Contrasting water–rock interaction behaviors of antimony and arsenic in contaminated rivers around an antimony mine,Hunan Province,China

Although antimony (Sb) and arsenic (As) exhibit similar geochemical behavior and toxicity in the environment, growing evidence suggests that their water–rock interaction behavior in contaminated rivers is quite different. Twenty-nine river water samples were collected between September and November 2018 from contaminated rivers around an antimony mine in Hunan Province, China. The concentrations of As and Sb were inversely proportional to the water flow distance. The rates and magnitudes of Sb decrease were more prominent than those of As. Silicate mineral dissolution from rocks such as silicified limestone increased the As and Sb concentration of in-mine-district (IMD) water. Dissolution of carbonate minerals, ion exchange, and competitive adsorption were the major water–rock interactions, resulting in rapidly decreasing As and Sb concentration in IMD direct impacted water and IMD indirect impacted water. The behaviors of As and Sb during water–rock interaction were dissimilar for areas dominated by carbonate and silicate minerals.     

Southern high latitude climate anomalies associated with the Indian Ocean dipole mode

1 INTRODUCTION In southern high latitudes, recent observations have shown a standing mode of ACW (Antarctic Circumpolar Wave) with eastward propagation across the Southern Ocean of the Antarctic in co- varying SST (sea surface temperature) and SLP (sea le…     

与西澳州西南部冬季降水相联系的大气环流特征分析

西澳大利亚州西南部(SWWA)是西澳大利亚州首府Perth的所在地,也是西澳州政治、经济、文化、教育和旅游的中心.自20世纪中期以来,SWWA地区雨季降水持续减少.本文利用近60年的观测及再分析数据,分析了已知的影响澳大利亚降水的热带海洋模态:厄尔尼诺—南方涛动(ENSO)、印度洋偶极子(IOD)和ENSOModoki...     

Damping coefficients for soil–structure systems and evaluation of FEMA 440 subjected to pulse-like near-fault earthquakes

In this study, attempts are made to investigate the effects of inertial soil–structure interaction (SSI) on damping coefficients subjected to pulse-like near-fault ground motions. To this end, a suit of 91 pulse-like near-fault ground motions is adopted. The soil and superstructure are idealized employing cone model and single-degree-of-freedom (SDOF) oscillator, respectively. The results demonstrate that soil flexibility reduces and amplifies the damping coefficients for structural viscous damping levels higher and lower than 5%, respectively. The coefficients reach one for both acceleration and displacement responses in cases of dominant SSI effects. The effect of structure dimensions on damping confidents are found insignificant. Moreover, damping coefficients of displacement responses are higher than those of acceleration responses for both fixed-base and flexible-base systems. Evaluation of damping correction factor introduced by FEMA 440 shows its inefficiency to predict acceleration response of soil–structure systems under pulse-like near-fault ground motions. Soil flexibility makes the damping correction factor of moderate earthquakes more pronounced and a distinctive peak value is reported for cases with dominant SSI effects.     

鄂尔多斯盆地靖边油田沙洼沟地区延安组延9油藏富集规律

基于储层基本特征、油藏分布及类型研究,利用基本成藏地质条件与油藏分布相叠合的方法,总结靖边沙洼沟延9油藏的油气富集规律。研究结果表明,研究区延9储层属于中孔–低渗储层,延9油藏类型为构造–岩性油藏,延9油藏的分布和富集受多因素控制,其中侏罗系古地貌对油藏的控制起先导作用,深切河谷为油气运移提供重要通道,有利相带和鼻状隆起构造为油气成藏提供了有利场所,隔层的发育状况及有效的生储盖组合控制了油藏纵向分布层位和规模。综合分析认为,在泥岩隔层不发育、分支河道砂体与构造隆起叠置部位是油气富集区,为勘探的重点部位。     

Arc magmatism in the Delhi Fold Belt: SHRIMP U–Pb zircon ages of granitoids and implications for Neoproterozoic convergent margin tectonics in NW India

The northwestern region of Peninsular India preserves important records of Precambrian plate tectonics and the role of Indian continent within Proterozoic supercontinents. In this study, we report precise SHRIMP zircon U–Pb ages from granitoids from the Sirohi terrane located along the western fringe of the Delhi Fold Belt in Rajasthan, NW India. The data reveal a range of Neoproterozoic ages from plagiogranite of Peshua, foliated granite of Devala, and porphyritic granite of Sai with zircon crystallization from magmas at 1015 ± 4.4 Ma, 966.5 ± 3.5 and 808 ± 3.1 respectively. The plagiogranite shows high SiO₂, Na₂O and extremely low K₂O, Rb, Ba, comparable with typical oceanic plagiogranites. These rocks possess low LREE and HREE concentrations and a relatively flat LREE–HREE slope, a well-developed negative Eu-anomaly and conspicuous Nb and Ti anomalies. Compared to the plagiogranite, the foliated Devala granite shows higher SiO₂ and moderate Na₂O, together with high K₂O and comparatively higher Rb, Ba, Sr and REE, with steep REE profiles and a weak positive Eu anomaly. In contrast to the plagiogranite and foliated granite, the porphrytic Sai granite has comparatively lower SiO₂ moderately higher Na₂O, extremely high Y, Zr, Nb and elevated REE. The geochemical features of the granitoids [HFSE depletion and LILE enrichment, Nb- and Ta-negative anomalies], and their plots in the fields of Volcanic Arc Granites and those from active continental margins in tectonic discrimination diagrams suggest widespread Neoproterozoic arc magmatism with changing magma chemistry in a protracted subduction realm. Our results offer important insights into a long-lived active continental margin in NW India during early and mid Neoproterozoic, consistent with recent similar observations on Cryogenian magmatic arcs widely distributed along the margins of the East African Orogen, and challenge some of the alternate models which link the magmatism to extensional tectonics associated with Rodinia supercontinent breakup.     

