Determination of Incompatible Trace Elements in Mantle Clinopyroxenes by LA-ICP-MS: A Comparison of Analytical Performance with Established Techniques

Incompatible trace element abundances have been determined in mantle-derived clinopyroxenes by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) in a comparative study with established microanalytical and bulk techniques. Individual clinopyroxene grains were sampled for the laser ablation study from sieved mineral separate fractions, from which similar mineral grains had been previously extracted for microprobe (SIMS) and bulk (INAA and ID-TIMS) analysis. Mineral grains were ablated with variable degrees of surface spatial resolution (50-200 μm) in order to maximise ICP-MS analyte count rates and to improve detection limits. A comparison of results from the different techniques reveals that for the most homogeneous samples LA-ICP-MS can achieve excellent levels of agreement with other techniques (10%) and good precision for most of the studied elements (1-5% RSD). Variations in calculated concentrations by LA-ICP-MS confirm inter- and intra-mineral heterogeneity determined by SIMS, reflecting changes in sample composition and texture. The long-term reproducibility of the technique is shown by the consistency of results for one sample analysed on thirteen occasions over a period of nine months.     

Suitability of Mn‐ and Fe‐Rich Reference Materials for Microanalytical Research

Manganese‐ and iron‐rich materials are of major geoscientific and economic interest, many of which contain microscopic features that provide valuable information. To obtain accurate results, a homogeneous microanalytical reference material for calibration is needed. Several researchers have used the Mn‐ and Fe‐rich RMs, JMn‐1, NOD‐A‐1, NOD‐P‐1 and FeMn‐1, for this purpose; therefore, they were tested in this study to determine their suitability for microanalysis. Their homogeneity was investigated by laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) with two different types of lasers (nano‐ and femtosecond), with spot and line scan analyses and with different operating parameters, such as spot size, pulse repetition rate and fluence. As the established manganese nodule RMs revealed inhomogeneities for picogram to microgram test portions, we also investigated the new synthetic Fe‐ and Mn‐rich RM, FeMnOx‐1. FeMnOx‐1 was found to be homogeneous for large (ø 40 μm: 2% RSD repeatability) and small (ø 8–10 μm: 10% RSD repeatability) spot sizes. This homogeneity is in the range of the homogeneous NIST SRM 610 and GSE‐1G reference glasses. Furthermore, FeMnOx‐1 revealed a large‐scale homogeneity within uncertainties of a few per cent, using test portions in the ng range, when measuring four individual mounts of this material.     

An Air‐Cooled,High‐Yield,Compact and Inexpensive Teflon Still for High‐Purity Reagents

Mattinson’s (1972) well‐known simple design of a sub‐boiling still for the preparation of ultra high‐purity reagents consists of two Teflon bottles connected at right angles with one acting as the feed bottle and heated on its upper surface by infrared radiation and the other kept in a cold water bath serving both as the condenser and receiver. Connection of the two bottles in a vertical configuration and replacement of radiative surface heating with conductive bulk heating result in an equally simple and inexpensive still but with a smaller footprint, much larger yield and higher energy efficiency using only ambient air cooling. It can be easily configured for tandem distillation, supply of continuously purified reagent and fractional distillation. Ease and very low cost of fabrication of this still may be of particular interest to many geochemical laboratories requiring up to 500 ml of mineral acids and other common reagents per day.     

An experimental study on variation of b value during deformation of rock samples with different structural models

A preliminary study of b value of rocks with two kinds of structural models has been made on the base of a new acoustic emission recording system. It shows that b value of the sample decreases obviously when the sample with compressive en echelon faults changes into a tensile one after interchange occurs between stress axis σ ₁ and σ ₂. A similar experiment is observed when the sample with tensile en echelon faults changes into that with a bend fault after two segments of the en echelon fault linking up. These facts indicate that the variation of b value may contain the information of the regional dominant structural model. Therefore, b-value analyses could be a new method for studying regional dominant structural models. Foundation item: National Natural Science Foundation of China (Grant No. 40072067) and Minister of Science and Technology of China (2004BA601B01).     

Multi-layer perceptrons with Levenberg-Marquardt training algorithm for suspended sediment concentration prediction and estimation / Prévision et estimation de la concentration en matières en suspension avec des perceptrons multi-couches et l’algorithme d’apprentissage de Levenberg-Marquardt

Abstract

Abstract The prediction and estimation of suspended sediment concentration are investigated by using multi-layer perceptrons (MLP). The fastest MLP training algorithm, that is the Levenberg-Marquardt algorithm, is used for optimization of the network weights for data from two stations on the Tongue River in Montana, USA. The first part of the study deals with prediction and estimation of upstream and down-stream station sediment data, separately, and the second part focuses on the estimation of downstream suspended sediment data by using data from both stations. In each case, the MLP test results are compared to those of generalized regression neural networks (GRNN), radial basis function (RBF) and multi-linear regression (MLR) for the best-input combinations. Based on the comparisons, it was found that the MLP generally gives better suspended sediment concentration estimates than the other neural network techniques and the conventional statistical method (MLR). However, for the estimation of maximum sediment peak, the RBF was mostly found to be better than the MLP and the other techniques. The results also indicate that the RBF and GRNN may provide better performance than the MLP in the estimation of the total sediment load.     

