西天山小于赞金矿成矿流体、成矿年代学特征及其地质意义

小于赞金矿床是产于新疆西天山也列莫顿盆地的浅成低温热液型金矿床,赋存于晚古生代大哈拉军山组火山岩中。矿石类型主要为蚀变岩型和石英脉型,主要发育硅化、黄铁绢英岩化、伊利石化、青磐岩化蚀变。流体成矿过程可分为3个阶段,分别为石英黄铁矿、石英玉髓黄铁矿和石英方解石黄铁矿阶段。小于赞金矿床流体包裹体类型单一,主要为水溶液包裹体,可分为纯液相水溶液包裹体(PL类)、富液相水溶液包裹体(L类)和富气相水溶液包裹体(V类)。石英黄铁矿阶段包裹体均一温度集中于130~190 ℃,盐度w(NaCleqv.)为0.2%~8.0%;石英玉髓黄铁矿阶段均一温度介于115~161 ℃,盐度w(NaCleqv.)为0.7%~3.4%;石英方解石黄铁矿阶段均一温度介于110~138 ℃,盐度w(NaCleqv.)为0.2%~3.4%。鉴于赋矿角砾凝灰岩的锆石U-Pb年龄为(353.8±1.8) Ma,且被下石炭统阿恰勒河组不整合覆盖,故可将小于赞金矿床的成矿时代限定在(353.8±1.8) Ma至早石炭世维宪期。锆石εHf(t)变化范围为+4.1~+8.4,平均值+6.1,两阶段Hf模式年龄tDM2变化范围为822~1 095 Ma,指示该区岩浆演化过程中有少量地幔物质的加入。综合考量矿床地质特征、流体包裹体特征和成矿时代,认为小于赞矿床为早石炭世低硫型浅成低温热液型金矿。     

天然气水合物区多相流体运移模型：以南海神狐海域为例

天然气水合物是重要的海洋油气资源,近年来利用孔隙水地球化学手段结合流体反应运移模型对水合物进行勘探已 成为研究热点。文章针对南海神狐海域钻探GMGS-1航次的数据资料,用孔隙水溴碘摩尔数比值拟合全新世流体运移速率, 构建了二期次非稳态水合物多相流体运移模型,并以SH7站位作为应用,发现自更新世以来研究区水合物成藏系统处于衰 退状态。通过模型参数敏感性分析,了解到影响模型输出的参数权重从高到低依次是沉积物孔隙度、有机质含量和沉积埋 藏速率。进一步数值分析表明,在水合物成藏系统中,有机质含量与水合物饱和度满足线性相关,其他主要参数与饱和度 的关系并非单调函数,且主导水合物稳定区内的甲烷物源是深部外源流体所携带的甲烷。多相流体运移模型对水合物资源 勘查具有一定的理论意义。     

Experimental and numerical study on vortex-induced motions of a deep-draft semi-submersible

An experimental study on vortex-induced motions (VIM) of a deep-draft semi-submersible (DDS) was carried out in a towing tank, with the aim to investigate the VIM effects on the overall hydrodynamics of the structure. In order to study the fluid physics associated with VIM of the DDS, a comprehensive numerical simulation was conducted to examine the characteristics of vortex shedding processes and their interactions due to multiple cylindrical columns. The experimental measurements were obtained for horizontal plane motions including transverse, in-line and yaw motions as well as drag and lift forces on the structure. Spectral analysis was further carried out based on the recorded force time history. These data were subsequently used to validate the numerical model. Detailed numerical results on the vortex flow characteristics revealed that during the “lock-in”, the vortex shedding processes of the upstream columns enhance the vortex shedding processes of the downstream columns leading to the rapid increase of the magnitude of VIM. In addition to the experimental measurements, for the two uniform flow incidences (0° and 45°) investigated, comprehensive numerical data of the parametric study on the VIM characteristics at a wide range of current strength will also serve as quality benchmarks for future study and provide guidance for practical design.     

