砂土液化中颗粒分析试验试剂用量标准的研究

采用不同剂量的六偏磷酸钠试剂，对GB／T50123—1999《土工试验方法标准》中的密度计法(甲种密度计)做颗粒分析试验的结果进行对比分析^[1]，由此对4％六偏磷酸钠溶液用量与分析结果的关系以及10m1的标准用量进行验证与探讨。     

First-principles investigation of the concentration effect on equilibrium fractionation of Ca isotopes in forsterite

Previous theoretical studies have found that the concentration variations within a certain range have a prominent effect on inter-mineral equilibrium isotope fractionation(10^3 lna).Based on the density functional theory,we investigated how the average Ca–O bond length and the reduced partition function ratios(10^3 lnb)and103lna of 44 Ca/40 Ca in forsterite(Fo)are affected by its Ca concentration.Our results show that Ca–O bond length in forsterite ranges from 2.327 to 2.267 A with the Ca/(Ca+Mg)varying between a narrow range limited by an upper limit of 1/8 and a lower limit of 1/64.However,outside this narrow range,i.e.,Ca/(Ca+Mg)is lower than1/64 or higher than 1/8,Ca–O bond length becomes insensitive to Ca concentration and maintains to be a constant.Because the 10^3 lnb is negatively correlated with Ca–O bond length,the 10^3lnb significantly increases with decreasing Ca/(Ca+Mg)when 1/64相似文献   

毒品贸易与国家主权破碎：基于缅甸北部的政治地理学分析

与中国云南省接壤的缅甸北部少数民族自治邦,包括掸邦和克钦邦,构成全球第二大非法毒品生产地的金三角核心区。通过借助历史档案和学术文献,聚焦缅甸北部,基于政治地理的视角,理清缅甸北部毒品贸易的历史起源,探讨了自缅甸1948年独立后毒品贸易给该国带来的政治与经济危机,以及相应的地缘政治冲突和外部干预。文章试图回答的问题有：为什么毒品贸易能够在缅北扎根?毒品贸易如何影响缅甸政府在其北部山区的主权完整和领土控制?文章的核心观点是毒品成为缅甸国内破碎主权和外部势力干预的原因和结果,毒品贸易以及与毒品相关的犯罪活动已经渗入缅北,严重危害了缅甸的主权完整。毒品贸易也为外部势力介入缅甸国内事务提供了契机。由于主体民族缅族控制的中央政府同缅北的少数民族地方武装间缺乏足够的信任,民族和解缺乏基础,也无法为全面禁毒创造有利的政治条件。因而,缅北的毒品贸易和缅甸的国家建设相互影响,导致国家主权破碎化和外部干预,导致缅北成为亚洲最贫穷落后的地区。文章分析以毒品为核心的开源权力机制与非正式或者非法全球化,丰富了Agnew有关主权的理论,在实践方面有助于认识中缅边境安全的复杂性,促进云南同东南亚的跨国区域化。     

Amphiphilic sodium alginate-vinyl acetate microparticles for drug delivery

To overcome the fast or burst release of hydrophilic drugs from hydrophilic alginate-based carriers,hydrophobic molecule(vinyl acetate,VAc)was grafted on alginate(Alg),which was further used to prepare drug carriers.Amphiphilic Alg-g-PVAc hydrogel beads were firstly prepared by emulsification/internal gelation technique for the loading of bovine serum albumin(BSA).Then,chitosan was coated on the surface of beads to form novel amphiphilic Alg-g-PVAc/chitosan(Alg-g-PVAc/CS)microcapsules.The BSA-loading amphiphilic Alg-g-PVAc/chitosan(Alg-g-PVAc/CS)microcapsules display similar morphology and size to the hydrophilic alginate/chitosan(AC)microcapsules.However,the drug loading and loading efficiency of BSA in Alg-g-PVAc/CS microcapsules are higher,and the release rate of BSA from Alg-g-PVAc/CS microcapsules is slower.The results demonstrate that the introduction of hydrophobic PVAc on alginate can effectively help retard the release of BSA,and the higher degree of substitution is,the slower the release rate is.In addition,the complex membrane can also be adjusted to delay the release of BSA.As a whole,amphiphilic sodium alginate-vinyl acetate/CS microparticles could be developed for macromolecular drug delivery.     

