水中氯代烃单体碳同位素分析中预富集方法进展

高精度准确测定氯代烃单体碳同位素对示踪污染物来源,了解污染物的生物降解过程具有重要意义。在环境转化过程中,有机污染物的同位素组成可能是稳定不变的,也有可能发生改变。若污染物的同位素组成在迁移转化过程中不变,根据其同位素组成可以示踪污染物的来源;若同位素组成变化,根据同位素分馏结果,可以评价环境中有机污染物降解发生的可能性和程度。本文综述了固相微萃取、静态顶空进样、吹扫-捕集、多级串联技术等前处理方法与气相色谱-燃烧-同位素比值质谱仪(GC-C-IRMS)联用分析水中氯代烃单体碳同位素的研究进展,比较了分析方法的优缺点。液-液萃取较少用于水中氯代烃的单体同位素分析。静态顶空进样、固相微萃取、吹扫-捕集都是无溶剂富集技术,与GC-C-IRMS联用分析水中氯代烃单体同位素过程中不存在或存在小且恒定的可校正的同位素分馏,分析精度一般优于1‰,没有二次污染,降低了杂质干扰,提高了GC-C-IRMS的分辨率和分析精度,降低了检测限。从静态顶空进样、固相微萃取、吹扫-捕集,到多级串联等技术与GC-C-IRMS联用分析水中氯代烃单体同位素比值,检测限逐渐降低。目前,吹扫-捕集-GC-C-IRMS在分析水中氯代烃中应用最广泛,重现性好、检测限低。针内微萃取、管内微萃取、搅动棒吸附萃取和顶空进样吸附萃取等前处理方法与GC-C-IRMS仪联用具有一定的应用前景。     

气侯时间序列变点的推断

本文研究时间序列的变点问题。所给出的统计方法可用来推断一个时间序列是否存在变点，存在几个变点以及变点在什么位置。这种统计推断方法可用于气候阶段的划分。     

唐山7.8级地震前地磁异常的综合分析

利用昌黎等台的磁测资料,并用多种方法进行综合分析,结果显示,在震前出现了约3个月的短期异常,这对于地震的预测预报有一定意义。     

浅水波长计算问题

浅水波周期保持常值,而波长缩减时其计算需进行迭代。提出了两个精度较高的经验公式供计算应用。水深波长比差值ΔLD0的变化规律反映出浅水波长缩减为一复杂过程,并与波能密度加大相关。LD0≤0.14时,特别是LD0=0.056前后,其特征会更加显著,由此可探讨波长变化的内在机理。     

Application of flocculation combined with vacuum preloading to reduce river-dredged sludge

Abstract

To achieve the rapid dewatering of dredged sludge, the flocculation–vacuum-preloading method was tested indoors. In this study, the optimal mixing ratio of six flocculants was determined through the settling column test, and then the proposed method was tested. The water drainage and settlement were monitored during the test, while the soil moisture content and shear strength were measured after the test. The results show that all the flocculants had an optimal mixing ratio, and the addition of 0.8% FeCl₃ or 0.08% anionic polyacrylamide (APAM) in the sludge can better accelerate solid–liquid separation of the sludge. After the test, the water content in the sludge decreased from 140% to 60%. Compared with general vacuum preloading, the use of the proposed method increased the water drainage by 46.5% and 56.8% and decreased the soil volumes by 60.5% and 82.4% for FeCl₃ and APAM, respectively. Moreover, the corresponding shear strength was increased from 10 to 14 and 17?kPa. In addition, the use of APAM increased the solidification rate of heavy metals in the sludge to more than 80%, effectively inhibiting the migration of heavy metals.     

Base cation concentrations in forest litter and topsoil have different responses to climate and tree species along elevational gradients

The forest litter is an essential reservoir of nutrients in forests, supplying a large part of absorbable base cations(BC) to topsoil, and facilitating plant growth within litter-soil system. To characterize elevational patterns of base cation concentrations in the forest litter and topsoil, and explore the effects of climate and tree species, we measured microclimate and collected the forest litter and topsoil(0-10 cm) samples across an elevational range of more than 2000 m(1243 ～ 3316 m a.s.l.),and analyzed the concentrations of BC in laboratory. Results showed that: 1) litter Ca concentration displayed a hump-shaped pattern along the elevational gradients, but litter K and Mg showed saddle-shaped patterns. Soil Ca concentration increased with elevation, while soil K and Mg had no significant changes. 2) Ca concentration in the forest litter under aspen(Populus davidiana) was significantly higher than that in all other species, but in topsoil, Ca concentration was higher under coniferous larch and fir(Larix chinensis and Abies fargesii). Litter K and Mg concentrations was higher under coniferous larch and fir, whereas there were nosignificant differences among tree species in the concentrations of K and Mg in topsoil. 3) Climatic factors including mean annual temperature(MAT), growing season precipitation(GSP) and non-growing season precipitation(NGSP) determined BC concentrations in the forest litter and topsoil. Soil C/N and C/P also influenced BC cycling between litter and soil. Observation along elevations within different tree species implies that above-ground tree species can redistribute below-ground cations, and this process is profoundly impacted by climate. Litter and soil Ca, K and Mg with different responses to environmental variables depend on their soluble capacity and mobile ability.     

不同开口比人工鱼礁体水动力特性及礁体稳定性研究

为研究方型人工鱼礁体开口比的变化对其水动力特性的影响,利用Fluent软件模拟了边长为3m、开口比为0～0.6之间7种不同方型鱼礁体周围水流场,通过分析水流场变化规律得到了礁体流场效应、阻力系数随开口比的变化情况;基于Morison方程计算了礁体在波流作用下的受力及其抗滑移、抗倾覆安全系数。研究结果表明:当礁体开口比小于0.2时,背涡区范围较大,流场效应明显;随着开口比的增大,礁体产生的上升流范围及竖直向最大速度分量逐渐减小;对于方形开口礁体,阻力系数与开口比的关系式为Cd=0.875φ+1.088(R2=0.963,P<0.01);随着开口比的增大,礁体所受最大波流作用力、抗滑移及抗倾覆安全系数逐渐减小,但礁体不会发生滑移和倾覆,可为实际礁体结构的设计提供参考。     

高精度高性价比的GPS定向仪的设计

介绍了一种高精度、高性价比的GPS定位定向仪的设计及实现（〈1mil,2σ）方法,系统利用了实际应用中的有利约束条件,对基于LAMBDA方法的载波相位整周模糊度解算算法进行了改进,经过系统工程设计,在实际应用中实现了单频、高精度、快速定向数据的输出。可以满足绝大多数环境下的使用需求,大大降低了系统成本。     

GPS现代化后L2C的信号质量分析

分析了L2C码的主要作用,比较了GPS现代化后L2载波信噪比的变化特点,阐述了伪距观测值的噪声水平。     

基于边缘分析的海面溢油检测

提出一种基于边缘检测的快速溢油信息提取方法, 首先对溢油图像进行ROA(radio of average)边缘检测, 根据检测结果进行AOI(area of interest)提取, 然后使用改进的Weibull-CFAR检测算法对AOI进行溢油检测, 并与全局CFAR检测结果进行对比。实验结果证明, 所提出的方法对于非均匀灰度SAR图像溢油检测准确性较好、效率较高, 特别适用于大图像的快速溢油检测。