Predicting the effect of biofouling on ship resistance using CFD

This paper proposes a Computational Fluid Dynamics (CFD) based unsteady RANS model which enables the prediction of the effect of marine coatings and biofouling on ship resistance and presents CFD simulations of the roughness effects on the resistance and effective power of the full-scale 3D KRISO Container Ship (KCS) hull.Initially, a roughness function model representing a typical coating and different fouling conditions was developed by using the roughness functions given in the literature. This model then was employed in the wall-function of the CFD software and the effects of a typical as applied coating and different fouling conditions on the frictional resistance of flat plates representing the KCS were predicted for a design speed of 24 knots and a slow steaming speed of 19 knots using the proposed CFD model. The roughness effects of such conditions on the resistance components and effective power of the full-scale 3D KCS model were then predicted at the same speeds. The resulting frictional resistance values of the present study were then compared with each other and with results obtained using the similarity law analysis. The increase in the effective power of the full-scale KCS hull was predicted to be 18.1% for a deteriorated coating or light slime whereas that due to heavy slime was predicted to be 38% at a ship speed of 24 knots. In addition, it was observed that the wave resistance and wave systems are significantly affected by the hull roughness and hence viscosity.     

Seismic indicators of focused fluid flow and cross-evaporitic seepage in the Eastern Mediterranean

We present for the first time a synthesis of the evidence of focused fluid flow in the Eastern Mediterranean, providing an updated record that includes recent and past occurrences through the last ca. 6 My of evolution of the basin. We do this by adding the interpretation of a previously unpublished regional 2D seismic dataset to the existing occurrences of focused fluid flow reported in the literature. Our interpretation shows a high number (141) of focused fluid flow features, which span the stratigraphic interval from late Miocene to Recent. Of these features, (82) are at the seabed, and (59) are buried. The previous published record is more difficult to quantify, but in comparison shows an overwhelming majority of seabed features, with only rare examples of buried features.The spectrum of the buried and seabed features covers pockmarks, pipes, mud volcanoes, clastic intrusions and collapse structures. Clustering of the fluid flow features is observed at different times in specific areas, including the Nile Cone, and the Levant, Herodotus, Cyprus and Latakia basins. With the buried record, we are able to highlight the evolution of the leakage points through time. Focused fluid flow venting has been occurring since the onset of the Messinian Salinity Crisis and the start of basinwide deposition of evaporites. We focus in particular on seismic indicators of leakage through evaporites, and of sub-evaporitic source for fluids and remobilised sediments. We also discuss the role of the evaporites as a seal to ascending fluids, and in which circumstances they can be breached.Fluids (and associated remobilised sediments) are sourced from different intervals, from the sub- and supra-evaporitic section, and possibly within the evaporites. Only a minor proportion of the fluid flow features are certainly sourced from below the Messinian evaporites, and most of them are located in the Nile-Levant-Eratosthenes areas. The few examples of pathways that are able to cross thick, undeformed and well preserved evaporites are typically correlated to overpressure release and hydrofracturing. This confirms that the evaporites do act regionally as a very good seal as expected, while fluids are able to cross the evaporites only in their most extreme expression, i.e. in near-lithostathic overpressure conditions. This is confirmed by our observations made in the Eastern Mediterranean, where in the presence of relatively undisturbed evaporites, cross-evaporite vertical fluid pathways are only observed at the high end of the flux-pressure range, and involve sediment remobilisation. Maps combining these different elements can be used to detect areas potentially more prone to breaching.     

Seafloor and buried mounds on the western slope of the Niger Delta

Seafloor mounds are potential geohazards to offshore rig emplacement and drilling operations and may contain evidence of underlying petroleum systems. Therefore, identifying and mapping them is crucial in de-risking exploration and production activities in offshore domains.A 738 km² high resolution three-dimensional seismic dataset was used to investigate the occurrence, seismic characteristics and distribution of features interpreted as seafloor and buried sediment mounds, at water-depths of 800–1600 m, on the western Niger Delta slope. Fifteen seafloor mounds and eighteen shallowly buried mounds were identified. The seafloor mounds are characterised by lower seismic amplitude anomalies than the surrounding seabed sediments, and overlie vertical zones of acoustic blanking. The buried mounds in contrast are characterised by high amplitude anomalies; they also directly overlie sub-vertical zones of acoustic blanking. Seismic evidences from the features, their distribution patterns and tectono-stratigraphic associations suggest that their formation was controlled by the juxtaposition of buried channels and structural highs and their formation caused by focused fluid flow and expulsion of entrained sediments at the seabed.Considering the acoustic and geometrical characteristics of the mounds and comparing them with mound-shaped features from around the world, we conclude that the mounds most likely comprise heterolithic seafloor extrusions of muds and sands from the Agbada Formation with gas and possibly oil in some of the pore space giving rise to the acoustic characteristics.     