A filtering approach for estimating lake water quality from remote sensing data

In this paper we consider the estimation of lake water quality constituent distributions from hyperspectral remote sensing data. We present a computational approach that can be used to assimilate information from mathematical evolution models into data processing. The method is based on a reduced order iterated extended Kalman filter, and a convection–diffusion model is used to describe the movement of the water quality constituents. The performance of the technique is evaluated in a simulation study. The results show that the filter approach with an appropriate evolution model yields estimates that have better spatial and temporal resolutions than those obtained with conventional methods. Furthermore, the use of a feasible evolution model may make it possible to obtain information also on the concentrations in the lower parts of the lake.     

Cenozoic paleo-environmental evolution of the Pamir–Tien Shan convergence zone

The retreat of the Tethys Sea and the uplift of the Tibetan Plateau play the critical roles in driving Asian climatic changes during the Cenozoic. In the Pamir–Tien Shan convergence zone, over 3000 m of Cenozoic successions, consisting of marine deposits in the lower, continental clay and fine sand in the middle, and molasse in the upper part, record the evolution of the Tethys Sea, the Asian aridification, and the deformation of the Pamir. In this work, the existing biostratigraphic subdivisions and new electronic spinning resonance dating results were used to assign ages to formations within the Ulugqat section. Sedimentary facies analysis and multi-proxy indices were used to reconstruct the paleo-environmental evolution. The results show: (1) the Pamir–Tien Shan convergence zone has undergone progressive environmental changes from shallow marine before ∼34 Ma to arid land at ∼23 Ma and finally to inter-mountain basin by ∼5.3 Ma; (2) the overall increase in mean size of grains, decrease in redness, in magnetic susceptibility, and in proportion of the ultrafine component of the sediments studied revealed a long-term strengthening in potential energy to transporting medium, cooling, and enhanced continental aridity, respectively; (3) the easternmost edge of the Tethys Sea prevailed in the western Tarim Basin from late Cretaceous to early Cenozoic, and finally retreated from this region around the Eocene–Oligocene transition, which in turn strengthened the Asian aridification; (4) accumulation of molasse with an upper age of ∼1 Ma suggests that the deformation front of the Pamir migrated to this area at or before that time.     

Re-examining urban region and inferring regional function based on spatial–temporal interaction

Urban system is shaped by the interactions between different regions and regions planned by the government, then reshaped by human activities and residents’ needs. Understanding the changes of regional structure and dynamics of city function based on the residents’ movement demand are important to evaluate and adjust the planning and management of urban services and internal structures. This paper constructed a probabilistic factor model on the basis of probabilistic latent semantic analysis and tensor decomposition, for purpose of understanding the higher order interactive population mobility and its impact on urban structure changes. First, a four-dimensional tensor of time (T)?×?week (W)?×?origin (O)?×?destination (D) was constructed to identify the day-to-day activities in three time modes and weekly regularity of weekday/weekend pattern. Then we reclassified the urban regions based on the space clustering formed by the space factor matrix and core tensor. Finally, we further analysed the space–time interaction on different time scales to deduce the actual function and connection strength of each region. Our research shows that the application of individual-based spatial–temporal data in human mobility and space–time interaction study can help to analyse urban spatial structure and understand the actual regional function from a new perspective.     

Evaluation of active and passive seismic earth pressures considering internal friction and cohesion

The Log-Spiral-Rankine (LSR) model, which is a generalized formulation for assessing the active and passive seismic earth pressures considering the internal friction and cohesion of backfill soil, is reviewed and improved in this study. System inconsistencies in the LSR model are identified, which result from an inaccurate assumption on the vertical normal stress field (σ_z=γz) in a general c–ϕ soil medium, and from omitting the effect of soil cohesion when solving for the stress states along the failure surface. The remedies to the said inconsistencies are presented, and local and global iteration schemes are introduced to solve the resulting highly coupled multivariate nonlinear system of equations. The modified LSR model provides a more complete and accurate solution for earth retaining systems, including the geometry of the mobilized soil body, the stress state along the failure surface, as well as the magnitude and the point of application of the resultant earth thrust.