微观尺度下毒品犯罪时空分布及成因分析——以SZ市NH、DM街道为例

毒品犯罪是全球共同关注的犯罪问题,许多学者从不同的专业领域开展了大量研究。已有文献对毒品犯罪的成因进行分析,由于数据的局限性,较少从微观尺度对毒品犯罪热点的时空分布进行研究。论文以SZ市NH、DM街道内社区为例,基于毒品犯罪案件数据,利用探索性数据分析和时空扫描识别毒品犯罪时空热点分布,结合用地类型、动态人流量等数据定量分析毒品犯罪案件的时空分布影响因素。研究结果如下：① 毒品犯罪主要分布在商业发达地区和城中村地区,且城中村的毒品犯罪时空热点分布的起始时间较商业发达地区更早,影响范围也更大;② 毒品犯罪在不同用地类型分布是不均匀的,其中“住宿旅游娱乐”“商业百货批发零售”“餐饮经营服务品牌”3类用地类型与毒品犯罪具有高度相关性;③ 人流量高热区的面积占比与毒品犯罪的发生有一定的相关性,高热区面积占比大于5%或为0时,能够抑制毒品犯罪的发生;高热区面积占比在0~5%之间,能够促进毒品犯罪的发生。     

中国红树林资源状况及其药用调查 Ⅲ.民间药用与药物研究状况

对中国红树植物药用状况和研究现状进行了调查.结果表明,中国共有红树植物20科37种,已发现具有药用价值的有23种,民间药用的红树植物主要有13种.已经有26种红树植物涉及到了化学成分的研究,其中木榄、秋茄、老鼠勒、榄李、海漆、木果楝、桐花树、白骨壤和玉蕊等研究较多.主要化合物结构类型包括二萜、三萜、甾体、黄酮、木脂素和生物碱等,显示抗菌、抗肿瘤、拒食、酶抑制、降压等多种生物活性,具有较高的药物开发应用价值.     

A multi-method approach for the identification and quantification of water balance components of two lentic small water bodies

The protection of the globally widespread lentic small water bodies (LSWB) must be based on detailed knowledge about their hydrological connectivity and water balance. The study aimed to identify and quantify water balance components as well as surface-groundwater interaction of two LSWB in a characteristic lowland region with a combination of different methods. This includes the collection of hydrological data and the use of bromide and water stable isotopes (δ²H and δ¹⁸O) as tracers. With their help, mixing models were established, and daily water balances were assessed. The results show a strong bidirectional interaction of both LSWB systems with shallow groundwater. Bromide and stable isotope tracers allowed for the identification of the most relevant in- and outflow sources and pathways. Thereby, isotope data revealed isotopic enrichment typical for open-water bodies and only minor precipitation inputs mainly relevant at the end of the dry season. Water balance calculations suggested accentuated seasonal dynamics that were strongly influenced by shallow groundwater, which represented large inputs into both LSWB. By that, different phases could be identified, with high inflow rates in winter and spring and decreasing fluxes in summer. In one LSWB, a drainage system was found to have a major impact next to the shallow groundwater interaction. The findings of this research provide detailed insights into the influence and importance of shallow groundwater for LSWB in lowland regions. This impacts the diffuse input of agricultural pollutants into these ecologically important landscape features.     

Forbidden transition probabilities of astrophysical interest among low-lying states of V III

Electric and magnetic multipole transitions among low-lying states of doubly ionized vanadium were computed using the multi-configuration Hartree-Fock (MCHF) method with Breit-Pauli (BP) corrections to a non-relativistic Hamiltonian. Energy levels were determined up to and including 3d ²(¹ G)4s b ² G _7/2 and computed energies were found to be in good agreement with experiment and other theories. In addition to Einstein A _ki coefficients for some E2 and M1 transitions, lifetime data and selected weighted oscillator strengths are also reported.     

High-pressure properties of diaspore,AlO(OH)

The structural compression mechanism and compressibility of diaspore, AlO(OH), were investigated by in situ single-crystal synchrotron X-ray diffraction at pressures up to 7 GPa using the diamond-anvil cell technique. Complementary density functional theory based model calculations at pressures up to 40 GPa revealed additional information on the pressure-dependence of the hydrogen-bond geometry and the vibrational properties of diaspore. A fit of a second-order Birch–Murnaghan equation of state to the p–V data resulted in the bulk modulus B ₀ = 150(3) GPa and B ₀ = 150.9(4) GPa for the experimental and theoretical data, respectively, while a fit of a third-order Birch–Murnaghan equation of state resulted in B ₀ = 143.7(9) GPa with its pressure derivative B′ = 4.4(6) for the theoretical data. The compression is anisotropic, with the a-axis being most compressible. The compression of the crystal structure proceeds mainly by bond shortening, and particularly by compression of the hydrogen bond, which crosses the channels of the crystal structure in the (001) plane, in a direction nearly parallel to the a-axis, and hence is responsible for the pronounced compression of this axis. While the hydrogen bond strength increases with pressure, a symmetrisation is not reached in the investigated pressure range up to 40 GPa and does not seem likely to occur in diaspore even at higher pressures. The stretching frequencies of the O–H bond decrease approximately linearly with increasing pressure, and therefore also with increasing O–H bond length and decreasing hydrogen bond length. Electronic Supplementary Material The online version of this article () contains supplementary material, which is available to authorized users.