Quaternary evolution of the Ría de Vigo, Spain

The seismic analysis of the sedimentary infill of the Ría de Vigo reveals that the infill comprises of a fifth order sequence (18 ky) bounded by a major discontinuity surface. Within the Holocene sequence, several seismic units have been identified; the oldest one originated after the Würm glaciation and the origin of its top discontinuity was eroded during the regression (sea level at − 120 m) of this last glacial episode (isotopic stages 2 to 4), 18 ky B.P.

In some places below this ría infill, another sequence can be identified. This older sequence is associated with the pre-existing faults and troughs in the deepest parts of the ría, and it was deposited during the Würm glaciation (Miocene–Pleistocene). Eroded sediments were moved from the rías area to deeper zones, where they accumulated in the lowstand system tract. The next sea level rise occured in two steps, producing two transgressive units separated by an hiatus surface. This cycle was interrupted by the next sea level fall (to − 55 m) marked on the seismic records by another recognizable boundary. The next sea level rise took place in several steps (back-stepping) with some stillstands, generating another transgressive system tract in the ría. From that time on, the relative sea level continued rising, depositing the most recent unit which represents the highstand system tract. Separating the highstand system tract and the transgresive unit below there is a consensed section.

The analysis of 29 cores provides groundtruthing for our hypothesis. The identified main lithologic units show a transgressive sequence: a granitic rock base, an overlying second unit-locally wedge shaped- and most recently, a marine muddy unit covering the present ría seafloor.     

Theoretical analysis of equatorial near-inertial solitary waves under complete Coriolis parameters

An investigation of equatorial near-inertial wave dynamics under complete Coriolis parameters is performed in this paper. Starting from the basic model equations of oceanic motions, a Korteweg de Vries equation is derived to simulate the evolution of equatorial nonlinear near-inertial waves by using methods of scaling analysis and perturbation expansions under the equatorial beta plane approximation. Theoretical dynamic analysis is finished based on the obtained Korteweg de Vries equation, and t...     

Concordance degrees in macrozoobenthic monitoring programmes using different sampling methods and taxonomic resolution levels

In summer 1997, an intensive survey on the hard bottoms of the 'Abra de Bilbao' (N. Iberian Peninsula) was carried out in the context of the macrozoobenthic monitoring programmes developed to assess the biological recovery of the area. Three types of measurements (abundance, biomass and cover) were used to describe and compare the structure and composition of the communities at three littoral zones: subtidal, lower intertidal and upper intertidal. In addition, several taxonomic aggregation levels of data were successfully applied. The main objective of this paper is to explore the relative effect caused on the results of such programmes by earlier decisions concerning the type of measurement and the taxonomic resolution level to be applied. A 'second stage' multivariate procedure of analysis has been perforrmed based on the previously obtained sampling site ordinations. The measurement type chosen has been found to have a greater effect on the results than the taxonomic resolution used. Moreover, it is suggested that analyses based on abundance data usually lose more information when taxonomic resolution decreases than those based on biomass or cover estimates. The highest concordance among the different analyses has been found in the subtidal zone, which is considered the most appropriate habitat for the development of benthic monitoring programmes.     

Iron Isotope Variations in Coastal Seawater Determined by Multicollector ICP-MS

In this paper, we applied a reliable technique for measuring Fe isotope variations in coastal seawater at nanomolar levels. Iron was directly pre-concentrated from acidified seawater samples onto a nitrilotriacetic acid chelating resin and further purified using anion-exchange resin. Sample recovery, determined using a standard addition method, was essentially quantitative. Iron was then determined using a high-resolution multicollector ICP-MS (Neptune) coupled to an ApexQ desolvation introduction system. The external precision for δ⁵⁶Fe values was 0.11‰ (2s) when using total a Fe quantity between 25 and 100 ng. We initially applied this technique to measure the Fe isotope composition of dissolved Fe from several coastal environments in the north-eastern United States and we observed a range of δ⁵⁶Fe values between -0.9‰ and 0.1‰ relative to the IRMM-14 reference material. Iron isotope compositions of several reference water materials for inter-laboratory comparisons were also reported. Our results suggest that iron in coastal seawater, derived from benthic diagenesis and/or groundwater has negative Fe isotopic signatures that are distinct from other iron sources such as atmospheric deposition and rivers.     

Effect of anorthite on granite phase relations: Experimental data and models

New experimental data on the effect of anorthite (An) on liquidus phase equilibria in the system Qz–Ab–Or are presented. The data were obtained for 5 wt% An added to variable Qz/Ab/Or compositions at 300 MPa and under H₂O-saturated conditions. Crystal–liquid equilibria were determined for 13 synthetic glass compositions made from gels in experiments performed between 660 and 750 °C in cold-seal pressure vessels. Forward and reversal experiments were systematically conducted on each composition to demonstrate equilibrium. A total of 51 charges was examined. Three crystalline phases, quartz, alkali feldspar and plagioclase appear on the H₂O-saturated liquidus surface. The determined minimum liquidus 5 wt% An “piercing” point (39% Qz, 33% Ab, 28% Or) is shifted away from the Ab apex toward the Qz–Or sideline when compared with the An-free 300 MPa H₂O-saturated minimum. This shift is of the same type as that observed at 100 MPa in the same system and at 200 MPa in a rhyolitic system. The new experimental results are used to test both empirical and thermodynamic models for silicic magmas. Empirical models reproduce reasonably well the new experimental data, although more sophisticated calculations schemes appear to be required to improve their accuracy. The new experimental results in the haplogranodiorite system are not well reproduced with the model of Holland and Powell (2001), mainly because plagioclase stability appears greatly enhanced in the model. Rhyolite-MELTS satisfactorily reproduces the Qz-, Pl- and Af-liquid phase equilibria, but model H₂O solubilities are significantly lower and crystallization temperatures higher than in experiments.     