Study on Pure IL VIV of A Free Spanning Pipeline Under General Boundary Conditions

Pipeline spans may occur due to natural seabed irregularities or local scour of bed sediment. The pure in-line (IL) vortex-induced vibrations (VIV) analysis of the free spans is an important subject for design of pipeline in uneven seabed. The main objective of this paper is to analyze the characteristics of pure IL VIV of a free spanning pipeline under general boundary conditions. An IL wake oscillator model which can describe the coupling of pipeline structure and fluctuating drag is introduced and employed. The coupled partial differential equations of structure and wake are transformed into a set of ordinary differential equations using two-mode Galerkin method. Some case studies are presented and thoroughly discussed in order to investigate the effects of internal fluid, axial force and boundary conditions on the pure IL VIV.     

Fluid Inclusions and Hydrogen,Oxygen, and Lead Isotopes of the Antuoling Molybdenum Deposit,Northern Taihang Mountains,China

The Antuoling Mo deposit is a major porphyry‐type deposit in the polymetallic metallogenic belt of the northern Taihang Mountains, China. The processes of mineralization in this deposit can be divided into three stages: an early quartz–pyrite stage, a middle quartz–polymetallic sulfide stage, and a late quartz–carbonate stage. Four types of primary fluid inclusions are found in the deposit: two‐phase aqueous inclusions, daughter‐mineral‐bearing multiphase inclusions, CO₂–H₂O inclusions, and pure CO₂ inclusions. From the early to the late ore‐forming stages, the homogenization temperatures of the fluid inclusions are 300 to >500°C, 270–425°C, and 195–330°C, respectively, with salinities of up to 50.2 wt%, 5.3–47.3 wt%, and 2.2–10.4 wt% NaCl equivalent, revealing that the ore‐forming fluids changed from high temperature and high salinity to lower temperature and lower salinity. Moreover, based on the laser Raman spectra, the compositions of the fluid inclusions evolved from the NaCl–CO₂–H₂O to the NaCl–H₂O system. The δ¹⁸O_H2O and δD values of quartz in the deposit range from +3.9‰ to +7.0‰ and ?117.5‰ to ?134.2‰, respectively, reflecting the δD of local meteoric water after oxygen isotopic exchange with host rocks. The Pb isotope values of the sulfides (²⁰⁸Pb/²⁰⁴Pb, 36.320–37.428; ²⁰⁷Pb/²⁰⁴Pb, 15.210–15.495; ²⁰⁶Pb/²⁰⁴Pb, 16.366–17.822) indicate that the ore‐forming materials originated from a mixed upper mantle–lower crust source.     

The δ18O of UST Quartz in Two Porphyry Deposits,China

The unidirectional solidification textures (UST) quartz is generally thought to form from fluids exsolved from shallow intrusions and/or magma chambers, but such an idea is still poorly constrained from the evidence of stable isotopes. In this study, we report for the first time the δ¹⁸O of quartz that shows UST from the Qulong Cu–Mo and the Yechangping Mo porphyry deposits in China. The analysis results show that the UST quartz samples from the Qulong deposit have δ¹⁸O values ranging from +6.2 ‰ to +7.6 ‰, which are similar to that of quartz phenocrysts (+6.7 ‰ to +7.8 ‰). In contrast, the UST quartz samples from the Yechangping porphyry Mo deposit yield a high δ¹⁸O value (+10.0 ‰). The δ¹⁸O_water value of Yechangping UST quartz (+8.5 ‰) is also higher than that of Qulong (+4.6 ‰ to +5.8 ‰). Hydrothermal biotite from potassic alteration and sericite from early phyllic alteration at Qulong have similar δ¹⁸O values to UST quartz, suggesting the involvement of magmatic fluids during this stage of deposit evolution.     

古流体研究的无机地球化学方法综述

研究与成藏过程相关的古流体活动有助于深入认识油气成藏过程,从经济目的出发预测储层质量,精确分析不同阶段古流体活动对油气成藏的影响具有重要意义。目前国内外石油地质学家主要利用同位素地球化学、元素地球化学、流体包裹体分析等无机地球化学方法分析古流体活动特征及其对油气成藏的影响。在归纳前人研究成果的基础上,总结了各种无机地球化学方法的最新研究进展,认为同位素地球化学方法有助于分析古流体来源与成因,元素地球化学方法可示踪烃类流体的运移,流体包裹体分析技术结合岩相学研究可分析油气运移的时间、期次、相态、通道和油气藏的富集规律,并指出油气运移和聚集的有利方向。在运用无机地球化学方法研究古流体活动时不应局限于单一方法,综合利用多种无机地球化学方法更有利于全面分析古流体活动特征。