与金刚石原生矿有关的铬尖晶石形态特征

铬尖晶石是寻找金刚石原生矿的重要指示矿物之一,重砂测量中往往发现大量的铬尖晶石。单纯利用矿物化学成分判别它们是否与金刚石原生矿有关,电子探针测试工作量大、耗资高。如果根据显微镜下矿物形态特征鉴定与选择性的电子探针分析相互验证,将是一种既经济又简单、而且更可靠的判别方法。本文主要介绍与金刚石原生矿有关的铬尖晶石在显微镜下的形态特征。     

Magnetic properties of the Fe2SiO4-Fe3O4 spinel solid solutions

 Magnetic measurement of Fe_{3− x} Si _x O₄ spinel solid solutions indicates that their Curie temperatures decrease gradually, but not linearly, from 851 to 12 K with increasing content of nonmagnetic ions Si⁴⁺. Magnetic hysteresis becomes more noticeable in solid solutions having a larger content of Fe₂SiO₄. Saturation magnetizations of Fe_{3− x} Si _x O₄ samples increase up to x=0.357 and they are easily saturated in the field of H=0.1 T. However, magnetization of the sample of x=0.794 does not approach saturation even at high field of H=7.0 T and has a large coercive force. The Si⁴⁺ disordered distribution is confirmed to be ^tetr[Fe³⁺ _{1− x + x t} Si⁴⁺ _{x (1− t )}] ^octa[Fe²⁺ _{1+ x} Fe³⁺ _{1− x − x t} Si⁴⁺ _{x t} ] O₄ by the spin moment, which is consistent with site occupancy obtained from X-ray crystal structure refinement. Their molecular magnetizations would be expressed as M _B={4(1+x)+10xt}μ_B as functions of composition parameter x and Si⁴⁺ ordering parameter t of the solid solution. The sample of x=0.794 is antiferromagnetic below the Néel temperature, mainly due to the octahedral cation interaction M _O–M _O, while both M _T–M _O and M _O–M _O interactions induce a ferrimagnetic property. Concerning magnetic spin configuration, in the case of x>0.42, the lowest dɛ level becomes a singlet, resulting in no orbital angular momentum. Received: 20 April 2000 / Accepted: 11 September 2000     

Provenance analysis of detrital monazite,zircon and Cr‐spinel in the northern Tibetan Plateau: Implications for the Paleozoic tectonothermal history of the Altyn Tagh and Qimen Tagh Ranges

Sediment provenance studies have proven to be an effective method to extract the sediment provenance and tectonic process information recorded by detrital minerals. In this contribution, we conducted detrital monazite and zircon U‐Pb geochronology and detrital Cr‐spinel major element chemistry analyses on samples from the Qaidam Basin to reconstruct the spatial and temporal evolution of the Altyn Tagh Range and the Qimen Tagh Range in the northern Tibetan Plateau. Based on the significant variation in [Th/U]_N, [Gd/Lu]_N and [Eu/Eu*]_N and the U‐Pb ages of the monazite and zircon, the South Altyn Tagh subduction‐collision belt and the North Qimen Tagh Range were, respectively, the main provenances of the Ganchaigou section and the Dongchaishan‐Weitai section in the Qaidam Basin in the Cenozoic. Paleozoic peak metamorphism, retrograde granulite‐facies metamorphism and amphibolite‐facies metamorphism in the South Altyn Tagh subduction‐collision belt were well recorded by the detrital monazite. In comparison, the detrital zircon is a better indicator of igneous events than detrital monazite. Synthesizing the detrital monazite, zircon and Cr‐spinel data, we concluded that the South Altyn Tagh Ocean and Qimen Tagh Ocean existed in the early Paleozoic and that the Altyn Tagh terrane and Qimen Tagh terrane experienced different Paleozoic tectonothermal histories. The collision between the Qaidam terrane and the Azhong terrane occurred at ca. 500 Ma. The Middle Ordovician was the key period of transformation from the collision‐induced compressional environment to an extensional environment in the area of the South Altyn Tagh Range. In the early Paleozoic, the Qimen Tagh area was characterized by the subduction of oceanic crust.     

扬子地块东段大陆岩石圈地幔的氧逸度

由尖晶石相橄榄岩包体中的矿物化学成分，采用新近校准的ＦＦＭ地质氧逸度计和地质温－压计，计算包体的平衡氧逸度，Δｌｏｇ（ｆＯ２）ＦＭＱ＝－３．３２－０．１２，它反映了扬子地块东段大陆岩石圈地幔的氧化还原状态。两种氧逸度计计算结果相差在０．５ｌｏｇｆＯ２单位内。     

雅鲁藏布江缝合带白朗县白岗尖晶石—石榴子石相二辉橄榄岩的相界反应及其意义

西藏白朗县白岗村蛇绿混杂岩中有一罕见的尖晶石石榴子石二辉橄榄岩小岩块,被松软的蛇纹岩化尖晶石二辉橄榄岩包裹其中。岩块中发育有碎基单斜辉石、斜方辉石中出溶单斜辉石、切过出溶单斜辉石的贯入单斜辉石和外来碎粒单斜辉石及钙质辉石+铬尖晶石→钙铁石榴子石相界反应。同时,在岩块和包壳岩石的橄榄石中出现针状硅镁石出溶物。计算这些矿物的温度压力表明,它们的温度压力都处于>800℃,>1.8GPa以上的地幔石榴子石域超高压环境,而且,经历过一个上升→俯冲→上升的"N"字形历程。     

