云南磷铝石谱学特征研究

使用电子探针、X射线粉晶衍射仪、傅里叶变换红外光谱仪、激光拉曼光谱仪、紫外可见分光光度计等仪器,对最近在云南发现的一种达到宝石级别的磷铝石进行了化学成分、矿物组成、红外吸收光谱、拉曼光谱、紫外可见吸收光谱等方面的研究。化学成分分析结果表明,该磷铝石的主要化学成分为P和Al,并含有少量的Fe和V;X射线粉晶衍射结果显示,该磷铝石的矿物成分主要为磷铝石,杂质较少;红外光谱与拉曼光谱分析均检出磷酸根基团的特征峰,红外光谱分析还显示有结晶水与结构水的存在;紫外可见吸收光谱在300和420 nm附近的吸收归属于Fe3+,630 nm附近较宽缓的吸收带由Fe3+和V3+共同产生。并将磷铝石与绿松石进行了谱学方面的对比分析,以便更好地区分两者。     

缅甸与莫桑比克红宝石的元素含量及紫外可见光谱学特征对比研究

采用镜下观察、激光剥蚀电感耦合等离子体质谱、紫外-可见吸收光谱等观察测试方法,对缅甸和莫桑比克红宝石的常规宝石学、包裹体、化学元素含量及紫外光谱特征进行了系统的对比研究。结果表明,缅甸红宝石在紫外荧光灯下呈现较强的红色荧光,内部含有互为60°夹角定向排列的短针状金红石、"糖浆状"构造等特征包裹体,具有低Fe、高V、高Ga的微量元素特征,紫外区吸收截止边小于320 nm,且694 nm处的荧光较强。莫桑比克红宝石在紫外荧光灯下荧光较弱,内部可见双晶面、无序排列的金红石和角闪石晶体等特征包裹体,具有高Fe、低V、低Ga的微量元素特征,紫外区吸收截止边在350 nm附近。上述性质可用作区分缅甸和莫桑比克红宝石的标志性识别特征。     

Comparative Study of Acid and Alkaline Stimulants with Granite in an Enhanced Geothermal System

The Enhanced Geothermal System (EGS) is an artificial geothermal system that aims to economically extract heat from hot dry rock (HDR) through the creation of an artificial geothermal reservoir. Chemical stimulation is thought to be an effective method to create fracture networks and open existing fractures in hot dry rocks by injecting chemical agents into the reservoir to dissolve the minerals. Granite is a common type of hot dry rock. In this paper, a series of chemical stimulation experiments were implemented using acid and alkaline agents under high temperature and pressure conditions that mimic the environment of formation. Granite rock samples used in the experiments are collected from the potential EGS reservoir in the Matouying area, Hebei, China. Laboratory experimental results show that the corrosion ratio per unit area of rock is 3.2% in static acid chemical experiments and 0.51% in static alkaline chemical experiments. The permeability of the core is increased by 1.62 times in dynamic acid chemical experiments and 2.45 times in dynamic alkaline chemical experiments. A scanning electron microscope analysis of the core illustrates that secondary minerals, such as chlorite, spherical silica, and montmorillonite, were formed, due to acid-rock interaction with plagioclase being precipitated by alkaline-rock interactions. Masking agents in alkaline chemical agents can slightly reduce the degree of plagioclase formation. A chemical simulation model was built using TOUGHREACT, the mineral dissolution and associated ion concentration variation being reproduced by this reactive transport model.     

不同地质建造类型的生态环境功能特征——以西昌地区为例

地质建造背景可以直接反映该地区的形成演化过程、物质组成和地理条件,直接或间接地影响基岩上的生态环境。小范围内生态环境效应由地质建造直接控制,再由不同的气候条件、人类活动进行改造。土壤中的营养元素基本继承于母岩,而气候条件和人类活动同样会对土壤的物理性质、化学性质形成扰动。以中国地质调查局生态地质调查工程之大凉山区生态地质调查项目为依托,以沉积建造特征、空间分布、大地构造属性等因素为基础,将西昌地区划分为11个地质建造单元。通过详细的野外调查和数据分析,对西昌地区不同地质建造单元进行研究,认为建造单元上的生态地质环境存在明显的差异性,地质建造背景直接制约了成土母质及土壤的物理化学性质,营养元素在成土母质和土壤之间的迁移存在明显的继承性。同时,不同的地质建造单元和不同的地理地貌特征共同决定了不同地质建造单元的生态功能属性。研究成果为下一步开展生态地质调查提供依据和思路。     

