A study on the reaction kinetics of mineral surface adsorption in mix system

The experimental results on adsorption of ions pb²⁺, Zn²⁺ and Ag⁺ onto mineral surfaces in a mix system show that the reaction kinetics of adions adsorbed onto mineral surfaces was mainly controlled by their diffusion rates in solution. The concentration variations can be fit for the second-order rate equation with good determined coefficients r = 0.800 5—0.979 7. In the near neutral solution, the concentration of exchanged ions K⁺ and Na⁺ related to reaction time can be described by the fint-order rate equation with r = 0.855 7–0.997 7. Meanwhile, the complex diffusionexchange rate equation is suitable for describing the ca^{2 +} concentration variation, as ions Pb^{2 +} and Zn²⁺ were adions. Experimental data show that the amount of ions K⁺, Na⁺and Ca²⁺ release is much more than that of adion decrement in solution. This fact may suggest that the complexstion reaction of adions Pb²⁺, Z²⁺ and Ag⁺ with the mineral surfaces was the major reaction process while adions were not entering the phyllosilicate interlayers or CaCO₃ lattice to exchange the ions K⁺, Na⁺ and Ca²⁺ at room temperature. Project supported by the National Natural Science Foundation of China (Grant No. 49773206) and the Natural Science Foundation of Guangdong Province (Grant No. 960504)     

SYNTHESIS AND PROPERTIES OF SULFHYDRYL CHITOSAN

A new adsorbent for heavy metal ions, sulfhydryl chitosan (S-chitosan), was produced by treatment of chitosan with sulhydryl acetic acid in the presence of sulfuric acid as a catalyst. Its structure was confrrmed by elemental analysis and FI‘-IR spectra analysis. The adsorption properties of sulthydryl chitosan for Cu(Ⅱ ), Cd(Ⅱ ), Pb(Ⅱ), Cr(Ⅲ) and Ni(Ⅱ) were investigated, and the effect of pH value on adsorption, adsorption kinetics, and selective adsorption was examined. It was shown that S-chitosan has good adsorption for Pb(Ⅱ), Cu(Ⅱ) and Cd(Ⅱ) like chitosan, is also insoluble in acid solution; has good adsorption kinetic properties for heavy metal ions; and can be used in acid solution. The adsorption capacities of S-chitosan can be affected by media acidity. The adsorbed Cu(Ⅱ) Cd(Ⅱ) and Pb(Ⅱ) could be eluted by diluted chlorhydric acid.     

Experimental study of the formation of inverted-V structures and their stratification using AUREOL-3 observations

Multiple inverted-V structures are commonly observed on the same auroral zone crossing by a lowaltitude orbiting satellite. Such structures appear grouped and apparently result from an ionospheric and/or magnetospheric mechanism of stratification. More than two years of AUREOL-3 satellite observations were analyzed to study their properties and their formation in the framework of the ionosphere-magnetosphere coupling model proposed by Tverskoy. This model predicts some natural periodicity in the electrostatic potential profile (and subsequently in the field-aligned current profiles) that could account for oscillations experimentally observed in the auroral zone, such as successive inverted-Vs. Experimental results obtained during quiet or moderately active periods demonstrate that the number of structures observed within a given event is well described by a scaling parameter provided by the hot plasma stratification theory and expressed in terms of the field-aligned current density, the total width of the current band, the plasma sheet ion temperature, and the height-integrated Pedersen conductivity of the ionosphere. The latitudinal width, in the order of 100/200 km at ionospheric altitudes, is relatively independent of the current density, and is determined not only by the existence of a potential difference above the inverted-Vs, but also by basic oscillations of the ionosphere-magnetosphere coupling system predicted by Tverskoy. The large number of cases studied by the AUREOL-3 satellite provides reliable statistical trends which permits the validation of the model and the inference that the multiple structures currently observed can be related directly to oscillations of the magnetospheric potential (or the pressure gradients) on a scale of 1000/2000 km in the near-Earth plasma sheet. These oscillations arise in the Tverskoy model and may naturally result when the initial pressure gradients needed to generate a large-scale field-aligned current have a sufficiently wide equatorial scale, of about 1 R_E or more.     

Cross-field gradients: general concept, importance of multi-spacecraft measurements and study at 1 AU of the source intensity gradient for E>30 keV solar event electrons

Three main physical processes (and associated properties) are currently used to describe the flux and anisotropy time profiles of solar energetic particle events, called SEP profiles. They are (1) the particle scattering (due to magnetic waves), (2) the particle focusing (due to the decrease of the amplitude of the interplanetary magnetic field (IMF) with the radial distance to the Sun) and (3) the finite injection profile at the source. If their features change from one field line to another, i.e. if there is a cross IMF gradient (CFG), then the shape of the SEP profiles will depend, at onset time, on the relative position of the spacecraft to the IMF and might vary significantly on small distance scale (e.g. 10⁶ km). One type of CFG is studied here. It is called intensity CFG and considers variations, at the solar surface, only of the intensity of the event. It is shown here that drops of about two orders of magnitude over distances of 10⁴ km at the Sun (1° of angular distance) can influence dramatically the SEP profiles at 1 AU. This CFG can lead to either an under or overestimation of both the parallel mean free path and of the injection parameters by factor up to, at least, 2/3 and 18, respectively. Multi-spacecraft analysis can be used to identify CFG. Three basic requirements are proposed to identify, from the observation, the type of the CFG being measured.     

