Prediction of the abiotic degradability of organic compounds in the troposphere

A statistically relevant correlation between the reaction rate coefficient, k _OH, for the OH radical reaction with 161 organic compounds in the gas phase at 300 K, and the corresponding vertical ionisation energies E _i,v, reveals two classes of compounds: aromatics where –log(k _OH/cm³s^-1)3/2E _i,v(eV)–2 and aliphatics where –log(k _OH/cm³s^-1)4/5E _i,v(eV)+3. The prediction of the rate coefficient, k _OH, for the reaction of OH with organic molecules from the above equations has a probability of about 90%. Assuming a global diurnal mean of the OH radical concentration of 5×10⁵ cm³, the upper limit of the tropospheric half-life of organic compounds and their persistence can be estimated.     

FTIR studies of reactions between the nitrate radical and haloethenes

Products and mechanisms for the gas-phase reactions of NO₃ radicals with CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂,cis-CHCl=CHCl andtrans-CHCl=CHCl in air have been studied. The experiments were carried out at 295±2 K and 740±5 Torr in a 480-L Teflon-coated reaction chamber and at 295±2 K and 760±5 Torr in a 250-L stainless steel reactor. NO₃ was generated by the thermal dissociation of N₂O₅. Experiments with¹⁵NO₃ and CD₂CDCl have also been performed. The initially formed nitrate peroxynitrates decay into carbonyl compounds, nitrates, HCl and ClNO₂. In adidtion, there are indications of nitrooxy acid chlorides being produced. The reactions with CH₂=CCl₂ and CHCl=CCl₂ are more complex due to release of chlorine atoms which eventually lead to formation of chloroacid chlorides.A general reaction mechanism is proposed and the observed concentration-time profiles of reactants and products are simulated for each compound. The rate constants for the initial step of NO₃ addition to the chloroethenes are determined as: (2.6±0.5, 9.4±0.9, 2.0±0.4 and 1.4±0.4) × 10^–16 cm³ molecule^–1 s^–1 for CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂ andcis-CHCl=CHCl, respectively.     

A preliminary study of the effects of some flow parameters in the generation of poloidal and toroidal energies within a 3-D spherical thermal-convective system with variable viscosity

The effects of variable viscosity on flow dynamics within spherical shells are investigated using a finite-element thermal convection model, and preliminary result for cases with relatively low Rayleigh numbers and small viscosity contrasts are reported. These results demonstrate some general effects of viscosity variation on mantle dynamics, and, in particular, the generation of toroidal energy. Since lateral viscosity variations are necessary in the generation of toroidal motion in a thermally driven convective system, it is not surprising our results show that flows with greater viscosity contrasts produce greater amounts of toroidal energy. Our preliminary study further shows that solutions become more time-dependent as viscosity contrasts increase. Increasing the Rayleigh number is also found to increase the magnitude of toroidal energy. Internal heating, on the other hand, appears to lead to less toroidal energy compared wth bottom heating because it tends to produce a thermally more uniform interior and thus smaller viscosity variations.     

Inference of mantle viscosity from GRACE and relative sea level data

Gravity Recovery And Climate Experiment (GRACE) satellite observations of secular changes in gravity near Hudson Bay, and geological measurements of relative sea level (RSL) changes over the last 10 000 yr in the same region, are used in a Monte Carlo inversion to infer-mantle viscosity structure. The GRACE secular change in gravity shows a significant positive anomaly over a broad region (>3000 km) near Hudson Bay with a maximum of ∼2.5 μGal yr⁻¹ slightly west of Hudson Bay. The pattern of this anomaly is remarkably consistent with that predicted for postglacial rebound using the ICE-5G deglaciation history, strongly suggesting a postglacial rebound origin for the gravity change. We find that the GRACE and RSL data are insensitive to mantle viscosity below 1800 km depth, a conclusion similar to that from previous studies that used only RSL data. For a mantle with homogeneous viscosity, the GRACE and RSL data require a viscosity between  1.4 × 10²¹  and  2.3 × 10²¹  Pa s. An inversion for two mantle viscosity layers separated at a depth of 670 km, shows an ensemble of viscosity structures compatible with the data. While the lowest misfit occurs for upper- and lower-mantle viscosities of  5.3 × 10²⁰  and  2.3 × 10²¹  Pa s, respectively, a weaker upper mantle may be compensated by a stronger lower mantle, such that there exist other models that also provide a reasonable fit to the data. We find that the GRACE and RSL data used in this study cannot resolve more than two layers in the upper 1800 km of the mantle.     