土壤环境中化学定时炸弹的研究现状与展望

土壤环境中的化学定时炸弹对生态环境乃至人类自身危害极大,国内外均有大规模发生化学定时炸弹的实例,但是,由于其不易发现而常常被忽略,这将造成更为严重的后果。化学定时炸弹的分类问题比较复杂,目前较为妥当的做法是对各种分类方案进行有益的探索。化学定时炸弹的触爆机制研究十分重要,是进行地球化学灾害评价、预测和防治的基础;地球化学工程技术是将来预防和治理化学定时炸弹最主要手段。从科学的严密性和严肃性考虑,化学定时炸弹的概念应该由具有更深刻内涵和更广泛外延的“缓变型地球化学灾害”来替代。     

额济纳绿洲沙尘暴沉积特征

1 Introduction Oases are unique ecosystems and important residences for our ancestors in arid and semiarid regions of the world, and have deeply been imprinted by human actions, such as Jericho oasis of Jordan Valley, Jarmo oasis of the Euphrates River an…     

Middle-high latitude N2O distributions related to the Arctic vortex breakup

The relationship of N2O distributions with the Arctic vortex breakup is first analyzed with a probability distribution function （PDF） analysis. The N2O concentration shows different distributions between the early and late vortex breakup years. In the early breakup years, the N2O concentration shows low values and large dispersions after the vortex breakup, which is related to the inhomogeneity in the vertical advection in the middle and high latitude lower stratosphere. The horizontal diffusion coefficient （Kyy） shows a larger value accordingly. In the late breakup years, the N2O concentration shows high values and more uniform distributions than in the early years after the vortex breakup, with a smaller vertical advection and Kyy after the vortex breakup. It is found that the N2O distributions are largely affected by the Arctic vortex breakup time but the dynamically defined vortex breakup time is not the only factor.     

Chemical Composition of Ancient Celadon Material （1127-1279 A.D.） from Zhejiang, China and Its Implication

The microprobe EDXRF equipment was used for analysis of the major and trace elements in glaze layer-transitive layer-body layer of the celadon from the Altar Yao （Kiln） and Laohudong Yao in the Southern Song Dynasty （1127-1279 A.D.）, Zhejiang, China. The K values of the discriminant factor for the celadon wares are larger than 8, which means the celadon of the Altar Yao and Laohudong Yao are different from that of the Longquan Yao. The former two belong to the Guan Yao system （the Chinese imperial kilns）, but the latter to the Min Yao system （the Chinese popular kilns）. The principle component analysis shows their relationship between the Altar and Laohudong wares with provenance postulation. The thickness of the transitive layer in the Altar and Laohudong wares is obviously different, which reveals the microstructure characteristics of the celadon even though both kinds of wares belong to the imperial kiln system.     

南海西南部晚更新世以来元素地球化学特征的古环境意义

对南海西南部近湄公河三角洲中陆坡上的MD01-2392站样品进行的地球化学分析表明,该站的沉积物主要为湄公河带来的陆源碎屑,并且其物源四十万年来没有发生明显变化。分别用元素TiO2、CaO估算出沉积物中陆源碎屑的含量及CaCO3的含量,结果显示CaCO3在间冰期时高,而在冰期时低,表现出“大西洋旋回”的特征。陆源碎屑含量与CaCO3含量相反,显示出南海CaCO3旋回属于稀释旋回。元素的Ti标准化值表明,该站沉积物源区在冰期时化学风化弱,而在间冰期时相对较强,说明间冰期时物源区存在相对温暖湿润的气候环境。     

入园率视角下长三角地区化工产业时空格局演化及影响因素

本文以全国化工产业密集区——长三角地区为例,基于规模以上中国工业企业详细数据,从化工企业入园率的视角出发,综合运用均值中心、标准差椭圆、核密度分析及空间自相关等分析方法,分析并揭示了1998—2013年长三角地区化工产业时空格局演化规律及影响因素。研究结果表明：1998—2013年长三角地区化工企业总体上呈现不断增长趋势,入园率由6.19%提升到36.98%;化工企业“西北-东南”方向分布明显,且近似呈“先东南,后西北”的路径迁移规律,较之全部企业,入园企业具有更高的离散度、更大的迁移幅度,入园企业与全部企业逐步由空间失配演变为空间匹配;中心集聚与外围扩散态势并存,发育并逐渐形成了环太湖集聚区、沿杭州湾集聚区、沿长江密集带及沿海密集带四大化工产业集聚片区,化工产业的区域空间结构趋于复杂化、有序化与稳定化;地级尺度上化工企业入园率不断提升,2003年与2013年呈显著的空间正相关,热点区逐渐由浙江东南转移到苏皖北部,冷点区从安徽北部迁移到浙江西北,基本完成了空间格局上的对称反转变换,但化工企业入园率与空间密度分布一直处于错配失衡状态。通过结合化工产业特性与长三角区域特征,定性探讨了长三角地区化工产业时空格局演化的影响因素,特别是阐述了化工产业“园区化”进程的作用机制。