Late Miocene–Pliocene eclogite facies metamorphism, D'Entrecasteaux Islands, SE Papua New Guinea

The D'Entrecasteaux Islands of south‐eastern Papua New Guinea are active metamorphic core complexes that formed within a region where the plate tectonic regime has transitioned from subduction to rifting. While rapid, post 4 Myr exhumation and cooling of amphibolite and greenschist facies rocks that constitute the footwall of the crustal scale detachment fault system have been previously documented on Fergusson and Goodenough Islands of the D'Entrecasteaux chain, the timing of eclogite facies metamorphism in rocks of the footwall was unknown. Recent work revealed that at least one of the eclogite bodies formed during the Pliocene. We present combined in situ ion microprobe U–Pb age analyses of zircon from five variably retrogressed eclogite samples from Fergusson and Goodenough Islands that document Late Miocene–Pliocene (8–2 Ma) eclogite formation on these islands. Textural relationships and zircon–garnet rare earth element partition coefficients indicate that U–Pb ages constrain zircon crystallization under eclogite facies conditions in all samples. Results suggest westward younging of eclogite facies metamorphism from Fergusson to Goodenough Island. Present‐day exposure of Late Miocene–Pliocene eclogites requires exhumation rates > 2.5 cm yr^?1.     

A new occurrence of retrogressed eclogite from the Sanbagawa belt of southwest Japan and its significance

The present paper reports, for the first time, the occurrence of an omphacite‐bearing mafic schist from the Asemi‐gawa region of the Sanbagawa belt (southwest Japan). The mafic schist occurs as thin layers within pelitic schist of the albite–biotite zone. Omphacite in the mafic schist only occurs as inclusions in garnet, and albite is the major Na phase in the matrix, suggesting that the mafic schist represents highly retrogressed eclogite. Garnet grains in the sample show prograde‐type compositional zoning with no textural or compositional break, and contain mineral inclusions of omphacite, quartz, glaucophane, barroisite/hornblende, epidote and titanite. In addition to the petrographic observations, Raman spectroscopy and focused ion beam system–transmission electron microscope analyses were used for identification of omphacite in the sample. The omphacite in the sample shows a strong Raman peak at 678 cm^?1, and concomitant Raman peaks are all consistent with those of the reference omphacite Raman spectrum. The selected area electron diffraction pattern of the omphacite is compatible with the common P2/n omphacite structure. Quartz inclusions in the mafic schist preserve high residual pressure values of Δω₁ > 8.5 cm^?1, corresponding to the eclogite facies conditions. The combination of Raman geothermobarometries and garnet–clinopyroxene geothermometry gives peak pressure–temperature (P–T) conditions of 1.7–2.0 GPa and 440–540 °C for the mafic schist. The peak P–T values are comparable to those of the schistose eclogitic rocks in other Sanbagawa eclogite units of Shikoku. These findings along with previous age constraints suggest that most of the Sanbagawa schistose eclogites and associated metasedimentary rocks share similar simple P–T histories along the Late Cretaceous subduction zone.     

山东莒南-日照地区榴辉岩与围岩的接触关系及其地质意义

对山东莒南日照地区榴辉岩与不同围岩的接触关系进行研究发现：包裹榴辉岩的斜长角闪岩有窄的细粒边；榴辉岩在变质地层及超镁铁岩中呈夹层状产出，与超镁铁岩相伴产出的榴辉岩有角闪石化边；变质含霓石花岗岩及闪长玢岩侵入榴辉岩。认为榴辉岩是“就地的”．其原岩类型较复杂。其形成时代可能为新元古代。     

