秋季胶州湾有色溶解有机物荧光特性研究及其来源分析

利用三维荧光光谱(EEMs)-平行因子分析(PARAFAC)技术研究了秋季胶州湾有色溶解有机物(CDOM)的荧光成分组成、分布特征及来源。PARAFAC模型解析出胶州湾CDOM由2类5个荧光组分组成,即类腐殖质成分C1(355nm/430nm)、C2(320nm/390nm)、C3(380nm/465nm)、C4(420(330)nm/505nm)及类蛋白质成分C5(280/325nm)。类腐殖质成分C1、C2、C3和C4的平面分布模式基本一致,呈现由近岸海域向湾中心海域逐渐减小的趋势,而类蛋白质成分C5则是由湾东北部近岸海域向西南部海域呈逐渐减小的趋势。分析表明,秋季胶州湾CDOM类腐殖质成分C1、C2、C3和C4的主要来源为陆源输入,而类蛋白质成分C5主要受城市排污的影响。系统聚类分析表明,以团岛南端和红岛西侧连线为界,所有采样站位被分为两类,分界线西部区域站位CDOM各荧光成分相对含量分别为C1:31.8%~35.5%,C2:30.3%~33.7%,C3:17.1%~20.2%,C4:4.5%~5.2%,C5:9.6%~12.5%;分界线东部区域站位CDOM各荧光成分相对含量分别为C1:30.6%~34.6%,C2:28.8%~32.7%,C3:17.0%~19.1%,C4:3.3%~4.8%,C5:12.1%~18.2%。西部区域CDOM具有较高的C4含量和较低的C5含量,大沽河等河流的陆源输入特征明显,而东部区域CDOM则具有较高的C5含量和较低的C4含量,反映该区域受城市排污影响显著。另外,秋季胶州湾CDOM的HIX范围为1.8~3.2之间,较小的腐殖化因子值反映了秋季胶州湾CDOM的腐殖化程度高较低,在环境中存在时间较短。     

东海表层水体中的多环芳烃及其沉积通量估算

以东海陆架水体中溶解态多环芳烃(PAHs)含量为基础,引入颗粒相-水相间的物质吸附系数(Koc)计算悬浮颗粒物中PAHs有机碳归一化含量,结合陆架沉积物有机碳的年埋藏通量,估算东海陆架沉积物中PAHs沉积通量。结果显示:水体中溶解态的15种PAHs总含量为(701±392)ng/L,变化范围为412~1 032ng/L,PAHs组成以3环为主。计算得到的悬浮颗粒物中15种PAHs有机碳归一化含量为20~28μg/g,对应的PAHs沉积通量为150~210t/a。估算结果与实测沉积物中PAHs含量和沉积通量结果基本吻合,表明实验室模拟实验获取的化合物Koc值适用于东海颗粒相-水相间的分配模型,证实悬浮颗粒物有机碳含量在控制PAHs两相分布过程中起着重要作用。同时,该方法为海洋沉积物中PAHs沉积通量的估算提供一种新途径。     

Seasonal dynamics of light absorption by chromophoric dissolved organic matter (CDOM) in the NW Mediterranean Sea (BOUSSOLE site)

We analyze a two-year time-series of chromophoric dissolved organic matter (CDOM) light absorption measurements in the upper 400 m of the water column at the BOUSSOLE site in the NW Mediterranean Sea. The seasonal dynamics of the CDOM light absorption coefficients at 440 nm (a_cdom(440)) is essentially characterized by (i) subsurface maxima forming in spring and progressively reinforcing throughout summer, (ii) impoverishment in the surface layer throughout summer and (iii) vertical homogeneity in winter. Seasonal variations of the spectral dependence of CDOM absorption, as described by the exponential slope value (S_cdom), are characterized by highest values in summer and autumn at the surface and low values at the depths of a_cdom(440) subsurface maxima or just below them. Variations of a_cdom(440) are likely controlled by microbial digestion of phytoplankton cells, which leads to CDOM production, and by photochemical destruction (photobleaching), which leads to CDOM degradation. Photobleaching is also the main driver of S_cdom variations. Consistently with previous observations, a_cdom(440) for a given chlorophyll a concentration is higher than expected from Case I waters bio-optical models. The total non-water light absorption budget shows that surface waters at the BOUSSOLE site are largely dominated by CDOM during all seasons but the algal bloom in March and April. These results improve the knowledge of CDOM absorption dynamics in the Mediterranean Sea, which is scarcely documented. In addition, they open the way to improved algorithms for the retrieval of CDOM absorption from field or satellite radiometric measurements.     

