近50年来长江口及邻近海域溶解氧的时空分布变化

长江口及邻近海域是我国最重要的河口海岸区域之一。基于多源、长时间序列的溶解氧资料,本文对近50年来长江口及邻近海域溶解氧的时空分布特征进行了研究。结果表明,近50年来,长江口及邻近海域表层溶解氧基本保持稳定,仅冬季呈现出一定的上升趋势。冬、春两季溶解氧浓度范围在7-11 mg/L,夏、秋两季为6-8 mg/L。长江口及邻近海域低氧值首先出现于5月,浙闽沿岸底层海域形成低氧水舌。水舌在夏季不断向北推进,北部断面低氧程度明显高于南部断面。到了秋季,低氧区逐渐消退,至冬季完全消失。在过去的50年中,长江口及邻近海域的低氧现象始于20世纪80年代。2000年起,低氧程度逐渐加深,低氧分布深度逐渐升高。本文基于大量的溶解氧历史数据开展研究,研究结论对于探讨长江口及邻近海域低氧区的发展变化具有非常重要的意义。     

海洋牧场溶解氧生态模型初探

文中利用黄海沿岸威海小石岛海洋牧场2016年6-11月份和荣成西霞口海洋牧场2016年6-10月份海洋牧场海底观测网实时高频温、盐、深、溶解氧、叶绿素浓度等水环境数据对牧场的海底环境进行季节变化分析和日变化分析,并利用自由水域假设建立溶解氧生态模型,对两个牧场的生态系统新陈代谢参数进行计算并分析,得到其GPP,R和NEP的月变化趋势,并结合实测溶解氧数据和海底视频,对生态系统稳定性较差的西霞口海洋牧场进行合理建议。研究还发现对于这两个浅水动物养殖型海洋牧场,物理过程对溶解氧变化的贡献和生物过程相当。     

试谈排污交易削减非点源污染

主要介绍采用排污交易的方法削减非点源污染的实施方法、条件及其应用,重点讨论了太湖磷污染的削减对策,并进行了效益评估,认为排污交易是解决太湖富营养化问题的有效方法之一.     

C18 Sep-Pak Extractable Dissolved Organic Copper Related to Hydrochemistry in the North-west Mediterranean

Extractable organic copper using C18 Sep-Pak cartridges was investigated in seawater after laboratory experiment showed that the (C18 Sep-Pak) cartridges were reliable, in open and coastal waters with normal levels of dissolved organic carbon, for the separation of a specific fraction of organo-copper complexes.Given that the Sep-Pak cartridges retain the hydrophobic fraction of the dissolved organic matter, this extraction technique was applied for studying the characteristics of this particular hydrophobic dissolved organic copper fraction (hDOCu) in the north-western Mediterranean waters. Surface distribution of hDOC is influenced by organic matter input from the river Rhone and its estuary as well as the physical processes affecting the primary productivity such as coastal upwelling. By correlating hDOCu concentrations with total dissolved copper and other hydrochemical data such as salinity and dissolved organic carbon, it was possible to examine the behaviour of hDOCu in the water masses of different sources and ages.Marine organic matter has been shown to have high complexing capacity. Productive superficial and intermediate waters as well as deep waters showed relatively high and comparable complexing capacity indicating that old organic matter may have strong complexing sites.     

Transitional, entraining, cloudy, and coastal boundary layers

Atmospheric boundary layers are marvelously varied and complex. Recent research has examined some of that variety. Boundary layers over land undergo drastic changes throughout the day as the sun rises and sets, and as clouds form and dissipate. Air is entrained at the top of the boundary layer at varying rates. As air moves over the coast, the boundary layer reacts to changes in surface forcing. All of these changes affect pollutant transport and weather formation. In this paper, research attempting to understand transitional, cloud-topped, and coastal boundary layers, and boundary-layer top entrainment, is reviewed.     

Attenuation of UVR and PAR in a clear and deep lake: Spatial distribution and affecting factors

Light attenuation is considered as a sentinel for environmental change in lakes and has a profound influence on aquatic ecosystems. However, the spatial distribution of ultraviolet radiation (UVR) and photosynthetically active radiation (PAR) attenuation, and the underlying mechanisms are still not fully understood. We carried out a field investigation with 60 sampling sites covering the entire Lake Qiandaohu from November 29 to December 1, 2013, during the weak stratification period to elucidate the spatial pattern and driving mechanisms. The diffuse attenuation coefficient of UVB (K_d(313)), UVA (K_d(340)) and PAR (K_d(PAR)) varied from 1.48 to 4.63 m⁻¹, 1.09 to 3.43 m⁻¹, and 0.26 to 0.94 m⁻¹, respectively. The corresponding ranges for the 1% attenuation depths were from 0.10 to 3.11 m, 1.34–4.21 m and 4.87–17.58 m, respectively. Total suspended matter (TSM) concentration was highly significantly correlated with K_d(313), K_d(340) and K_d(PAR) indicating that TSM was the main driver of UVR and PAR attenuation in Lake Qiandaohu in the late autumn and early winter. TSM concentration, K_d(313), K_d(340) and K_d(PAR) had obvious horizontal spatial heterogeneity presenting a decreasing trend from the estuary area to the center area in the lake. These results suggested that the spatial distribution of TSM from the inflow drived the spatial distribution of UVR and PAR attenuation. Significantly positive correlations were also observed between the chromophoric dissolved organic matter (CDOM) absorption coefficient and K_d(313). TSM and CDOM absorption spectra showed that in the UVR waveband (350–400 nm), the mean relative contribution rates of CDOM (a_g(λ)), non-algal particles (a_nap(λ)), phytoplankton (a_ph(λ)) and pure water (a_w(λ)) to the total absorption were 67.5 %, 24.0 %, 5.0 % and 3.5 %, respectively. In the PAR waveband, the mean relative contribution rates of a_g(λ), a_nap(λ), a_ph(λ) and a_w(λ) to the total absorption were 25.4 %, 18.6 %, 9.4 % and 46.6 %, respectively. Our findings could provide support for ecological environment protection in Lake Qiandaohu considering the importance of UVR and PAR attenuation in aquatic ecosystems.     

