圆盘固相萃取富集-气相色谱法测定地表水中有机氯和有机磷农药

采用环境友好的圆盘固相萃取新技术富集水体中有机氯农药和有机磷农药,分别用微池电子捕获检测器(μECD)和火焰光度检测器(FPD)气相色谱法检测,实现了水中有机氯和有机磷农药残留物的测定。结果表明,16种有机氯农药的平均回收率为64.7%~102%,精密度(RSD,n=6)为2.9%~15%;13种有机磷农药的平均回收率为65.9%~104%,精密度(RSD,n=6)为1.7%~17%。方法快速、灵敏、低污染,可用于水体中多种有机氯农药和有机磷农药的残留分析。     

Using Sequential Self-Calibration Method to Identify Conductivity Distribution: Conditioning on Tracer Test data

An iterative inverse method, the sequential self-calibration method, is developed for mapping spatial distribution of a hydraulic conductivity field by conditioning on nonreactive tracer breakthrough curves. A streamline-based, semi-analytical simulator is adopted to simulate solute transport in a heterogeneous aquifer. The simulation is used as the forward modeling step. In this study, the hydraulic conductivity is assumed to be a deterministic or random variable. Within the framework of the streamline-based simulator, the efficient semi-analytical method is used to calculate sensitivity coefficients of the solute concentration with respect to the hydraulic conductivity variation. The calculated sensitivities account for spatial correlations between the solute concentration and parameters. The performance of the inverse method is assessed by two synthetic tracer tests conducted in an aquifer with a distinct spatial pattern of heterogeneity. The study results indicate that the developed iterative inverse method is able to identify and reproduce the large-scale heterogeneity pattern of the aquifer given appropriate observation wells in these synthetic cases.     

岩石破坏前后曲线分类及脆-延转换围压研究——蚀变岩常规三轴压缩试验Ⅰ

蚀变岩是工程中少见的软弱岩类,在西南某重大水电工程中,蚀变岩处于工程的重要部位,为保证工程的长期稳定性,对蚀变岩力学特性进行了深入全面的试验研究.通过对孔隙度不同的饱水蚀变岩进行系统的常规三轴压缩试验和总结分析,提出了蚀变岩三轴压缩下破坏前应力.应变曲线可分为3大类,破坏后应力-应变曲线亦可分为3大类的形态模式.并得出结论:蚀变岩的破坏类型受围压与孔隙度的共同影响,在给定的12 MPa围压下蚀变岩以脆性破坏为主,只有孔隙度大于16%且围压大于4 MPa时才有可能进入脆-延转换状态,且脆-延转换围压随孔隙度增加而降低,临界状态应力比随孔隙度增大而增加.     

原状非饱和黄土的三轴试验研究

利用特制的非饱和土三轴仪器,对不同含水量条件下原状非饱和黄土的强度和土-水特征曲线进行了试验研究。试验结果表明：非饱和黄土的抗剪强度随着含水量的不同而不同,含水量越大,非饱和黄土的基质吸力就越小,抗剪强度亦越小。含水量趋于饱和时,非饱和黄土的抗剪强度值逐渐接近于饱和黄土的强度值。原状非饱和黄土的抗剪强度均高于饱和黄土的抗剪强度。非饱和黄土的内摩擦角受含水量的影响不大。凝聚力受含水量的影响很大,含水率越大,基质吸力越小,总凝聚力越小。根据实验结果,提出了非饱和土的抗剪强度模型,该模型易于确定,与实测基本吻合,误差较小,满足非饱和黄土的强度计算要求。     

粉煤灰湿陷变形的三轴试验和计算

采用双压力室三轴仪对粉煤灰试样进行了单线法湿陷试验,研究了在静水压力作用以及在不同应力状态和应力水平下粉煤灰湿陷变形的规律,得出了粉煤灰湿陷变形的经验计算公式.提出了计算粉煤灰地基湿陷变形的"全应变曲线"增量有限元法.基于本文的试验结果,对一个粉煤灰地基的湿陷变形进行了有限元计算.     

Accumulation and speciation of selenium in evaporation basins in California,USA

The accumulation of selenium in evaporation basins (or ponds) in the San Joaquin Valley, California is of a great concern due to its potential hazards to environments. In this study, the accumulation, speciation and concentrations of Se were examined in waters as well as sediments in a system of the evaporation ponds. A significant decrease in the total dissolved Se concentration in Cell 1 in which drainage water with higher Se concentration was pumped from Inlet Channels indicated that the immobilization of Se was active in the Cell 1 and resulted in the higher Se concentration in sediments compared to the terminal cell such as Cell 9. The percentage of reduced Se species such as selenite [Se(IV)] and org-Se of total Se in drainage waters was also found increased in Cell 1 compared to Inlet Channels. The total dissolved Se concentrations in water along flow paths from Cell 1 were relatively constant except for terminal cells such as Cells 9 and 10, which showed higher total dissolved Se concentrations due to evapoconcentration. The percentage of reduced Se forms of total Se was inversely proportional to the percentage of Se(VI) depending on the redox condition of evaporation ponds along the flow paths. Sequential extractions of Se species in sediments indicated that organic associated Se and elemental Se were prevalent forms in sediments in the ponds system. The higher concentrations of elemental Se and organic associated Se in sediments in Cell 1 indicated that the immobilization of Se was active in the sediments compared to Cell 9, while the percentage of both fractions of total Se in sediments in Cells 1 and 9 was relatively constant. The organic materials from algae might provide carbon sources for Se reduction and Se sink in sediments in its elemental and organic associated forms.     

柴达木盆地自然伽玛曲线记录的古气候变化对太阳辐射响应关系的对比研究

采用柴达木盆地达参1井自然伽玛(GR)曲线,建立了2 85MaBP以来的轨道调谐时标.对GR曲线、深海记录和黄土记录与太阳辐射曲线时频域的多维谱分析及奇异谱分析结果表明:达参1井GR曲线相对于太阳辐射的滞后时间短于深海及黄土记录3～4ka,GR曲线记录的岁差周期成分更为显著,且与太阳辐射在岁差周期上显示了更强的相关性.表明盆地古气候演化受到太阳辐射岁差周期强烈影响,具有低纬陆地记录的特征,而与深海记录和黄土记录受轨道倾斜周期和全球冰量变化的重要影响有别.     

表面波谱分析影响因素研究

基于理论分析及数值计算,研究了频率分辨率、反射波等对谱分析影响,结果表明：频率分辨率会影响相位差曲线及相位差折迭数量;与振源相对的场地沟槽反射的瑞利波或分层界面的反射体波会使测点信号功率谱估计及计算的相速度-波长曲线出现扰动。通过细化技术及干扰信号切除方法可提高相速度计算精度。在低频域相位差折迭数无法统计时,用优化分析方法可以估计可能损失折迭数或额外多余的折迭数。     

陆域冻土区地震探测信号提取技术——以青海哈拉湖地区为例

青海哈拉湖地区的陆域冻土区天然气水合物,其埋藏深度较浅,地震有效信号往往被干扰波淹没,如何从复杂的地震波场里有效提取出与地层、水合物有关的地震反射信号是开展地震资料精细解释和天然气水合物预测工作的前提.为此,详细分析青海哈拉湖地区地震探测原始数据,总结该地区干扰噪声的类型及特点,制定地震信号提取流程,并在叠前道集上逐步采用有针对性的噪声衰减、振幅补偿、反褶积以及叠加等处理技术,压制各类干扰信息,最大程度地保留有效反射信号,提高地震资料的分辨率、信噪比和保真度,更好地为地震资料解释和有利储层预测服务.