广西北仑河口红树林保护区表层海水溶解态重金属时空分布及其影响因素

根据2013年5月(春季)和8月(夏季)对广西北仑河口红树林保护区的现场调查监测数据,研究了表层海水中溶解态重金属Cu、Zn、Pb、Cd、Cr、As、Hg的时空分布特征,探讨了其影响因素,并对其污染水平进行了评价。结果表明,表层海水各溶解态重金属的浓度、空间波动程度在春、夏季均存在一定的差异;Hg的污染明显超过国家一类海水水质标准,且夏季污染水平高于春季。Cu-Zn、Cu-Cd、Zn-Pb、Zn-Cd之间存在显著正相关,春、夏季As以及夏季Cr分别与盐度之间呈显著正相关,其他重金属与盐度之间无显著相关性。各重金属的时空分布主要受到陆源输入、沿岸江河冲淡水和海水盐度变化等因素的影响。     

Isotopic Composition of Dissolved Carbonates Meromictic Soda Lake Doroninskoe(Eastern Transbaikalia,Russia)

正1 Introduction Meromictic soda Lake Doroninskoe localized in the intermountain area,filled with continental sediments of the Mesozoic,in the upper basin of the river Amur.Coordinates of its location are N51°14'42"E112°14'40",     

环青海湖地下水溶解性碳的时空变化特征

区域地下水溶解性碳的时空变化特征研究对于认识区域物质循环和能量传递及推动区域生态可持续发展具有重要意义。本研究在青海湖流域冻结期和融化期分别收集了地下水、河水和湖水样品,研究了环青海湖地下水在冻结期和融化期的溶解性碳特征,并探究了不同类型地下水的溶解性碳特征及其对不同冻融时期的响应,最后揭示了环湖区域不同水体的溶解性碳的差异特征及影响因素。结果表明：冻结期地下水、河水和湖水的溶解性无机碳（DIC）均相对高于融化期,溶解性有机碳（DOC）均相对低于融化期。地下水、河水和湖水的溶解性碳均主要以DIC为主,DIC在溶解性碳的占比高达92%。地下水的DIC平均含量在基岩裂隙水、水量中等和浅埋藏的水文地质条件下相对较高,DOC平均含量在基岩裂隙水、水量丰富和浅埋藏的水文地质条件下相对较高。地下水的DIC在湖滨平原砂砾石层、淤泥质砂层潜水和水量中等的水文地质条件下受冻融期影响较大,DOC在基岩裂隙水和水量贫乏的水文地质条件下受冻融期影响较大。湖水的DIC和DOC均远高于河水和地下水。河水的DIC在融化期和冻结期均低于地下水,DOC在融化期高于地下水,在冻结期低于地下水。     

A 24 h investigation of the hydrogeochemistry of baseflow and stormwater in an urban area impacted by mining: Butte,Montana

Changes in water quality during a storm event were continuously monitored over a 24 h period at a single location along an urban stormwater drain in Butte, Montana. The Butte Metro Storm Drain (MSD) collects groundwater baseflow and stormwater draining Butte Hill, a densely populated site that has been severely impacted by 130 years of mining, milling, and smelting of copper‐rich, polymetallic mineral deposits. On the afternoon of 26 June 2002, a heavy thunderstorm caused streamflow in the MSD to increase 100‐fold, from 0·2 ft³ s⁻¹ to more than 20 ft³ s⁻¹. Hourly discharge and water quality data were collected before, during, and following the storm. The most significant finding was that the calculated loads (grams per hour) of both dissolved and particulate copper passing down the MSD increased more than 100‐fold in the first hour following the storm, and remained elevated over baseline conditions for the remainder of the study period. Other metals, such as zinc, cadmium, and manganese, showed a decrease in load from pre‐storm to post‐storm conditions. In addition to the large flush of copper, loads of soluble phosphorus increased during the storm, whereas dissolved oxygen dropped to low levels (<2 mg l⁻¹). These results show that infrequent storm events in Butte have the potential to generate large volumes of runoff that exceed Montana water quality standards for acute exposure of aquatic life to copper, as well as depressed levels of dissolved oxygen. This study has important implications to ongoing reclamation activities in the upper Clark Fork Superfund site, particularly with respect to management of storm flow, and may be applicable to other watersheds impacted by mining activities. Copyright © 2005 John Wiley & Sons, Ltd.     