Stream depletion by a pumping well including the effects of nonlinear variation of captured evaporation from a phreatic aquifer / Vidange en cours d’eau par puits de pompage incluant les effets de la variation non-linéaire de l’évaporation capturée d’une nappe à surface libre

Abstract

Abstract A study was made to develop a model that can be used to predict the steady-state stream depletion rates caused by a continuous pumping well located in a water table aquifer. The effects of nonlinear variation of evaporation with the depth to water table on steady-state stream depletion rate were investigated using model results. Dimensional analysis was used to determine the relationship between the scaled steady-state stream depletion, the scaled pumping distance, the scaled hydraulic conductivity, and the scaled initial depth to the water table. A dimensionless graph was developed for a wide range of these parameters. Analysis of this graph showed that the steady-state stream depletion rate decreases as the pumping distance between the well and the stream increases. The dimensionless graph also showed that steady-state stream depletion rates strongly depended on the initial position of the water table. Analysis indicated that, as the saturated conductivity increased, the effect of the initial position of the water table on the magnitude of stream depletion rate was more influential. Analysis also showed that, as the value of saturated conductivity decreased, the relative error produced by the assumption that at steady state all the pumped water is captured from the evaporation, also decreased.     

Uber,Public Transit,and Urban Transportation Equity: A Case Study in New York City

With the explosive growth of Uber and other mobility service providers, their influences on urban mobility have attracted attention from both researchers and policy circles alike, yet few quantitative studies have been conducted on the topic. Using Uber pickup data in New York City in 2014, this article investigates the spatiotemporal relationship between Uber and public transit using buffer analysis and spatial cross-correlation analysis and assesses Uber’s impact on urban transportation equity with the Gini coefficient and correlation analysis. Our results confirm previous arguments that Uber both complements and competes with public transit, but competition is more prevalent in New York City. Specifically, Uber competes with public transit during most hours of the day and in areas with good public transit coverage, whereas it complements public transit at midnight and in places with insufficient public transit services. The distribution of Uber services is highly unequal, and Uber’s role in improving transport equity is insignificant. Correlation analysis shows that there tend to be fewer Uber pickups in low-income areas, which diverges from previous studies suggesting that Uber serves low-income areas well. In addition, a weak negative correlation is detected between the number of Uber pickups and the percentage of minorities.     

Mesures in situ par infiltrométrie des propriétés hydrodynamiques des sols de Mnasra (Maroc)

The aim of this work is the field hydraulic characterisation of Mnasra soils in northern Morocco, which represents an essential step to study the hydraulic and chemical transports through the vadose zone. We have used a tension infiltrometer associated with a transient axisymmetric infiltration method to determine the hydraulic conductivity, which reduces the duration of measurements. This allows us to characterise a large area with many measurements. Parameters of the characteristic functions K(h) and θ(h) are estimated for six different soils belonging to two geomorphologically different domains: a sandy zone and an alluvial plain. To cite this article: K. Tamoh, A. Maslouhi, C. R. Geoscience 336 (2004).     

On the ages of flood basalt events

We review available data constraining the extent, volume, age and duration of all major Phanerozoic continental flood basalts (CFB or traps) and oceanic plateaus (OP), together forming the group of large igneous provinces (LIP), going from the smallest Columbia flood basalts at ～16 Ma to the as yet ill-known remnants of a possible trap at ～360 Ma in eastern Siberia. The 16 traps (CFB and OP) reviewed form a rather unimodal distribution with an initial modal volume of the order of 2.5 Mkm³. Most provinces agree with a rather simple first order model in which volcanism may have lasted of the order of 10 Ma, often resulting in continental break-up, but where most of the volume was erupted in about 1 Ma or sometimes less. This makes CFBs/OPs (LIPs) major geodynamic events, with fluxes exceeding the total output of present day hot spots and even possibly exceeding over short times the entire crustal production of mid-ocean ridges. The proposed correlation between trap ages and the ages of several geological events, including mass extinctions and oceanic anoxia, is found to have improved steadily as more data have become available, to the point that the list of trap ages may coincide with many major divisions in the geological time scale. The four largest mass extinctions in the last 260 Ma coincide to the best resolution available with four traps, making a causal connection between the two through some form of catastrophic climatic perturbations the most likely hypothesis. The time sequence of LIPs appears to have been random and there is no robust evidence for long time trends in the corresponding crustal production rate over the last 260 Ma.     

四川盆地中部主干走滑断裂带及伴生构造特征与演化

根据下—中三叠统嘉陵江组和雷口坡组膏盐岩层内的伴生构造及上震旦统灯影组台缘带被错动的位置、方向与距离,判定川中及北斜坡地区主干走滑断裂带的性质与分布规律。嘉陵江组和雷口坡组膏盐岩层内发育多排呈左阶排列的NW向雁列式构造,与深部(盐下)走滑断裂构成2种伴生组合。第1种组合主要发育在磨溪地区,膏盐岩层内的雁列式构造位于深部走滑断裂的正上方;第2种组合主要发育在北斜坡地区,膏盐岩层内的雁列式构造发育在2条主干走滑断裂带之间。根据这2种组合及灯影组台缘带的错动位置,共识别出6条主干走滑断裂带。在盆地整体演化格架的制约下,通过川中地区代表性生长构造的定量解析,将走滑断裂演化划分为3个阶段:(1)晚奥陶世—志留纪右行走滑阶段;(2)晚古生代—三叠纪走滑断裂沉寂阶段;(3)中侏罗世至今左行走滑阶段。其中,上震旦统灯影组二段台缘带呈现出有规律的向东逐段错动(错动距离20~40 km)的特征,可作为加里东期右行走滑活动的间接证据;川中及北斜坡地区在晚三叠世处于扬子地块北缘和雪峰山前陆盆地前缘隆起的隆后稳定地区,而中侏罗世以来周缘造山带的急剧隆升与差异性演化使得川中地区遭受持续的挤压和抬升,激发了基底断裂与早期走滑断裂的再次活动。