Raman spectroscopy of natural silica in Chicxulub impactite,MexicoSpectroscopie Raman de silices naturelles dans l'impactite de Chicxulub,Mexique

A series of natural silica impactite samples from Chicxulub (Mexico) was investigated by Raman microprobe (RMP) analysis. The data yield evidence for high-pressure shock metamorphism in the rock. The impactite contains three polymorphs of silica: the original α-quartz, and two high-pressure varieties – coesite and disordered quartz representing various degrees of crystallinity. We found systematic changes in frequencies and half-widths of the Raman bands, caused by increasing irregularities of bond-lengths and bond-angles and a general breaking-up of the structure as a result of impact events. Therefore, RMP is an adequate tool for measuring the crystallinity of disordered quartz. The half-width Γ and the frequency ω of the symmetric SiOSi stretching vibrational band (A₁ mode) of the SiO₄ tetrahedra are the most amenable parameters for estimating the degree of crystallinity. In well-crystallized quartz, Γ=5 cm^?1 and ω=464 cm^?1, while in highly disordered quartz this line shifts up to ω=455 cm^?1 and broadens up to Γ=30 cm^?1. The Raman lineshapes appear to depend strongly on the degree of lattice disorder subsequent to impact events. To cite this article: M. Ostroumov et al., C. R. Geoscience 334 (2002) 21–26     

Mn-oxide: a major source of easily mobilisable Co and Ni under reducing conditions in New Caledonia FerralsolsLes oxydes de Mn : une source majeure de Co et Ni facilement mobilisables en conditions réductrices dans les Ferralsols de Nouvelle-Calédonie

Chemical and bacterial reduction and dissolution of Fe and Mn-oxide and the concomitant solubilisation of Co and Ni were studied in a surface horizon of a New-Caledonia Ferralsol. Chemical extractions showed that Mn and Co were in a large part associated in Mn-oxides. The main part of Ni was associated with goethite, but a very small fraction was also associated with Mn-oxides. Anaerobic reducing bacterial activity was responsible for Fe solubilisation at a smaller extent than for Mn solubilisation and consequently for associated metal release. Submicroscopic investigations revealed the presence of a Mn-oxide containing Co, Ni and Al, close to a lithiophorite–asbolane mixed-layers Mn-oxide, which can be considered as a main source of easily available metals in this soil. To cite this article: C. Quantin et al., C. R. Geoscience 334 (2002) 273–278.     

Caractérisation des variations lithologiques saisonnières des sédiments de la baie de Seine orientale ; impact des crues de la Seine (France)Characterisation of seasonal lithological variations of the superficial sediment in the eastern part of the Bay of Seine: impact of floods Seine River (France)

This paper presents the first results obtained during cruises since 1995 in the southeastern part of the Bay of Seine. New sedimentological data concerning sediment samples, box cores and water column measurements have been obtained recently in the framework of the Research Programme PNEC (French National Coastal Environment Programme). Fine sediments are deposited on form of temporary veneers of fluid-to-soft mud formed during high floods episodes. In the subtidal area (<10 m water depth), mobility of fine sediments is important and temporary mud deposited during high discharge period composes part of the distal estuarine system of the Seine River. To cite this article: S. Garnaud et al., C. R. Geoscience 334 (2002) 323–330.     

Homogénéisation et validation des corrections de terrain gravimétriques jusqu'à la distance de 167 km sur l'ensemble de la FranceUpdating and validating the French gravity terrain corrections out to a distance of 167 km

For regional and national study purposes, there is a high need for updating the terrain corrections (TC) in the French gravity database. We have recomputed the TC for all the French gravity stations from 50 m out to a distance of 167 km. We compute the TC with a flat-top-prism algorithm and three DEM with grid spacing of 50, 250 and 1000 m, used in the zones 53 m/3 km, 3 km/10 km et 10 km/167 km, respectively. Analysing the DEM/station Δz and comparing our results to the ones previously obtained in the Alps area, we estimate the accuracy of our TC to be better than 1 mGal. To cite this article: G. Martelet et al., C. R. Geoscience 334 (2002) 449–454.     

Peut-on évaluer le rôle de la sédimentation sur l'effet de serre à l'échelle de temps des cycles orbitaux ?Can the role of sedimentation in the greenhouse effect at the time scale of orbital cycles be evaluated?

The evolution of the atmospheric CO₂ content is partly a response to the lack of balance between oceanic sedimentation and continental weathering, because the oceanic C reservoir tends to balance net inputs or losses from slow processes by rapid exchanges with the atmospheric reservoir. This response strongly depends on both amplitudes and time scales of the related processes. At Milankovitch or lower time scales, global models generally do neglect organic matter fossilisation, but such an assumption is only valid for oligotrophic systems. In eutrophic or mesotrophic systems, organic matter is not negligible and should be considered relatively to the carbonate sedimentation in order to know whether the impact of the sedimentation was a source or a sink for atmospheric CO₂. To cite this article: P. Bertrand, C. R. Geoscience 334 (2002) 521–528.