Daily variability of river concentrations and fluxes: indicators based on the segmentation of the rating curve

The variability of water chemistry on a daily scale is rarely addressed due to the lack of records. Appropriate tools, such as typologies and dimensionless indicators, which permit comparisons between stations and between river materials, are missing. Such tools are developed here for daily concentrations (C), specific fluxes or yields (Y) and specific river flow (q). The data set includes 128 long‐term daily records, for suspended particulate matter (SPM), total dissolved solids (TDS), dissolved and total nutrients, totalling 1236 years of records. These 86 river basins (10³–10⁶ km²) cover a wide range of environmental conditions in semi‐arid and temperate regions. The segmentation—truncation of C–q rating curves into two parts at median flows (q₅₀) generates two exponents (b_50inf and b_50sup) that are different for 66% of the analysed rating curves. After segmentation, the analysis of records results in the definition of nine major C–q types combining concentrating, diluting or stable patterns, showing inflexions, chevron and U shapes. SPM and TDS are preferentially distributed among a few types, while dissolved and total nutrients are more widely distributed. Four dimensionless indicators of daily variability combine median (C₅₀, Y₅₀), extreme (C₉₉, Y₉₉) and flow‐weighted (C*, Y*) concentrations and yields (e.g. C₉₉/C₅₀, Y*/Y₅₀). They vary over two to four orders of magnitude in the analysed records, discriminating stations and river material. A second set of four indicators of relative variability [e.g. (Y*/Y₅₀)/(q*/q₅₀)], takes into account the daily flow variability, as expressed by q*/q₅₀ and q₉₉/q₅₀, which also vary over multiple orders of magnitude. The truncated exponent b_50sup is used to describe fluxes at higher flows accounting for 75% (TDS) to 97% (SPM) of interannual fluxes. It ranges from ? 0·61 to + 1·86 in the database. It can be regarded as the key amplificator (positive b_50sup) or reductor (negative b_50sup) of concentrations or yields variability. C₅₀, Y₅₀, b_50sup can also be estimated in discrete surveys, which provides a new perspective for quantifying and mapping water quality variability at daily scale. Copyright © 2011 John Wiley & Sons, Ltd.     

Theoretical analyses of acidization dissolution front instability in fluid‐saturated carbonate rocks

This paper presents an instability theory that can be used to understand the fundamental behavior of an acidization dissolution front when it propagates in fluid‐saturated carbonate rocks. The proposed theory includes two fundamental concepts, namely the intrinsic time and length of an acidization dissolution system, and a theoretical criterion that involves the comparison of the Zhao number and its critical value of the acidization dissolution system. The intrinsic time is used to determine the time scale at which the acidization dissolution front is formed, while the intrinsic length is used to determine the length scale at which the instability of the acidization dissolution front can be initiated. Under the assumption that the acidization dissolution reaction is a fast process, the critical Zhao number, which is used to assess the instability likelihood of an acidization dissolution front propagating in fluid‐saturated carbonate rocks, has been derived in a strictly mathematical manner. Based on the proposed instability theory of a propagating acidization dissolution front, it has been theoretically recognized that: (i) the increase of the mineral dissolution ratio can stabilize the acidization dissolution front in fluid‐saturated carbonate rocks; (ii) the increase of the final porosity of the carbonate rock can destabilize the acidization dissolution front, while the increase of the initial porosity can stabilize the acidization dissolution front in fluid‐saturated carbonate rocks; (iii) the increase of the mineral dissolution ratio can cause an increase in the dimensionless propagation speed of the acidization dissolution front; (iv) the increase of the initial porosity can enable the acidization dissolution front to propagate faster, while the increase of the final porosity can enable the acidization dissolution front to propagate slower in the acidization dissolution system. Copyright © 2012 John Wiley & Sons, Ltd.     

Travel time controls the magnitude of nitrate discharge in groundwater bypassing the riparian zone to a stream on Virginia's coastal plain

Groundwater that bypasses the riparian zone by travelling along deep flow paths may deliver high concentrations of fertilizer‐derived NO₃^? to streams, or it may be impacted by the NO₃^? removal process of denitrification in streambed sediments. In a study of a small agricultural catchment on the Atlantic coastal plain of Virginia's eastern shore, we used seepage meters deployed in the streambed to measure specific discharge of groundwater and its solute concentrations for various locations and dates. We used values of Cl^? concentration to discriminate between bypass water recharged distal to the stream and that contained high NO₃^? but low Cl^? concentrations and riparian‐influenced water recharged proximal to the stream that contained low NO₃^? and high Cl^? concentrations. The travel time required for bypass water to transit the 30‐cm‐thick, microbially active denitrifying zone in the streambed determined the extent of NO₃^? removal, and hydraulic conductivity determined travel time through the streambed sediments. At all travel times greater than 2 days, NO₃^? removal was virtually complete. Comparison of the timescales for reaction and transport through the streambed sediments in this system confirmed that the predominant control on nitrate flux was travel time rather than denitrification rate coefficients. We conclude that extensive denitrification can occur in groundwater that bypasses the riparian zone, but a residence time in biologically active streambed sediments sufficient to remove a large fraction of the NO₃^? is only achieved in relatively low‐conductivity porous media. Instead of viewing them as separate, the streambed and riparian zone should be considered an integrated NO₃^? removal unit. Copyright © 2011 John Wiley & Sons, Ltd.     

