油页岩成矿作用研究中的关键方法和技术

油页岩作为一种重要的非常规油气资源,如何有效地利用油页岩成矿作用研究中的关键方法和技术实现油页岩的综合识别与评价极其重要。油页岩识别的关键技术主要包括基于岩石学的地质识别、精确的地球化学指标识别、测井技术的垂向高分辨率快速识别和地震技术的三维空间定量刻画。先进的测试技术、创新的理论方法以及高品质地球物理资料的二次开发利用将不断提升油页岩从定性到定量预测识别的精度。油页岩成矿作用研究的关键方法是从古构造条件、古气候条件、古地理条件以及古湖泊环境等地质因素入手,探讨其综合作用下有机质来源、保存条件及成岩作用的变化,由定性向半定量—定量地精细刻画油页岩中有机质聚集过程,从而有效地预测油页岩的展布及其富集规律。由于文中材料以中国陆相含油页岩盆地的研究成果为主,而陆相成因油页岩的识别特征及成因机制可能与海相等成因存在差异,因此,仍需油页岩地质学家不断深入研究与总结。希望此文对页岩油、页岩气及烃源岩研究也具有一定的借鉴意义。     

Multi-scale Characteristics and Comprehensive Evaluation of Precipitation Heterogeneity in Guangxi

Aiming at the uneven spatial and temporal distribution of precipitation and frequent occurrence of drought and waterlogging disasters in Guangxi, the multi-scale characteristics and comprehensive evaluation of precipitation heterogeneity can provide scientific support for regional response to drought and waterlogging disasters and intelligent management of water resources. Based on the daily precipitation data of 87 grid points from 1961 to 2017 in Guangxi, the Precipitation Concentration Degree (PCD) and Precipitation Concentration Period (PCP) index were used to build day, pentad, ten days, month, season precipitation heterogeneity of multiple time scale level evaluation system. By using R/S analysis and geographical spatial analysis methods, the space-time evolution characteristics and climate division in Guangxi were discussed. The study showed that the spatial and temporal variation characteristics of PCD and PCP at the diurnal, synoptic and monthly scales were relatively consistent, and the heterogeneity of precipitation in Guangxi could be better expressed than that at the monthly and seasonal scales. The diachronic change of PCD in precipitation in Guangxi shows an increasing trend in northeast China and a decreasing trend in southwest China, and the trend of its future period is the same as the diachronic evolution. The spatial distribution of PCD in Guangxi has significant spatial autocorrelation and stratification heterogeneity, which are mainly reflected in the mean value, coefficient of variation and frequency of PCD. The comprehensive heterogeneity of precipitation in Guangxi is highly dispersed in the northeast, highly concentrated in the south, and slightly concentrated or dispersed in the northwest and central regions. The time-scale within a month is the best scale to express the non-uniformity of precipitation in Guangxi. If the advantages of more stable climatic and ten-day scales and more fine daily scales are taken into account, the use of climatic scale for daily sliding calculation and analysis will be the best way.     

某Cr(Ⅵ)污染场地修复的PRB反应材料及结构设计研究

渗透反应格栅(permeable reactive barrier,PRB)在国外被广泛应用于场地尺度的地下水污染修复,因其无须外源动力、不占地面空间、运行成本低等优势在国内受到广泛关注。不同场地水文地质条件、污染物类型、污染羽分布具有差异性,前期场地调查、反应材料的筛选、反应墙尺寸结构的设计对于PRB的有效运行至关重要。本文以PRB修复河南某Cr(Ⅵ)污染场地为例,详细阐述场地调查、材料筛选、材料反应参数确定、PRB结构优化等方面的研究过程及成果,可为后续PRB修复技术的应用提供参考。研究结果表明:PRB修复技术适用于该场地,铸铁与活性炭混合材料为最佳修复材料;反应门长40 m(反应材料厚2 m,上下游分别为2 m厚砾石层),东西两侧隔水墙长为60 m的U型漏斗-门系统型PRB,可有效捕获并修复污染羽,工程成本远低于连续反应墙式PRB,为该场地修复最优PRB结构类型。     

基于砂箱物理模拟的断层封闭有效性评价新方法

泥岩涂抹的连续性影响油气跨断层运移,在相似岩性、相似应力条件下,泥岩厚度和断距长度是影响泥岩涂抹连续性的主要因素.本文结合岩芯观察,借助三维定量物理模拟实验对泥岩涂抹的连续有效性进行了研究.结果表明:①泥岩有效涂抹是决定断层封闭性的必要条件,涂抹连续厚度是封闭性评价的重要参数;②受剪切作用在断层带中形成连续的泥岩涂抹油...     

