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81.
Jean Servant Georges Kouadio Bernard Cros Robert Delmas 《Journal of Atmospheric Chemistry》1991,12(4):367-380
In the tropical rain forests of the Congo during the dry season, from June to September 1987, carboxylic acid partial pressures (P
gas) in the air above the canopy, at ground level, and at the boundary layer, were estimated from water samples such as fog and rainwater. The concentrations of these acids were also measured in the sap of tree leaves. Tree leaves act as a sink or as a source if the acid P
gas is greater of lower than the acid concentrations in molecular form in sap. For each of these soluble gases, there is a value of P
gas where the exchange is nul. This is called the compensation point. Values of the compensation point for some tree leaves were evaluated according to Henry's law. Henry's law coefficients at ppm levels were redetermined for formic (HCOOH), acetic (CH3COOH), propionic (CH3CH2COOH), and isobutyric (CH3CH(CH3)COOH) acids.By comparison of P
gas and compensation points, it is concluded that the forest was a potential source for these acids. The soil-or the litter-acts as a significant source of a carboxylic acid of C3 or C4 atoms in the aliphatic chain. This carboxylic acid, not yet fully characterized, could play an important role in the rain acidity in forested zones of the equatorial areas.The direct emission of these carboxylic acids by vegetation was the main source in the boundary layer above the forest. The average emissions were 3.1×109, 7.8×109, and 8.4×109 molecules cm-2 s-1 for HCOOH, CH3COOH, and CH3CH2COOH, respectively. The savanna is an exogenous source of HCOOH and CH3CH2COOH during moderately rainy days for 30% of the time. The ozonolysis of isoprene seems to be a small source of HCOOH. 相似文献
82.
小试金光谱法同时测定地质样品中超痕量铂钯金 总被引:9,自引:2,他引:9
用小试金光谱法同时测定地质样品中低至0·x×10~(-9)级Pt、Pd和Au,包括先用小试金熔炼和灰吹预富集10g样品中的Pt、Pd和Au于1mg的银合粒中,然后把银合粒装入石墨电极同锇-锑合金(ω(Os)=0.06)一起激发,以发射光谱法同时测定它们的含量。小试金法类同经典火试金,但采用纯化过的2PbCO_3·Pb(OH)_2(Pt、Pd和Au的含量皆<0.05 ×10~(-9)代替商品PbO,并且用50ml高铝坩埚在950℃进行熔炼。方法的检出限是Pt0.2×10~(-9),Pd和Au均为0.1×10~(-9)。对于3×10~(-9)的含量,全过程的相对标准偏差(%)是Pt15,Pd11,Au9。此法快速、简便,适用于地质物料的分析。 相似文献
83.
84.
We began continuous monitoring of H2 concentration in soil along the San Andreas and Calaveras faults in central California in December 1980, using small H2/O2 fuel-cell sensors. Ten monitoring stations deployed to date have shown that anomalous H2 emissions take place occasionally in addition to diurnal changes. Among the ten sites, the Cienega Winery site has produced data that are characterized by very small diurnal changes, a stable baseline, and remarkably distinct spike-like H2 anomalies since its installation in July 1982. A major peak appeared on 1–10 November 1982, and another on 3 April 1983, and a medium peak on 1 November 1983. The occurrences of these peaks coincided with periods of very low seismicity within a radius of 50 km from the site. In order to methodically assess how these peaks are related to earthquakes, three H2 degassing models were examined. A plausible correlational pattern was obtained by using a model that (1) adopts a hemicircular spreading pattern of H2 along an incipient fracture plane from the hypocenter of an earthquake, (2) relies on the FeO–H2O reaction for H2 generation, and (3) relates the accumulated amount of H2 to the mass of serpentinization of underlying ophiolitic rocks; the mass was tentatively assumed to be proportional to the seismic energy of the earthquake. 相似文献
85.