三江南段景洪大勐龙地区基性高压变质岩岩石地球化学特征及其大地构造意义

本文以三江南段景洪大勐龙地区新发现的退变榴辉岩和蓝片岩为研究对象,对其进行了系统的地球化学、原岩性质及锆石U-Pb定年的综合研究。大勐龙地区退变榴辉岩呈透镜状产于白云钠长石英片岩、白云母片岩和斜长角闪（片）岩中,其原岩为亚碱性拉斑玄武岩,球粒陨石标准化稀土元素配分曲线呈轻稀土弱亏损、重稀土平坦型的分布特征,不具有Nb、Ta、Ti的亏损,与典型的N-MORB（正常型洋中脊玄武岩）地球化学特征一致,表明其原岩可能来源于亏损的地幔区,形成于洋中脊环境;变质锆石SHRIMP U-Pb年龄为230.3±1.7Ma,可能代表榴辉岩峰期的变质时代。蓝片岩的原岩为亚碱性拉斑玄武岩,具有较高Ti玄武岩的特征（TiO₂含量2.55%~2.88%,均大于2%）,稀土元素总量变化范围小,比典型的N-MORB稀土总量偏高,轻稀土元素（LREE）亏损,无明显负Eu异常,地球化学性质与N-MORB类似。结合以往区域研究成果,进一步确定研究区退变榴辉岩和蓝片岩的原岩属于典型N-MORB型,该项研究不仅在昌宁-孟连缝合带的南段发现典型的特提斯洋壳残片,而且为进一步深入探讨滇西地区特提斯洋消减-闭合的动力学背景及其复杂的构造演化过程提供了重要的科学依据。

     

Ubiquitous post-peak zircon in an eclogite from the Kumdy-Kol,Kokchetav UHP-HP Massif (Kazakhstan): Significance of exhumation-related zircon growth and modification in continental-subduction settings

U–Pb geochronological, trace-element and Lu–Hf isotopic studies have been made on zircons from ultrahigh-pressure (UHP) mafic eclogite from the Kumdy-Kol area, one of the diamond-facies domains of the Kokchetav Massif (northern Kazakhstan). The peak eclogitic assemblage equilibrated at > 900 °C, whereas the bulk sample composition displays light rare-earth element (LREE) and Th depletion evident of partial melting. Zircons from the eclogite are represented by exclusively newly formed metamorphic grains and have U–Pb age spread over 533–459 Ma, thus ranging from the time of peak subduction burial to that of the late post-orogenic collapse. The major zircon group with concordant age estimates have a concordia age of 508.1 ±4.4 Ma, which corresponds to exhumation of the eclogite-bearing UHP crustal slice to granulite- or amphibolite-facies depths. This may indicate potentially incoherent exhumation of different crustal blocks within a single Kumdy-Kol UHP domain. Model Hf isotopic characteristics of zircons (ε_Hf(t) +1.5 to +7.8, Neoproterozoic model Hf ages of 1.02–0.79 Ga) closely resemble the whole-rock values of the Kumdy-Kol eclogites and likely reflect in situ derivation of HFSE source for newly formed grains. The ages coupled with geochemical systematics of zircons confirm that predominantly late zircon growth occurred in Th–LREE-depleted eclogitic assemblage, that experienced incipient melting and monazite dissolution in melt at granulite-facies depths, followed by amphibolite-facies rehydration during late-stage exhumation-related retrogression.     

Constraining peak P–T conditions in UHP eclogites: calculated phase equilibria in kyanite‐ and phengite‐bearing eclogite of the Tromsø Nappe,Norway