水泥—丙烯酸盐复合浆液的实验性研究

水泥-丙烯酸盐复合浆液是在丙烯酸盐浆液的基础上研制出来的一种复合浆液，它既保留了丙烯酸盐浆液流动性好，固结体弹性好的优点，又大幅度地提高了浆液的抗压强度和粘结强度，因此在注浆时可以带来良好的综合灌注效果，还对复合浆液的粘度和强度进行了试验性研究。     

平极长期漂移与地球平均下地幔黏性估计

利用9个国际纬度观测站的平纬长期变化序列,重新讨论并估计了平极的长期漂移,得到漂移的平均速率为(3.356“±0.142”)×l0-3/a,方向为西经78.7°±2.5°.进一步基于最新的ICE-4G冰期后地壳反弹模型,采用地球上8个冰盖的冰融参数,估计了理论的平极长期漂移方向为西经74.8°.由观测的平极长期漂移速率为约束,基于1066B地球模型,估计得到地球平均下地幔的黏性为vLM=(0.5-1.7)×1022Pa^.s,表明vLM应具有近1022Pa^.s量级,并认为地球平极的长期漂移很可能是由最近的21000年以来冰期后的地壳反弹所致.     

Latent heat effects of the major mantle phase transitions on low-angle subduction

Very low to zero shallow dip angles are observed at several moderately young subduction zones with an active trenchward moving overriding plate. We have investigated the effects of latent heat for this situation, where mantle material is pushed through the major mantle phase transitions during shallow low-angle subduction below the overriding plate. The significance of the buoyancy forces, arising from the latent heat effects, on the dynamics of the shallowly subducting slab is examined by numerical modeling. When a 32-Ma-old slab is overridden with 2.5 cm/yr by a continent, flat subduction occurs with a 4–5 cm/yr convergence rate. When latent heat is included in the model, forced downwellings cause a thermal anomaly and consequently thermal and phase buoyancy forces. Under these circumstances, the flat slab segment subducts horizontally about 350 km further and for about 11 Ma longer than in the case without latent heat, before it breaks through the 400-km phase transition. The style of subduction strongly depends on the mantle rheology: increasing the mantle viscosity by one order of magnitude can change the style of subduction from steep to shallow. Similarly, an overriding velocity of less than 1 cm/yr leads to steep subduction, which gradually changes to flat subduction when increasing the overriding velocity. However, these model parameters do not change the aforementioned effect of the latent heat, provided that low-angle subduction occurs. In all models latent heat resulted in a substantial increase of the flat slab length by 300–400 km. Varying the olivine–spinel transition Clapeyron slope γ from 1 to 6 MPa/K reveals a roughly linear relation between γ and the horizontal length of the slab. Based on these results, we conclude that buoyancy forces due to latent heat of phase transitions play an important role in low-angle subduction below an overriding plate.     

Delineation of sulphide ore-zones by borehole radar tomography at Hellyer Mine, Australia

Velocity and absorption tomograms are the two most common forms of presentation of radar tomographic data. However, mining personnel, geophysicists included, are often unfamiliar with radar velocity and absorption. In this paper, general formulae are introduced, relating velocity and attenuation coefficient to conductivity and dielectric constant. The formulae are valid for lossy media as well as high-resistivity materials. The transformation of velocity and absorption to conductivity and dielectric constant is illustrated via application of the formulae to radar tomograms from the Hellyer zinc–lead–silver mine, Tasmania, Australia. The resulting conductivity and dielectric constant tomograms constructed at Hellyer demonstrated the potential of radar tomography to delineate sulphide ore zones.