蒙脱石,富集Ca、亏损Si,这些变化主要与黏土矿物的脱水转变有关。表明泥火山流体主要来源于深部低盐度沉积物孔隙水,但经历了地表的蒸发作用,并混合了大气降水。     

成矿流体动力学与大地构造环境的关系(英文)

热液矿床的形成需要大量流体,而流体的运移需要包括地势差、岩石变形、热梯度及热异常等多种驱动力。这些流体驱动力与构造环境及过程有密切关系。流体压力状态和热场及地势差的组合决定了压性构造环境流体以向上运动为主,如造山型成矿系统,而张性构造环境流体以对流为主,如VMS和SEDEX成矿系统。造山作用造成的地势差及水平挤压作用所产生的超压可以驱动流体侧向迁移数百公里,如MVT成矿系统。但是,具体的成矿流体动力学过程比较复杂,且随构造演化而变化。在经历过多个大地构造演化阶段的地区,如地洼区,老的成矿流体动力系统不断被新的系统叠加或取代;新的构造单元需要来自地幔的流体源补充才有利于成矿。成矿学研究的是成矿作用与大地构造的关系,而流体动力学系统与大地构造环境密切相关,因此,成矿流体动力学应成为成矿学的一个重要组成部分。     

透岩浆流体作用与矿田构造

从透岩浆流体成矿理论的角度对矿田构造进行了重新认识,提出矿田构造系统是一种复杂性动力系统的观点。根据这个模型,矿田构造是近场应力场与远场应力场强烈相互作用的产物。近场应力场由岩浆成矿系统而不是远场应力场派生,因而不能由矿田构造反演区域构造,但可以从区域构造限定矿田构造。矿田构造常有岩脉和热液脉充填,因而是可识别的。利用构造统计学方法,可以根据岩脉和/或热液脉的分布密度图(或等值线图)预测找矿靶区。     

基于DEM-CFD耦合的气吸式排种器仿真研究

为提高大白菜等小粒径精密播种机的机械化水平,设计了一种小粒径气吸式排种器.首先利用JPS-12排种器性能检测试验台对排种器进行测试,得到不同参数组合下的性能指标与最优参数组合.然后使用计算流体力学方法（CFD）,借助FLUENT软件分析了吸种器内部流场的分布,得到了吸种器内部压力分布云图和吸种孔截面云图.最后基于离散元法（DEM）建立大白菜种子颗粒模型,对排种器仿真模型进行简化和网格划分,完成了小粒径气吸式排种器DEM-CFD耦合仿真实验.对比台架与仿真试验结果,得出如下的结论：当排种盘转速为20 r/min,真空度为2.2 kPa时,排种性能最佳.     

核幔耦合对地球自由核章动的激发影响

地球自由核章动（FCN）是地幔与液核相互作用的重要动力学现象,其激发机制涉及地表流体层、地幔和地核等圈层之间的耦合,此前研究多利用地表流体层角动量数据单独研究其对FCN的激发,对核幔耦合的影响考虑不足.本文基于角动量守恒理论分析了核幔耦合对FCN周期及振幅的影响,并结合多个大气及海洋角动量函数时间序列首次估算了核幔耦合在FCN激发过程中的贡献.结果表明核幔耦合对FCN周期产生的固定和时变影响对FCN激发的作用均不可忽视,尤其时变影响可达几十个微角秒,对于进一步解释FCN时变特征非常重要;核幔耦合对FCN振幅的直接影响是地表流体层的激发与实测FCN不相符的主要原因,黏滞、电磁和地形等耗散耦合的存在对地表流体的激发振幅有67%左右的减弱效果.