High Frequency Current Fluctuations and Cross-shelf Flows around the Pycnocline near the Shelf Break in the East China Sea

Relation between internal waves with short time scale and density distribution near the shelf break in the East China Sea is studied utilizing moored current meters, thermometers and conductivity-temperature-depth (CTD) casts. A well developed pycnocline was frequently observed around 150–200 m depth near the shelf break accompanied with the development of internal waves with short time scale. During the cruise in May 1998, the intensified internal wave motion with short time scale and the distinct offshore flow were observed just below the lower pycnocline, which shoaled and extended above the shelf area. It is suggested that vertical mixing generated by amplified internal waves would produce cross-shelf ageostophic density current around the pycnocline. During the cruise in May 1999, on the other hand, the lower pycnocline was located offshore below the shelf break, and the internal wave motion was amplified just above the lower pycnocline. In this case, the offshore flow should be generated above the lower pycnocline, but vertical profiles of current velocity were not obtained because acoustic Doppler current profiler (ADCP) data were not available around the lower pycnocline.     

Determination of cadmium(II), copper(II), manganese(II) and nickel(II) species in Antarctic seawater with complexing resins

The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log α_M(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 10²⁰ M^− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log α_M(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations.     

Atmospheric Correction of SeaWiFS Data for the Retrieval of Suspended Sediment in East China Coastal Waters

The data of SeaWiFS (Sea-Viewing Wide Field-of-View Sensor), installed on SeaStar, has been used to generate SSC (suspended sediment concentration) of complex and turbid coastal waters in China. In view of the problems of the SeaDAS (SeaWiFS Data Analysis System) algorithm applied to China coastal waters, a new atmospheric correction algorithm is discussed, developed, and used for the SSC of East China coastal waters. The advantages of the new algorithm are described through the comparison of the restdts from different algorithms.     

南海西部表层沉积物钙质浮游生物分布与碳酸盐溶解

对南海西部300多个表层沉积样品中的浮游有孔虫和钙质超微化石定量分析表明，几乎所有样品均含浮游有孔虫、钙质超微化石，但丰度相差十分悬殊，浮游有孔虫丰度介于0．5～36673个／g之间，钙质超微化石丰度为0～1725个／10个视域，两者的分布规律相似。在陆坡区钙质浮游生物最富集，尤其在西沙群岛西南、南沙西部礁滩附近海区丰度最高；向深海盆区和陆架浅水区，钙质浮游生物丰度均下降。但从两者的丰度分布来看，其溶解程度不同，浮游有孔虫更容易溶解，在200～2000m水深区，丰度最高，2000m以下丰度锐减；而钙质超微化石的最富集区在500～3000m，且3000m以下仍较丰富。从碳酸盐的分布来看，本区碳酸盐的临界补偿深度(CCrD)为3500m，而CCD大于4300m，碳酸盐的溶解主要由有孔虫和钙质超微化石构成。     

南海东北部末次冰期以来的沉积环境演变

利用南海东北部上陆坡处所取的D孔柱样进行硅藻分析,结合粒度与碎屑矿物分析结果,探讨该海域末次冰期以来沉积环境演变过程.结果表明：粒度与硅藻分析结果较为吻合,共同显示D孔柱样可分为上下两层.上表层（0～2 cm）的砂质沉积层为冰后期海进过程改造的晚更新世残留沉积层,即变余沉积;下层（2～130 cm）主要是末次冰期形成的浅海沉积.整个柱样可反映出海洋同位素MIS 4期海退至MIS 3期海进与MIS 2期海退至冰后期海进的沉积变化韵律.     

人工神经网络方法反演东中国海悬移质浓度

海中悬移质是决定海洋光学性质、海洋水质,河口海岸带演变动力过程的重要环境参数。本文利用模拟遥感反射比数据集建立人工神经网络反演悬移质浓度,并利用东中国海现场同步数据对该算法进行验证。     

冬季东中国海环流中的中尺度涡旋数值模拟

采用高精度的POM模式 ,考虑了海底地形、外来流、长江径流、海面风应力、海面热通量等多方面因素的影响 ,模拟了冬季东中国海环流结构。模拟结果显示 :在黄海东部很可能存在两个涡 ,中心分别在124°37′E ,37°N ,124°E ,35°30′N ;东海北部存在一个大型的气旋式涡旋 ,其中心位置在125.1°E ,30.5°N附近 ,该涡旋是由东北向的台湾暖流、西北向的黄海暖流及南下的沿岸流组成的封闭结构 ;日本九州以西黑潮入侵分支形成一涡旋 ,黑潮分支是形成此涡旋的直接动力因素 ,另外地形和冬季盛行的偏北风也对该涡旋的形成有一定正面影响。     

南海北部陆缘地壳结构探测结果分析

深部地震和重力资料反演揭示了南海北部陆缘地壳结构在总体上由北部的华南沿海（厚约30km）向南部的洋盆（5──8km）逐渐减薄。南海的近SN向拉张不仅造成南北方向地壳结构的巨大变化，也造成东西向的明显变化。在南海北部陆缘的西部，局部拉张产生了一系列裂谷构造。西沙海槽作为一条狭窄的陆内裂谷向西延伸，海槽南北两侧地壳厚度超过25km，海槽中部地壳减薄至不足10km。西端的莺歌海盆地地壳厚仅5km，缺少明显的壳内反射－折射。在珠江口盆地中部，地壳厚度在下陆坡明显减薄，地壳下部存在较薄的（3──4km）高速层（地震波速7．2──7．5km·s－1）；在珠江口盆地东部，地壳底部存在约 10km厚、300km宽的高速层。在台湾地区，由于弧陆碰撞，曾经减薄的陆壳在碰撞带增厚，莫霍面深度超过30km。南海北部陆缘在裂谷拉张和海底扩张期间岩浆活动平静，表明南海北部陆缘为非火山型陆缘。     

南海北缘东部盆地油气资源研究

南海北缘东部的珠江口盆地及台西南盆地蕴藏着十分丰富的油气资源，根据区域构造背景、盆地发育分布的特点及中、新生代的油气地质条件，结合含油气构造、油气田、油气井的分布规律，利用油气资源评价的理论、方法，对区内的油气资源进行了综合研究，并按照油气资源状况划分出油气富集区、油气潜力区、油气远景区，在此基础上，再进一步划分出4条油气富集带、11条油气潜力带、8条油气远景带，充分显示了该区石油、天然气的分布规律和油气地质特点，为商业性的勘探开发和理论研究奠定了基础。     

Modelling linear wave transformation induced by dissipative structures—Random waves

The relevant theory is presented and numerical results are compared with the analytical solution for the interaction of non-breaking waves with an array of vertical porous circular cylinders on a horizontal bed. The extension to the cases of unidirectional and multidirectional waves is obtained by means of a transfer function. The influence of the mechanical properties of porous structures and wave irregularity on wave transformation is analysed. Results for unidirectional and multidirectional wave spectra are compared to those obtained for regular waves. The model presented reproduces well the analytical results and provides a tool for analysing several engineering problems.