Toxicities of p-nitrotoluenes and their effects on blood corpuscles and ovaries in Crusian carps (Carassius auratus)

p-nitrotoluene is an important organic intermediate widely used in pesticide, foamed plastics, dyestuff and medicine industries. In this paper, Crusian carps (Carassius auratus) were exposed to dilute p-nitrotoluene solutions with different concentrations of 0, 20, 40, 80, 120, 160, 240 and 320 μg/L; the subsequent physiological responses to the chemical were observed, and the variation characteristics of blood corpuscles, ovaries and oocytes were studied by bio-microscopy. Results showed that even very low concentrations of p-nitrotoluene would lead to toxicosis and even the death of Carassius auratus. The bio-microscopic structures revealed that, compared with the compartment of Carassius auratus growing in the p-nitrotoluene-free water (the control group), the lower concentrations of p-nitrotoluene (for example no more than 80 μg/L) would result in the faster disintegration of erythrocytes and the significant enlargement of oocytes, while the higher contents of p-nitrotoluene (no less than 240 μg/L in this case) would inhibit the division of cells and their further growth, even degenerate blood corpuscles and ovaries, suggesting stronger estrogenic activities. The study is financially supported by the Development Foundation of Science and Technology under Shandong Provincial Education Department (No. J05D51).     

Experimental research on a new encapsulated heat-generating hydraulic fracturing fluid system

1 IntroductionFracturing plays an important role in increasingthe production and injection and enhancing the final re-covery of oil and gas. At present, the use of ahydroxypropyl guar gum, borate-crosslinked, hydraulicfracturing fluid systemhas become ext…     

旧供水井化学处理方法介绍--以加德满都市旧供水井修复为例

本文以加德满都市旧供水井修复项目为例,针对因滤水管缝隙被化学物质堵塞,导致井出水量逐年减少的旧供水井。通过井下电视摄像系统检查,采用六偏磷酸钠、氨基黄酸等有机酸,结合刷洗、高压喷射等机械方法进行处理,使旧供水井出水量得到明显提高。     

利用钻孔超声成像的图像特征进行岩石风化程度分类

钻孔超声成像方法能精确地反映井壁的光滑情况, 进而判断岩石的风化发育程度, 确定风化层的厚度。阐述了钻孔超声成像的走时和振幅图像特征, 给出了1个在香港地区的应用实例。     

水库下游河流再造床过程中的河岸侵蚀

根据实测河道地形资料,分析了水库下游河床演变中的河岸侵蚀现象,包括不同横向边界约束条件、不同床沙组成和不同河型河段的河岸侵蚀的特征及规律。结果表明:①水库下游均会有河岸侵蚀发生,但初期一般以下切为主,后期以展宽为主。②对于横向边界约束较强的河段,河岸侵蚀相对较弱;相反,则河岸坍塌严重,河岸侵蚀强烈;③对不同的河床组成和边滩组成的河段:河床较粗特别是形成抗冲粗化层,且边滩组成较细的河段,河岸侵蚀现象非常剧烈;河床组成较细的河段,如果边滩抗冲性较强,则河岸侵蚀现象相对较弱,如果滩地组成较细、容易坍塌,河岸侵蚀也会较强;④不同的河型有着不同的河岸侵蚀现象。分汊河段以主汊为主;游荡段的游荡特性在初期受到抑制;弯曲河段的撇弯切滩现象较普遍。     

吐哈盆地侏罗纪煤中主要组分结构特征与生烃性分析

在高纯度煤岩显微组分分离富集的基础上,应用透射式显微傅里叶红外光谱技术 (Micro FTIR),对吐哈盆地侏罗纪煤中的主要组分-镜质体、丝质体、角质体、藻类体的结构组成进行了测定。结果表明 :藻类体主要由长链脂族结构组成,芳香结构含量相对较少;角质体和基质镜质体中含有较丰富的芳香结构以及长链脂族结构;而丝质体则主要由芳香结构组成,脂族结构含量很少。显微组分的这种结构特征决定了藻类体具有很高的生烃潜力、角质体和镜质体的生烃潜力中等、而丝质体的生烃潜力则很低。对于吐哈盆地煤成油来说,由于藻类体主要由长链脂族结构组成,并且生烃潜力也高,因此其具有高的液态烃产率、丝质体的产油率最小、角质体和镜质体的液态烃产率中等。由于镜质体是本区煤中含量最高的组分。因此,对于吐哈盆地所形成的具有工业规模的油田来说,镜质体应该是主要的贡献组分之一。但对于富含藻类体的厚层状烛藻煤,由于它类型好,品质高、生烃潜力大、以中长链脂族结构为主,是煤成油最理想的源岩。     

The effect of rock moisture on Schmidt hammer rebound: tests on rock samples from Marion Island and South Africa

In an assessment of the influence of internal rock moisture content on Schmidt hammer readings, rebound (R) values are found to decrease with increasing moisture content. For samples of basalt, sandstone and dolerite the maximum decrease in R‐values is found between oven dry values and saturated rock rebound values, the magnitude of which varies from 2 to 10 points on the R‐scale. A quartzite block has the greatest decline of 6 points at 60 per cent saturation. For certain rock types under differing site‐to‐site field moisture conditions the moisture effect can be a significant factor in the interpretation of the relative state of weathering from rebound values. Copyright © 2002 John Wiley & Sons, Ltd.     

25～75℃酸性NaCl溶液中方铅矿的溶解动力学

在25～75℃、pH=0.43～2.45的1mol/LNaCl溶液中进行了方铅矿的溶解动力学实验。发现在远平衡条件下,方铅矿的溶解速率r与氢离子活度犤H+犦呈线性关系,溶解速率方程(速率定律)为:r=k犤H+犦,即对H+而言,溶解反应为一级。其中速率常数k为2.344×10-7mol/m2·s(25℃)、1.380×10-6mol/m2·s(50℃)、7.079×10-6mol/m2·s(75℃)。溶解反应的活化能为43.54kJ/mol,方铅矿的溶解机理为表面化学反应,速率决定步骤为表面配合物的离解。     

三类高强度悬式瓷绝缘子的成分和物相分析

为探讨高原牌70kN和进口120，210kN瓷绝缘子的成分和结构性能，中采用原子吸收光谱（AAS）和X射线衍射（XRD）方法，对三类产品进行了检测。结果表明，有效成分除K2O外，70kN和210kN的SiO2,Al2O3,Fe2O3含量接近，主晶相基本相同，有刚玉，莫来石、石英和长石等；结晶相总量：70kN35%，120kN40%,210kN48%，这表明机械强度愈大，结晶相含量愈高，只需调整70kN原样的部分成分，粒度和工艺，即生产出高等级（如210kN)瓷绝缘子。     

柱撑粘土矿物层间域的性质及其环境意义

柱撑粘土矿物是近年来胺国内外矿物学广泛关注的矿物材料之一。柱撑粘土矿物层间域是一个特殊的化学反应场所。本系统评述了氮氧化物、重金属离子、阴离子、肥料养分及有机污染物等环境污染物在柱撑粘土矿物层间域中的催化还原、吸附、脱附、控释及光催化反应机理，着重阐述了柱撑粘土矿物的层间域性质，讨论了它们的环境化学行为对环境的影响和意义。