DISSOLVED AND PARTICULATE ORGANIC CARBON IN YANTAI SISHILI BAY AQUICULTURE WATERS

Investigation of dissolved organic carbon (DOC) and particulate organic carbon (POC) at 12 stations in Yantal Sishili Bay in May, August, and November of 1997 and March and May of 1998 showed that DOC concentrations varied from 1.14 mg/L to 5.35 mg/L; that the average values at all staticrLs ineach entise varied from 1.52 mg/L to 2.12 mg/L; that POC concentrafions varied from 0.049 mg/L to 1.411mg/L; and averaged 0.159 mg/L to 0.631 mg/L in each cruise. Horizontal distribution of DOC was influ-enced by factors such as continental input, organism activity, temperature, aquieulture environment, etc. The higher POC concentration occurred along the coast. The vertical distribution of DOC and POC changed obviously in spring and summer, but not obviously in autumn and winter. DOC concentration was highest in summer and POC in spring; both were lowest in winter. The seasonal change of DOC was con-sistent with primary productivity seasonal variation, and that of POC was consistent with ehlorophyll-a sea-sanal variation. The seasonal change trend of the C/N ratio of dissolved organic matter was obvious, but the C/N ratio of particulate organic matter had no such trend.     

Kinematic wave solutions for pollutant transport over an infiltrating plane with finite‐period mixing and mixing zone

Kinematic wave solutions are derived for transport of a conservative non‐point‐source pollutant during a rainfall‐runoff event over an infiltrating plane for two cases: (i) finite‐period mixing and (ii) soil‐mixing zone. Rainfall is assumed to be steady, uniform and finite in duration, and it is assumed to have zero concentration of pollutants. Infiltration is assumed constant in time and space. Prior to the start of rainfall, the pollutant is distributed uniformly over the plane. In the first case, when rainfall occurs, the mixing of pollutant in the runoff water occurs in a finite period of time. In the second case, the chemical concentration is assumed to be a linearly decreasing function of rainfall intensity and overland flow. The solute concentration and discharge are found to depend on the flow characteristics as well as the solute concentration parameters. The characteristics of solute concentration and discharge graphs seem to be similar to those reported in the literature and observed in laboratory experiments. Copyright © 2002 John Wiley & Sons, Ltd.     

Continuous fluorescence assessment of organic matter variability on the Bournbrook River,Birmingham, UK

Continuous monitoring of dissolved organic matter (DOM) character and concentration at hourly resolution is rare, despite the importance of analysing organic matter variability at high‐temporal resolution to evaluate river carbon budgeting, river water health by detecting episodic pollution and to determine short‐term variations in chemical and ecological function. The authors report a 2‐week experiment performed on DOM sampled from Bournbrook, Birmingham, UK, an urban river for which spectrophotometric (fluorescence, absorbance), physiochemical (dissolved organic carbon [DOC], electrical conductivity, pH) and isotopic (D/H) parameters have been measured at hourly frequency. Our results show that the river had sub‐daily variations in both organic matter concentration and characteristics. In particular, after relatively high‐magnitude precipitation events, organic carbon concentration increased, with an associated increase in intensity of both humic‐like and tryptophan‐like fluorescence. D/H isotopic ratio demonstrates different hydrological responses to different rainfall events, and organic matter character reflects this difference. Events with precipitation < 2 mm typically yielded isotopically heavy water with relatively hydrophilic DOM and relatively low specific absorbance. Events with precipitation > 2 mm had isotopically lighter water with higher specific absorbance and a decrease in the proportion of microbially derived to humic‐like fluorescence. In our heavily urbanized catchment, we interpret these signals as one where riverine DOM is dominated by storm sewer‐derived ‘old’ organic matter at low‐rainfall amounts and a mixed signal at high‐precipitation amounts where ‘event’ surface runoff‐derived organic matter dominate during storm sewer and combined sewer overflow routed DOM. Copyright © 2009 John Wiley & Sons, Ltd.