Kyanite‐ and phengite‐bearing eclogites have better potential to constrain the peak metamorphic P–T conditions from phase equilibria between garnet + omphacite + kyanite + phengite + quartz/coesite than common, mostly bimineralic (garnet + omphacite) eclogites, as exemplified by this study. Textural relationships, conventional geothermobarometry and thermodynamic modelling have been used to constrain the metamorphic evolution of the Tromsdalstind eclogite from the Tromsø Nappe, one of the biggest exposures of eclogite in the Scandinavian Caledonides. The phase relationships demonstrate that the rock progressively dehydrated, resulting in breakdown of amphibole and zoisite at increasing pressure. The peak‐pressure mineral assemblage was garnet + omphacite + kyanite + phengite + coesite, inferred from polycrystalline quartz included in radially fractured omphacite. This omphacite, with up to 37 mol.% of jadeite and 3% of the Ca‐Eskola component, contains oriented rods of silica composition. Garnet shows higher grossular (X_Grs = 0.25–0.29), but lower pyrope‐content (X_Prp = 0. 37–0.39) in the core than the rim, while phengite contains up to 3.5 Si pfu. The compositional isopleths for garnet core, phengite and omphacite constrain the P–T conditions to 3.2–3.5 GPa and 720–800 °C, in good agreement with the results obtained from conventional geothermobarometry (3.2–3.5 GPa & 730–780 °C). Peak‐pressure assemblage is variably overprinted by symplectites of diopside + plagioclase after omphacite, biotite and plagioclase after phengite, and sapphirine + spinel + corundum + plagioclase after kyanite. Exhumation from ultrahigh‐pressure (UHP) conditions to 1.3–1.5 GPa at 740–770 °C is constrained by the garnet rim (X_Ca^Grt = 0.18–0.21) and symplectite clinopyroxene (X_Na^Cpx = 0.13–0.21), and to 0.5–0.7 GPa at 700–800 °C by sapphirine (X_Mg = 0.86–0.87) and spinel (X_Mg = 0.60–0.62) compositional isopleths. UHP metamorphism in the Tromsø Nappe is more widespread than previously known. Available data suggest that UHP eclogites were uplifted to lower crustal levels rapidly, within a short time interval (452–449 Ma) prior to the Scandian collision between Laurentia and Baltica. The Tromsø Nappe as the highest tectonic unit of the North Norwegian Caledonides is considered to be of Laurentian origin and UHP metamorphism could have resulted from subduction along the Laurentian continental margin. An alternative is that the Tromsø Nappe belonged to a continental margin of Baltica, which had already been subducted before the terminal Scandian collision, and was emplaced as an out‐of‐sequence thrust during the Scandian lateral transport of nappes.     

P–T evolution of kyanite eclogite from the Pirin Mountains (SW Bulgaria): implications for the Rhodope UHP Metamorphic Complex

A new occurrence of kyanite eclogite in the Pirin Mountains of southwestern Bulgaria within the rocks belonging to the Obidim Unit of the Rhodope Metamorphic Complex is presented. This eclogite provides important information about the peak–pressure conditions despite strong thermal overprint at low pressure. Textural relationships, phase equilibrium modelling and conventional geothermobarometry were used to constrain the metamorphic evolution. Garnet porphyroblasts with inclusions of omphacite (up to 43 mol.% Jd), phengite (up to 3.5 Si p.f.u.), kyanite, polycrystalline quartz, pargasitic amphibole, zoisite and rutile in the Mg‐rich cores (X_Mg = 0.44–0.46) record a prograde increase in P–T conditions from ～2.5 GPa and 650 °C to ～3 GPa and 700–750 °C. Maximum pressure values fall within the stability field of coesite. During exhumation, the peak–pressure assemblage garnet + omphacite + phengite + kyanite was variably overprinted by a lower pressure one forming symplectitic textures, such as diopside + plagioclase after omphacite and biotite + plagioclase after phengite. The development of spinel (X_Mg = 0.4–0.45) + corundum + anorthite assemblage in the kyanite‐bearing domains at ～1.1 GPa and 800–850 °C suggests a thermal overprint in the high‐pressure granulite facies stability field. This thermal event was followed by cooling at ～0.8 GPa under amphibolite facies conditions; retrograde kelyphite texture involving plagioclase and amphibole was developed around garnet. Our results add to the already existing evidence for ultra high pressure (UHP) metamorphism in the Upper Allochthon of the Rhodope Metamorphic Complex as in the Kimi Unit and show that it is more widespread than previously known. Published age data and field structural relations suggest that the Obidim Unit represents Variscan continental crust involved into the Alpine nappe edifice of the Rhodopes and that eclogite facies metamorphism was Palaeozoic, in contrast to the Kimi Unit where age determinations suggest a Jurassic or Cretaceous age for UHP metamorphism. This implies that UHP metamorphism in the Upper Allochthon of the Rhodopes may have occurred twice, during Alpine and pre‐Alpine orogenic events, and that two independent HP/UHP provinces of different age overlap in this area.     