河岸带蜿蜒性与植被密度对潜流驻留时间的复合效应

潜流驻留时间是反映潜流交换、溶质迁移转化、生物组成、生态过程的重要特征变量。应用双循环可控式河岸带模型，以NaCl为示踪剂，深入研究了河岸带蜿蜒性与植被密度对潜流驻留时间的复合效应；应用量纲分析和主成分分析法，探析了潜流驻留时间的关键影响因子及其作用程度和敏感性。结果表明：①河岸带植被密度对潜流驻留时间具有促进作用，但存在一定的阈值。②潜流驻留时间分布与河岸蜿蜒形态呈类镜像效应；潜流驻留时间在河岸带蜿蜒波不同位置差异明显，迎水面平均驻留时间约为背水面的1/2。③河岸带蜿蜒性与植被密度是影响潜流驻留时间的关键因子，总作用程度达91.07%。潜流驻留时间对蜿蜒性最敏感，对植被密度敏感性较弱，对复合因子的敏感性介于两者之间；迎水面内组合因子对潜流驻留时间具有共同促进效应，背水面内组合因子对潜流驻留时间具有抑制和促进双重效应。     

Induced gravity anomalies and seismic energy as a basis for prediction of mining tremors

The results of prediction of occurrence of mining tremors and bursts in the course of the exploitation of the remaining part of the hard coal in seam 510 of the mine Pstrowski, Upper Silesia, have been presented in the paper. The exploitation has taken place under extremely difficult conditions hazardous for the mining crew.To predict the occurrence of mining tremors, bursts and direction of migration of increased elastic strain in the rock mass, the microgravity method has been applied.The microgravity observations were carried out in the measurement points located at mutual distances equal 20 m in three profiles of the lengths 700 m, 760 m and 260 m respectively. The profiles were located in mining workings in the vicinity of the exploited part of the bed. In the course of exploitation, lasting 25 months, 29 series of measurements including 3600 individual microgravity observations were carried out. Microgravity observations were made with a Worden-Master gravimeter.The observed time changes of gravity microanomalies were essential for prediction. Local negative changes of gravity microanomalies signalled the approaching mining tremor. The tremor would cover an area of the radius 60 m to 100 m. The regional time changes of the gravity microanomalies appearing as linear trends of these anomalies signalled the development of the fields of elastic strain in the whole investigated area and the approaching violent release of elastic strain energy from the rock mass.The values of the amplitudes AMP of the above-mentioned trend were the measure of this hazard. In the course of the investigations each shock was preceded by considerably increased values of AMP.     

Microseismicity in a flooded potash mine,the Hope mine,Federal Republic of Germany

Measuring of microseismic events has been carried out at the former potash mine of Hope since early 1984.Analysis of the data demonstrates an immediate temporal relationship between brine introduction and onset of microseismic activity. The spatial distribution of the sources indicates a dependence on brine level height. Sources are found preferentially immediately next to roads and workings. Source radii, estimated from the frequency ranges in the seismograms, varied with the cross-section of neighbouring cavities and had a similar, order of size.Events occurred rarely in the previously flooded mine sections Similarly, the zone below a depth of approx. 600 m below sea level was virtually inactive.     

BPM时号传播时延的连续观测与研究

利用新研制的短波传播时延实时数字显示系统,在武汉电离层观象台对BPM时号的传播时延进行了长时间连续观测。发现这种时延曲线的主要特征是:它是分段光滑的,光滑段工的相对时间比对精度可优于0.1ms;各光滑段之间,时延值发生突跳。结合多普勒图和频高图的同时观测记录,解释了时延突跳的原因,着重说明了突跳好几毫秒的所谓异常时号的传播机制。此外,还讨论了提高短波授时精度的某些技术措施。     

东伙房金矿床成矿构造条件及成矿时代讨论

东伙房金矿床从空间和时间看，固阳～察右中旗韧脆性变形带控矿是间接的，而其变形带附近有成生联系的破裂带控矿则是直接的。固阳～察右中旗变形带及容矿断裂经历了多期变形历史，具有从韧性～脆性变形的全过程。但同成矿期活动明显地表现为脆性破裂。这种浅层次的破裂系统为金矿热液在由深部向上运移过程中，温压条件的改变和金矿的沉淀提供了适宜的物理条件，控矿断裂显示了张性特点，反映了容矿断裂在成矿期自由度相对较大，处于一种扩张的环境之内。金矿形成于中生代这一特定的构造环境之中。     

南极地区小象幅航测内业成图

本文阐述了用１２０型非量测相机对南极中山站地区所摄制的１４００００小象幅航片制作１５０００地形图、正射像片图及１１００００地形图的原理、方法和精度。在外定向中适当增加控制点及考虑到加入适当的权的情况下，其外定向最大对点误差平面为２．２ｍ，高程为１．２ｍ。所制作的正射像片图和相应的地形图套合中误差为０．１４ｍｍ。其结果完全可满足南极科研、考察的要求