A Simplified Analytical Procedure for the Determination of Organically Bound Halogens in Salt‐containing Water Samples

A method was developed for the determination of organic halogens in water samples with the aim of minimizing matrix effects and simplifying the sample preparation technique commonly used. The method is based on the adsorption of organic halogens in modified hydrophilic divinylbenzene polymer columns and their elution with methanol. The adsorbent used enables rapid adsorption and desorption due to comparatively high operating flow rates and minimized solvent amounts. Furthermore, no additional reconcentration steps are needed. The methanol extract obtained is combusted with a standard EOX (extractable organic halogen) analyzer and the concentration of organically bound halogens is determined by microcoulometric analysis. The matrix effects are considerably reduced compared to the standard procedure (EN 1485) commonly used. A detection limit of 13 μg/L was established.     

Weathering control over geomorphology of supermature Proterozoic Delhi quartzites of India

Quartz and quartzite are thought to be resistant as a mineral and a rock respectively; however, we have shown that the presence of small amounts of pyrite in the quartzites makes them vulnerable to weathering. We observe that weathering of Proterozoic quartzite in the semi‐arid conditions around Delhi proceeded from fractures towards the inside and produced weathering rinds. The chemical index of alteration (CIA), which is actually a measure of weathering of aluminosilicate minerals, increases from the core outwards, through the rinds. Although aluminosilicate minerals occur only as minor phases (<2 per cent), their weathering indicates a movement of the weathering front from the periphery towards the core. We have suggested a coupled mechanism in which the dissolution of pyrites by moving water produced a sulphate‐bearing acidic solution and ferrous iron, which reacted with aluminosilicate minerals and quartz, respectively. This initially makes the Delhi quartzite porous and subsequently friable. The total disintegration of grain to grain contacts imparted friability to this quartzite to produce silica sand. Subsequent physical erosion of loose sand, produced during rind development in the outermost zones, has given rise to features like tors, spheroids, gullies, cavities and small‐scale caves on these quartzites. Thus, the terrain has acquired ruggedness in semi‐arid conditions. Copyright © 2003 John Wiley & Sons, Ltd.     

Mid‐Holocene sub‐blanket‐peat alluvia and sediment sources in the upper Liffey valley,Co. Wicklow,Ireland

A recently exposed section across a ?rst‐order valley buried beneath the regional blanket peat on hillside slopes in the upper Liffey valley, Co. Wicklow, is described. The section shows two alluvia within a shallow valley form underlain by an extensive boulder and stone line over regional till and weathered granite. ¹⁴C dates from wood in the alluvia indicate the older alluvium to have formed between 4324 ± 53 BP and 4126 ± 45 BP and the younger between 3217 ± 53 BP and 2975 ± 53 BP . The basal layer of the overlying peat yielded a date of 2208 ± 61 BP . The younger alluvium shows the effects of soil paludi?cation prior to the peat expansion. Dated pollen analyses elsewhere in the upper catchment con?rm the spread of blanket peat over most areas above 350 m after 4000–3600 BP . The buried valley was contributing sediments to the mid‐Holocene ?oodplains in the upper Liffey valley prior to the extension of blanket peat over the catchment after which sediment yields from it and the other catchment slopes declined. Copyright © 2003 John Wiley & Sons, Ltd.     

Simulation and measurement of surface shear stress over isolated and closely spaced transverse dunes in a wind tunnel

Topographic interactions generate multidirectional and unsteady air?ow that limits the application of velocity pro?le approaches for estimating sediment transport over dunes. Results are presented from a series of wind tunnel simulations using Irwin‐type surface‐mounted pressure sensors to measure shear stress variability directly at the surface over both isolated and closely spaced sharp‐crested model dunes. Findings complement existing theories on secondary air?ow effects on stoss transport dynamics and provide new information on the in?uence of lee‐side air?ow patterns on dune morphodynamics. For all speeds investigated, turbulent unsteadiness at the dune toe indicates a greater, more variable surface shear, despite a signi?cant drop in time‐averaged measurements of streamwise shear stress at this location. This effect is believed suf?cient to inhibit sediment deposition at the toe and may be responsible for documented intermittency in sand transport in the toe region. On the stoss slope, streamline compression and ?ow acceleration cause an increase in ?ow steadiness and shear stress to a maximum at the crest that is double that at the toe of the isolated dune and 60–70 per cent greater than at ?ow reattachment on the lower stoss of closely spaced dunes. Streamwise ?ow accelerations, rather than turbulence, have greater in?uence on stress generation on the stoss and this effect increases with stoss slope distance and with incident wind speed. Reversed ?ow within the separation cell generates signi?cant surface shear (30–40 per cent of maximum values) for both spacings. This supports ?eld studies that suggest reversed ?ow is competent enough to return sediment to the dune directly or in a de?ected direction. High variability in shear at reattachment indicates impact of a turbulent shear layer that, despite low values of time‐averaged streamwise stress in this region, would inhibit sediment accumulation. Downwind of reattachment, shear stress and ?ow steadiness increase within 6 h (h = dune height) of reattachment and approach upwind values by 25 h. A distance of at least 30 h is suggested for full boundary layer recovery, which is comparable to ?uvial estimates. The Irwin sensor used in this study provides a reliable means to measure skin friction force responsible for sand transport and its robust, simple, and cost‐effective design shows promise for validating these ?ndings in natural dune settings. Copyright © 2003 John Wiley & Sons, Ltd.     