Chrome spinel in normal MORB‐type greenstones from the Paleozoic–Mesozoic Mino terrane,East Takayama area,central Japan: Crystallization course with a U‐turn

Phenocrystic chrome spinel crystallized in normal MORB‐type greenstones in the East Takayama area. Associated phenocryst minerals show a crystallization sequence that was olivine first, followed by plagioclase, and finally clinopyroxene. Chrome spinel ranges from 0.54 to 0.77 in Mg/(Mg+Fe²⁺) and 0.21 to 0.53 in Cr/(Cr+Al); the Fe³⁺ content varies from 0.07 to 0.22 p.f.u. (O = 4). Significant compositional differences of spinel were observed among the phenocryst mineral assemblages. Chrome spinel in the olivine–spinel assemblage shows a wide range in Cr/(Cr+Al), and is depleted in Fe²⁺ and Fe³⁺. Chrome spinel in the olivine–plagioclase–clinopyroxene–spinel assemblage is Fe²⁺‐ and Fe³⁺‐rich at relatively high Cr/(Cr+Al) ratios. Basalt with the olivine–plagioclase–spinel assemblage contains both aluminous spinel and Fe²⁺‐ and Fe³⁺‐rich spinel. The assumed olivine–spinel equilibrium suggests that chrome spinel in the olivine–spinel assemblage changed in composition from Cr‐ and Fe²⁺‐rich to Al‐ and Mg‐rich with the progress of fractional crystallization. Chrome spinel in the olivine–plagioclase–clinopyroxene–spinel assemblage, on the other hand, exhibits the reversed variations in Mg/(Mg+Fe²⁺) and in Cr/(Cr+Al) ratios that decrease and increase with the fractional crystallization, respectively. The entire crystallization course of chrome spinel, projected onto the Mg/(Mg+Fe²⁺)–Cr/(Cr+Al) diagram, exhibits a U‐turn, and appears to be set on a double‐lane route. The U‐turn point lies in the compositional field of chrome spinel in the olivine–plagioclase–spinel assemblage, and may be explained by plagioclase fractionation that began during the formation of the olivine–plagioclase–spinel assemblage.     

南天山榆树沟麻粒岩地体的尖晶石研究

新疆榆树沟麻粒岩地体中发育两类尖晶石：一类见于中、基性麻粒岩体中,其化学成分富 Ａｌ 贫 Ｃｒ ,属铝尖晶石,镜下为深绿色,呈半自形至他形粒状,与其它变质矿物共生,表现为麻粒岩相的新生变质矿物;另一类发育在空间上与麻粒岩体紧密相邻的超镁铁质岩体中,为铬尖晶石,镜下为深褐红色,呈不规则粒状分布于橄榄石、斜方辉石和单斜辉石之间,为麻粒岩相变质过程中稳定的残余矿物。后者属于 Ｄｉｃｋ 等人划分的 Ｉ 型尖晶石,它的存在说明超镁铁质岩体为大洋岩石圈地幔的组成部分。这两类尖晶石的特征一方面说明该地体遭受了麻粒岩相的变质作用改造,另一方面也提供了榆树沟麻粒岩相蛇绿岩套属洋盆构造环境的直接矿物学证据。     

Ultra-high-temperature metamorphism in Central Brazil: the Barro Alto complex

The Barro Alto complex, central Brazil, is a layered mafic–ultramafic intrusion, which was subjected to granulite facies metamorphism during the Neoproterozoic. Ultra-high-temperature conditions are recorded by parageneses that occur in some lenses of quartz-bearing rock (metagranite, metapelite and impure quartzite). The peak paragenesis consists of spinel+quartz±cordierite±leucosome (recording the former presence of melt with quartz in excess), which is replaced by either orthopyroxene+sillimanite or garnet+sillimanite. Quartz+biotite±sillimanite±garnet symplectites are ubiquitous and indicate reactions between Fe–Mg phases and melt. Late kyanite porphyroblasts have overgrown these symplectites. The direct replacement of spinel+quartz±cordierite by orthopyroxene+sillimanite or garnet+sillimanite occurred around the [Sa] invariant point, which appears only in a petrogenetic grid with inverted topology. The topology inversion occurs at conditions of high oxygen fugacity or due to the presence of ZnO-bearing spinel. Minimum peak conditions of ultra-high-temperature metamorphism were calculated as c. 980 °C and c. 7.9 kbar. The succession of observed mineral textures can be explained by a near-isobaric cooling P–T  path, with a cooling stage occurring between c. 980 and 750 °C.     

Point defects and cation tracer diffusion in (Ti x Fe 1?x ) 3?δ O4 1. Non-stoichiometry and point defects

 The deviation from stoichiometry, δ, in spinel solid solutions of the type (Ti _x Fe _1−x )_3−δ O₄ with x=0.1, 0.2 and 0.25 was studied thermogravimetrically as a function of oxygen activity, a _O2, at 1100, 1200 and 1300 ^∘C. The experimental results, S-shaped curves for δ vs. log a_O2, are presented and discussed with regard to the type of point defects prevailing under different conditions in the deviation from stoichiometry. It is concluded that cation vacancies are the predominant point defects at high oxygen activities, while cation interstitials prevail at low oxygen activities. The temperature and composition dependencies of point defect concentrations are also discussed. Received: 1 October 1996 / Accepted: 15 September 2002 Acknowledgements The authors thank the US Department of Energy for support of this work under Grant no. DE-FGO2–88ER45357. This work made use of the Cornell Center of Materials Shared Experimental Facilities, supported through the National Science Foundation Materials Research Science and Engineering Centers program (DMR-0079992).