A. H. Goldstein B. C. Daube J. W. Munger S. C. Wofsy 《Journal of Atmospheric Chemistry》1995,21(1):43-59
A fully automated system measuring C2–C6 hydrocarbon concentrations and vertical gradients was installed at Harvard Forest in Petersham, Massachusetts, using a gas chromatograph with dual flame ionization detectors and cryogenic sample preconcentration. Measurements were made simultaneously at two heights above the forest canopy at forty five minute intervals, continuously from July 1992 to the present. Data for concentration gradients were combined with CO2 flux measured by eddy correlation to determine the rates of production of biogenic hydrocarbons by the forest. 相似文献
86.
Emission rates of biogenic volatile organic compounds emitted by the forests were estimated for five geographical regions as well as for all Switzerland. Monoterpene and isoprene emissions rates were calculated for each main tree species separately using the relevant parameters such as temperature, light intensity and leaf biomass density. Biogenic emissions from the forests were found to be about 23% of the total annual VOC emissions (anthropogenic and biogenic) in Switzerland. The highest emissions are in July and lowest in January. Calculations showed that the coniferous trees are the main sources of the biogenic emissions. The major contribution comes from the Norway spruce (picea abies) forests due to their abundance and high leaf biomass density. Although broad-leaved forests cover 27% of all the forests in Switzerland, their contribution to the biogenic emissions is only 3%. Monoterpenes are the main species emitted, whereas only 3% is released as isoprene. The highest emission rates of biogenic VOC are estimated to be in the region of the Alps which has the largest forest coverage in Switzerland and the major part of these forests consists of Norway spruce. The total annual biogenic VOC emission rate of 87 ktonnes y–1 coming from the forests is significantly higher than those from other studies where calculations were carried out by classifying the forests as deciduous and coniferous. The difference is attributed to the high leaf biomass densities of Norway spruce and fir (abies alba) trees which have a strong effect on the results when speciation of trees is taken into account. Besides the annual rate, emission rates were calculated for a specific period during July 4–6, 1991 when a photochemical smog episode was investigated in the Swiss field experiment POLLUMET. Emission rates estimated for that period agree well with those calculated for July using the average temperatures over the last 10 years. 相似文献
87.
粘滑失稳及其物理场时空分布的实验研究 总被引:6,自引:3,他引:6
摩擦滑动的物理场实验研究表明:(1)能量空间分布的差异是失稳的重要条件,单发型大事件常发生于高能量向低能量的突变带或高能量背景区内的相对低能量区;(2)单发型大事件的孕育过程常常经历若干个能量输入输出循环,产生多个前兆阶段,并在失稳前源区常有一个弱化过程。小震或群发型事件失稳前常常只有一个能量积累与强化的过程,失稳前兆阶段性反映较差;(3)粘滑失稳时断层的位错与声发射的大小未见明显关系 相似文献
88.
89.
90.
Séverine Bernardie Jean-Pascal Gilbert François Lebert Hubert Fabriol 《Pure and Applied Geophysics》2007,164(1):177-197
The monitoring of the stability of old mines constitutes an important research objective for our institution, BRGM. The study
reported here shows the contribution of high-frequency (>30 kHz) acoustic emissions to the detection of the damage within
a rock mass, during an experiment within a pilot site of an old flooded iron mine. The experiment consisted of recording all
the hydroacoustic events in a broad frequency band (between 30 Hz and 180 kHz), during 18 months. The monitoring network has
been calibrated by a triggered block fall that made it possible to highlight a relationship between the occurrence of high-frequency/low-frequency
hydroacoustic emissions and rock falls. The events recorded have been associated with the micro-failure of the rock mass near
the roof, prior to the detachment of the blocks. This monitoring showed important high-frequency hydroacoustic activity, which
may be associated with mechanical instabilities generated by the evolution of water pressure during the experiment. In conclusion,
the high-frequency hydroacoustic activity appears to be a good indicator of instability and, therefore, this new technique
constitutes a promising tool for monitoring abandoned underground cavities. 相似文献