Metamorphic evolution of the Naga Hills eclogite and blueschist, Northeast India: implications for early subduction of the Indian plate under the Burma microplate

Tectonic slices and lenses of eclogite within mafic and ultramafic rocks of the Early Cretaceous–Eocene Naga Hills ophiolite were studied to constrain the physical conditions of eastward subduction of the Indian plate under the Burma microplate and convergence rate prior to the India–Eurasia collision. Some of the lenses are composed of eclogite, garnet-blueschist, glaucophanite and greenschist from core to margin, representing a retrograde hydrothermal alteration sequence. Barroisite, garnet, omphacite and epidote with minor chlorite, phengite, rutile and quartz constitute the peak metamorphic assemblage. In eclogite and garnet-blueschist, garnet shows an increase in Mg and Fe and decrease in Mn from core to rim. In chlorite in eclogite, Mg increases from core to rim. Inclusions of epidote, glaucophane, omphacite and quartz in garnet represent the pre-peak assemblage. Glaucophane also occurs profusely at the rims of barroisite. The matrix glaucophane and epidote represent the post-peak assemblage. The Fe³⁺ content of garnet-hosted omphacite is higher than that of matrix omphacite, and Fe³⁺ increases from core to rim in matrix glaucophane. Albite occurs in late stage veins. P – T pseudosection analysis indicates that the Naga Hills eclogites followed a clockwise P – T path with prograde metamorphism beginning at ∼1.3 GPa/525 °C and peaking at 1.7–2.0 GPa/580–610 °C, and subsequent retrogression to ∼1.1 GPa/540 °C. A comparison of these P – T conditions with numerical thermal models of plate subduction indicates that the Naga Hills eclogites probably formed near the top of the subducting crust with convergence rates of ∼ 55–100 km Myr⁻¹, consistent with high pre-collision convergence rates between India and Eurasia.     

苏北超高压变质带榴辉岩的对比性研究及成矿作用

苏北超高压变质带是秦岭—大别造山带的东延部分,所产出的榴辉岩有三种类型,分别为产于片麻岩中的G类榴辉岩、产于大理岩中的M类榴辉岩和产于蛇纹岩中P类榴辉岩。地球化学研究表明,三类榴辉岩的原岩复杂多样,源岩为下地壳或上地幔的基性-超基性岩,兼具大陆和大洋玄武岩的特征,富含TiO2等有用组分,是金红石矿床的成矿母岩。金红石矿床的形成是华北、扬子两大板块俯冲碰撞的结果,金红石成矿作用的强弱与岩性、构造、变质变形作用等密切相关。榴辉岩中含有金红石、钛铁矿、磷灰石、石榴子石、绿辉石等多种有用矿物,具有较高的综合利用价值。     

Petrogenesis and implications of jadeite‐bearing kyanite eclogite from the Sanbagawa belt (SW Japan)

Jadeite‐bearing kyanite eclogite has been discovered in the Iratsu body of the Sanbagawa belt, SW Japan. The jadeite + kyanite assemblage is stable at higher pressure–temperature (P–T) conditions or lower H₂O activity [a(H₂O)] than paragonite, although paragonite‐bearing eclogite is common in the Sanbagawa belt. The newly discovered eclogite is a massive metagabbro with the peak‐P assemblage garnet + omphacite + jadeite + kyanite + phengite + quartz + rutile. Impure jadeite is exclusively present as inclusions in garnet. The compositional gap between the coexisting omphacite (P2/n) and impure jadeite (C2/c) suggests relatively low metamorphic temperatures of 510–620 °C. Multi‐equilibrium thermobarometry for the assemblage garnet + omphacite + kyanite + phengite + quartz gives peak‐P conditions of ~2.5 GPa, 570 °C. Crystallization of jadeite in the metagabbro is attributed to Na‐ and Al‐rich effective bulk composition due to the persistence of relict Ca‐rich clinopyroxene at the peak‐P stage. By subtracting relict clinopyroxene from the whole‐rock composition, pseudosection modelling satisfactorily reproduces the observed jadeite‐bearing assemblage and mineral compositions at ~2.4–2.5 GPa, 570–610 °C and a(H₂O) >0.6. The relatively high pressure conditions derived from the jadeite‐bearing kyanite eclogite are further supported by high residual pressures of quartz inclusions in garnet. The maximum depth of exhumation in the Sanbagawa belt (~80 km) suggests decoupling of the slab–mantle wedge interface at this depth.