A novel high-resolution small ion spectrometer to study ion nucleation of aerosols in ambient indoor and outdoor air

An electrically based ion spectrometer is described, capable of measuring particle sizes and mobilities from molecular ions (small ions) to aerosol particles across a size range of 0.4 to 30 nm in diameter. It consists of a single cylindrical capacitor divided into three electrically insulated sections. The current arriving at the central section is measured by an electrometer and represents the ion flux over a known range of mobilities determined by the applied voltage. The applied voltage is scanned in steps to measure the ion fluxes over a large number of overlapping mobility ranges. The recorded signal and the response function of the instrument are unfolded using a maximum entropy procedure to give a high-resolution measured mobility spectrum. The maximum entropy approach offers a considerable improvement over traditional aspiration collectors and can approach the resolution of a drift tube system. In this way, the spectrometer successfully overcomes the diffusion limit to small ion resolution. Illustrative spectra are shown, demonstrating for the first time the presence of some resolved structure within the small ion spectrum at the highest mobilities. It is demonstrated that the actual mobility spectrum of small ions falls in the range 0.8–2.0 × 10⁻⁴ m² V⁻¹ s⁻¹. This represents a narrower range than that previously measured which is attributed to improved spectral resolution in the present work.     

Preparation and Characterization of Hydroxyiron-Montmorillonite Complexes

Iron elementin soil exists mainly in form s of Fe(OH) 2 ,Fe(OH ) 2 and Fe2 (OH ) 2 2 in tropical and subtropical areaswhere p H values are less than7.These hydroxy- Fe ions reactslowly with montmorillonite by intercalation into their inter-layer space and adsorption on their surfaces,and in this wayvarious hydroxyiron- montmorillonite complexes are formed(Cool and Vansant,1998;Wu et al.,1997;Molinared andClearfield,1994) . Hydroxyiron- montm orillonite complexesare assum ed to have…     

青藏高原中部各拉丹冬峰雪冰记录特征

2005年10~11月在青藏高原唐古拉山脉各拉丹冬峰冰川区不同海拔采集了3个雪坑样品,分析结果表明,雪坑中δ¹⁸O和主要离子浓度具有明显的季节变化特征.夏季风期间降水中δ¹⁸O低于其它季节,表明该地区夏季δ¹⁸O的"降水量效应"仍然存在.雪坑中主要离子在非季风期的浓度高于夏季风期.主要离子的相关分析表明,除NH₄⁺、NO₃^-外,雪坑中其它离子浓度之间均存在较好的正相关性.各拉丹冬峰冰川区仍受到南亚季风的影响,但因其位于夏季风影响的边缘区域,其影响程度相对于高原南部较弱;同时也受到大陆性气候的影响,在冬春季节具有较高的粉尘气溶胶沉降.     

Mobility of major ions and nutrients in the unsaturated zone during paddy cultivation: a field study and solute transport modelling approach

Study of the movement of water and solute within soil profiles is important for a number of reasons. Accumulation of prominent contaminants from agricultural chemicals in the unsaturated zone over the years is a major concern in many parts of the world. As a result, the unsaturated zone has been a subject of great research interest during the past decade. Hence, an intensive field study was conducted in a part of Palar and Cheyyar river basins to understand the variation of major ions and nutrients in the soil zone during paddy cultivation. The chloride and nitrate data were used to model the movement of these chemicals in the unsaturated zone using the HYDRUS‐2D model. The field study shows that fertilizer application and irrigation return flow increases the major ions and nutrients concentration in the unsaturated zone. Further, the nutrient concentrations are regulated by plant uptake, fertilizer application and infiltration rate. Additionally, denitrification and soil mineralization processes also regulate the nitrogen concentration in the unsaturated zone. The solute transport modelling study concluded that the simulated results match reasonably with the observed trends. Simulated concentrations of chloride and nitrate for a 5‐year period indicate that the concentrations of these ions fluctuate in a cyclic manner (from 60 to 68 mg l^?1 and from 3·4 to 3·5 mg l^?1 respectively in groundwater) with no upward and downward trend. The influence of excessive fertilizer application on groundwater was also modelled. The model predicts an increase of about 17 mg l^?1 of chloride and 2·3 mg l^?1 of nitrogen in the groundwater of this area when the application of fertilizers is doubled. The model indicates that the present level of use of agrochemicals is no threat to the groundwater quality. Copyright © 2007 John Wiley & Sons, Ltd.     

Diffusive propagation of fast particles in the presence of a moving shock wave

Based on an analytical model, we determined the temporal dynamics of the spectral shape and spatial distribution of the particles that were impulsively (in time) injected with a specified spectrum in the vicinity of a moving plane shock front. We obtained a condition to determine the influence of the shock front on the particle propagation, where the spatial diffusion coefficient of the particles plays a major role. Diffusive shock acceleration is shown to strongly affect low-energy particles (the intensity maximum coincides spatially with the shock front; hard and soft spectral regions are formed in the spectrum) and weakly affect high-energy particles (the time at which the intensity reaches its maximum is well ahead of the shock arrival time; the spectral shape does not change). In events accompanied by a significant increase in the turbulence level, the influence of the shock front on high-energy particles can change from weak to strong. This change shows up in the spatial distribution and spectral shape of the particles. The dynamics of the particle intensity, calculated with the diffusion coefficients that were determined in accordance with the quasi-linear theory for measured turbulence levels, qualitatively corresponds to the observed solar energetic-particle intensity.