Chemical weathering indices are useful tools in characterizing weathering profiles and determining the extent of weathering. However, the predictive performance of the conventional indices is critically dependent on the composition of the unweathered parent rock. To overcome this limitation, the present paper introduces an alternative statistical empirical index of chemical weathering that is extracted by the principal component analysis (PCA) of a large dataset derived from unweathered igneous rocks and their weathering profiles. The PCA analysis yields two principal components (PC1 and PC2), which capture 39.23% and 35.17% of total variability, respectively. The extent of weathering is reflected by variation along PC1, primarily due to the loss of Na2O and CaO during weathering. In contrast, PC2 is the direction along which the projections of unweathered felsic, intermediate and mafic igneous rocks appear to be best discriminated; therefore, PC1 and PC2 represent independent latent variables that correspond to the extent of weathering and the chemistry of the unweathered parent rock. Subsequently, PC1 and PC2 were then mapped onto a ternary diagram (MFW diagram). The M and F vertices characterize mafic and felsic rock source, respectively, while the W vertex identifies the degree of weathering of these sources, independent of the chemistry of the unweathered parent rock.
The W index has a number of significant properties that are not found in conventional weathering indices. First, the W index is sensitive to chemical changes that occur during weathering because it is based on eight major oxides, whereas most conventional indices are defined by between two and four oxides. Second, the W index provides robust results even for highly weathered sesquioxide-rich samples. Third, the W index is applicable to a wide range of felsic, intermediate and mafic igneous rock types. Finally, the MFW diagram is expected to facilitate provenance analysis of sedimentary rocks by identifying their weathering trends and thereby enabling a backward estimate of the composition of the unweathered source rock. 相似文献
In this paper,we analyze the time series of site coordinates of 27 continuously monitoring GPS sites covered bythe Crustal Movement Observation Network of China over the whole country.The data are obtained in the periodfrom the beginning of the observation to the November of 2005.On the basis of data processing,we analyze thepower spectrum density of coordinate component noise at each site and calculate the spectral indexes manifestingthe noise property of each component.The spectral indexes indicate that for most sites,the noise of time series ofeach coordinate component can be addressed by the model of white noise flicker noise;and for a small amountof sites,it can be described by the model of white noise flicker noise random walk noise.We also quantita-tively estimate each noise component in the model by using the criterion of maximum likelihood estimation.Theresult shows that the white noise in the time series of GPS site coordinates does not constitute the main part ofnoise.Therefore,the error estimation of site movement parameters is usually too small,or too optimistic if weconsider the white noise only.Correspondingly,if this factor is not fully considered in explaining these movementparameters,it might mislead the readers. 相似文献
Groundwater is the most prioritized water source in India and plays an indispensable role in India's economy. The groundwater potential mapping is key to the sustainable groundwater development and management. A hybrid methodology is applied to delineate potential groundwater zones based on remote sensing, geographical information systems(GIS) and analytic hierarchy process(AHP) as on multicriteria decision making. For the purpose of demonstrating field application, Chittar watershed, Tamilnadu, India is studied as an example. The important morphological characteristics considered in the study are lithology, geomorphology, lineament density, drainage density, slope, and Soil Conservation Service–Curve Number(SCS-CN). These six thematic layers are generated in a GIS platform. Based on intersecting the layers, AHP method, the values for adopting the pairwise comparison normalized weight and normalized subclasses weightage were given. The normalized subclass weightage is input into each layer subclass. Then, weighted linear combination method is used to add the data layers in GIS platform to generate groundwater potential Index(GWPI) map. The GWPI map is validated based on the net recharge computed from the differences of measured groundwater levels between the pre-monsoon and post-monsoon in the year 2018. The kappa statistics are used to measure level spatial consistency between the GWPI and net recharge map. The overall average spatial matching accuracy between the two data sets is 0.86, while the kappa coefficient for GWPI with net recharge, 0.78. The results show that in Chittar watershed about 870 km~2 area is divided into high potential zone(i.e. sum of very high and high potential zone), 667 km~2 area, as the moderate one and the rest 105 km~2 area, as the poor zone(i.e. sum of very poor and poor potential zone). 相似文献