Optimal distribution of linear control intensity over the frequency range

In this paper, a control strategy for structural systems is proposed and developed in the frequency domain. The algorithm is substantially based on a linear derivative feedback and a convolution of the control parameter, whose distribution in the frequency field is chosen in such a manner as to comply with the requirements of an ad hoc formulated constrained optimum problem, with the response data monitored until the instant of control action application. Some numerical testing is carried out by referring to given recorded accelerograms, showing a good performance of the proposed approach. Copyright © 2002 John Wiley & Sons, Ltd.     

Sliding fragility of block‐type non‐structural components. Part 1: Unrestrained components

Motivated by the development of performance‐based design guidelines with emphasis on both structural and non‐structural systems, this paper focuses on seismic vulnerability assessment of block‐type unrestrained non‐structural components under sliding response on the basis of seismic inputs specified by current seismic codes. Two sliding‐related failure modes are considered: excessive relative displacement and excessive absolute acceleration. It is shown that an upper bound for the absolute acceleration response can be assessed deterministically, for which a simple yet completely general equation is proposed. In contrast, fragility curves are proposed as an appropriate tool to evaluate the excessive relative displacement failure mode. Sample fragility curves developed through Monte‐Carlo simulations show that fragility estimates obtained without taking into account vertical base accelerations can be significantly unconservative, especially for relatively large values of the coefficient of friction. It is also found that reasonable estimates of relative displacement response at stories other than the ground in multistorey buildings cannot in general be obtained by simply scaling the ground acceleration to the peak acceleration at the corresponding storey. Failure modes considered in this study are found to be essentially independent of each other, a property that greatly simplifies assessment of conditional limit states. Copyright © 2002 John Wiley & Sons, Ltd.     

A procedure for evaluating seismic energy demand of framed structures

Energy serves as an alternative index to response quantities like force or displacement to include the duration‐related seismic damage effect. A procedure to evaluate the absorbed energy in a multistorey frame from energy spectra was developed. For low‐ to medium‐rise frames, it required a static pushover analysis of the structure to determine the modal yield force and ductility factor of an equivalent single‐degree‐of‐freedom system for the first two modes. The energy spectra were then used to determine the energy contribution of each mode. A procedure was also developed to distribute the energy along the frame height based on energy shapes. This study showed that the second‐mode response in some cases needs to be considered to reflect the energy (or damage) concentration in the upper floors. Copyright © 2002 John Wiley & Sons, Ltd.     

Simplified vibratory characterization of alluvial basins

For the analysis of seismic wave amplification, modal methods are interesting tools to study the modal properties of geological structures. Modal approaches mainly lead to information on such parameters as fundamental frequencies and eigenmodes of alluvial basins. For a specific alluvial deposit in Nice (France), a simplified modal approach involving the Rayleigh method is considered. This approach assumes a set of admissible shape functions for the eigenmodes and allows a fast estimation of the fundamental frequency of the basin. The agreement with other numerical results (Boundary Element Method) and experimental ones is fully satisfactory. The simplified modal method then appears as an efficient mean for the global vibratory characterization of geological structures towards resonance. To cite this article: J.-F. Semblat et al., C. R. Geoscience 335 (2003).     

La vallée d'Ys : un paléoréseau hydrographique immergé en baie de Douarnenez (Finistère,France)

Interpretation of the recent high-resolution survey, CANADOU 2000, in the Bay of Douarnenez (Finistère, France) allowed us to restore the morphology of the substratum and the sedimentary filling of the bay. The Brioverian and Palaeozoic substratum reveals a well-defined network of incised valleys as results of successive emergence stages of the Bay during the Quaternary. Valleys join in a westward-widened mean valley, called Ys Valley. The present-day sedimentary fill of the bay of Douarnenez appears mainly controlled by the Holocene rise and the consecutive highstand. It comprises fluvial and estuarine deposits filling up incised valleys and marine sedimentation extending out of the incised valleys. To cite this article: G. Jouet et al., C. R. Geoscience 335 (2003).To cite this article: G. Jouet et al., C. R. Geoscience 335 (2003).