Forecasting Air Quality Indicators for 33 Cities in China

The Jing‐Jin‐Ji (Beijing‐Tianjin‐Hebei) and the surrounding Jin‐Lu‐Yu (Shanxi‐Shandong‐Henan) regions are experiencing severe problems with air pollution. To measure the change in pollutant concentrations over the next few years, the fractional order accumulation grey model is used to forecast the air quality indicators. The results show that the concentrations of fine particulate matter, particulate matter 10, and sulfur dioxide show a downward trend, and 8‐h O₃ (annual) and 8‐h O₃ (spring and summer) show an upward trend in these areas. There is a slight increase in nitrogen dioxide concentration in Shanxi, but its concentration in other areas shows a slight decline. The results obtained can provide a clear direction for air quality management decisions.     

长江流域水库"过滤器效应"对入海溶解硅通量的影响

根据1960-2000年间长江大通水文站记录的水、沙以及硅、氮、磷等数据,结合1954-2006年间长江流域库容大于10⁸ m³的162座水库的库容、上游径流量、总磷等数据,利用Vollenweider模型分析了水库"过滤器效应"对入海溶解硅(DSi)通量的影响.结果表明:1)1990s相比1960s,长江入海DSi通量下降了约1.85×10⁶ t/a,减少了大约25.3%;入海DSi通量的下降与流域径流波动、入海悬沙通量下降以及溶解无机氮通量的增加紧密相关.2)流域水库明显改变径流的自然过程,增加径流的滞留时间,流域90%以上的水库对上游径流的滞留时间超过0.05年,水库产生显著的DSi"生物过滤器"效应.模型计算显示流域大型水库对DSi的累计滞留量可达0.85×10⁶ t/a,占年均入海DSi通量(1990-2000年)5.4×10⁶ t的15.7%,是入海DSi通量减少量(1.85×10⁶ t/a)的45.9%.3)根据保守估计,流域162座大型水库内泥沙累计淤积量达6.75×10⁸ t/a,不仅使悬沙入海通量显著下降,而且造成大量颗粒吸附的外源和内源DSi颗粒沉淀,这对入海DSi通量减少也起到重要贡献.但目前对水库"泥沙过滤器"的滞留机理并不清楚,需要展开进一步的研究.     

氡钍分析仪水氡观测最佳工作状态

中国水氡观测历经50余年,观测仪器老化严重。2011年至今分别引入新生产的3批次64套FD-125型氡钍分析仪。经过仪器测试、地震台站运行以及多次现场实验,发现:该仪器定标器阈值不应按照地震水文地球化学观测技术规范选定的2 V,需选择0.7 V甚至更低阈值,才能保证测值的可靠稳定,保障水氡观测继续发挥防灾减灾作用。     

太湖3种优势微囊藻对不同形态磷的吸收利用

微囊藻(Microcystis)是最常见的淡水水华蓝藻,它们对磷营养盐的竞争力是其成为优势种的最主要影响因素.本文以太湖水华中的3种优势微囊藻(Microcystis flos-aquae,Microcystis wesenbergii和Microcystis aeruginosa)为材料,比较研究了它们对正磷酸盐(K₂HPO₄)、三聚磷酸盐(Na₅P₃O₁₀)、小分子溶解态有机磷(葡萄糖-6-磷酸,G-6-P)和大分子溶解态有机磷(卵磷脂)的吸收和利用能力.结果发现,3种微囊藻对4种磷形态有明显的嗜好.当磷浓度为0.2 mg/L时,M. flosaquae只在正磷酸盐下生长最快,M. wesenbergii在三聚磷酸盐和大、小分子有机磷下生长最快,M. aeruginosa在所有磷形态下生长都最慢.而当磷浓度为2.0 mg/L时,M. flos-aquae在所有形态磷下生长都最快.在2种磷浓度下M. wesenbergii都表现出最高的溶解态无机磷比例和光合活性F_v/F_m.以上结果说明,3种藻在磷形态利用方面存在明显的互补性差异,即低磷浓度下M. wesenbergii适宜利用的磷形态更多,高磷浓度下M. flos-aquae适宜利用的磷形态更多,而不论磷浓度高低,M. aeruginosa对4种形态磷的适应性最差.由此可知,可利用磷形态的丰富性只是部分优势微囊藻的竞争策略.