鲁西南邵庄-双庙水源地地下水环境质量现状评价

按照单项组分、综合评价法,对邵庄-双庙水源地第四系孔隙水和寒武-奥陶系岩溶水环境质量现状进行了评价。第四系孔隙水,总体上,以京杭运河为界,运河以西水质较差,运河以东地区、邵庄、双庙水源地所在地段水质较好;蜀山背斜岩溶水系统内大多地段岩溶水水质较好,邵庄水源地岩溶水水质良好,其它地段及双庙地垒岩溶水系统岩溶地下水质量普遍较差。     

金沙江白格滑坡残留体稳定性分析与防治对策

金沙江白格滑坡在经历了2018年10月和11月的2次滑动堵江后,在其后缘仍存在K1、K2和K3等3处规模较大的残留崩滑体,并有再次失稳堵江的可能。目前关于残留体稳定性的研究还存在较大争议,多从影响因素及成因机制等方面进行定性分析,其结果依赖于评价者的经验,差异较大。在野外调查的基础上,针对白格滑坡所在区工程地质条件及其残留体变形特征,选取坡高、坡度、坡面形态、临空面、地下水出露、裂缝发育和变形等7个因素作为评价因子,基于模糊综合评判模型,运用层次分析法对白格滑坡残留体进行分区稳定性评价,并提出相应的防治对策。评价结果表明:K1与K2残留体稳定性较差;K3残留体基本稳定,与实际调查状况较吻合。研究结果可为同类型滑坡的评价与防治提供参考。     

Chemical Procedures for Rhenium Extraction from Geological Samples: Optimising the Anion Resin Bead Clean‐up Step

Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices.     

基于层次分析法和模糊数学相结合的甘肃东乡八丹沟泥石流易发性评价

八丹沟位于甘肃东乡县,近年来多次发生泥石流,对流域内居民生命财产造成了巨大的威胁,因此对八丹沟泥石流易发性评价是非常必要的。本文在详细分析八丹沟流域特征和动力学特征的基础上,选取了11个评价因子作为八丹沟泥石流易发性评价的指标,利用层次分析法对各个因子赋予权重,并且构建模糊数学综合评价模型对八丹沟泥石流进行易发性评价。结果表明:八丹沟泥石流爆发频率20年、50年、100年的的易发性为中易发,应加强防范并采取合理的防治措施,保证当地居民的生命财产安全。     

页岩储层可压裂性影响因素及评价方法

可压裂性是页岩在水力压裂中具有能够被有效压裂的能力的性质,是页岩开发中最关键的评价参数,影响因素包括页岩脆性、天然裂缝、石英含量、成岩作用及其他因素,目前常利用页岩矿物组成或岩石力学参数来表征,难以全面反映页岩在水力压裂过程中的综合性质。采用极差变换和经验赋值方法将参数标准化,使用层次分析法确定不同因数对可压裂性影响的权重,使用标准化值与权重系数加权得到可压裂系数的数学模型可对页岩可压裂性进行定量评价。可压裂系数越大,页岩可压裂性越强。采用该模型计算渝东南地区渝页1井龙马溪组页岩可压裂系数为0.485 5,Barnett页岩可压裂系数为0.484 4,总体处于同一水平;同时,使用该模型将页岩可压裂性分为3个级别,可压裂系数在0.132 0~0.282 0的页岩可压裂性低,水力压裂效果不佳;可压裂系数在0.282 0~0.456 7的页岩可压裂性中等,水力压裂能够取得较好的效果;可压裂系数在0.456 7~0.784 0的页岩可压裂性高,是优质的可压裂层。水力压裂应选择可压裂系数大于0.360 7的页岩。     

川藏公路巴塘至拉萨段典型地质灾害危险性分析

川藏公路巴塘至拉萨段沿线边坡地质灾害较为严重.根据多年来采集的边坡灾害数据, 利用地理信息系统(GIS)综合插值等多种方法分析了该段公路沿线典型边坡地质灾害的危险性. 研究表明: 低度、中度、高度危险区占总里程的78.9%, 总长度1 008 km, 其中高度达到30.28%, 而基本无危险区里程为270 km, 占总里程的21.1%. 通过野外复核, 该分析结果较为合理可靠.