东营凹陷沙三段烃源岩中火成岩岩石学特征分析

东营凹陷沙三段烃源岩中发现一些规模不大的玄武岩和辉长岩体。通过对其岩性及产状、岩石化学和地球化学元素分析，认为研究区玄武岩是碱性－亚碱性橄榄玄武岩；辉长岩的岩石化学和微量元素组成与上述玄武岩相似，认为它们具有同源性，只是辉长岩没有喷发到地表而被封存在刚刚沉积下来的沙三段烃源岩中。水下喷溢的玄赋岩对烃源岩的沉积和生烃演化具有促进作用，辉长岩可以造成局部烃源岩的热变质作用。     

Observations of wind and waves in the central Bay of Bengal during BOBMEX-99 and their effect on mixed layer depth variability due to forced mixing

Time-series wind and wave measurements were carried out onboard INS Sagardhwani in the central Bay of Bengal during BOBMEX-99. Various other marine meteorological and oceanographic measurements relevant to monsoon studies were also collected simultaneously. The observed variations of wind and waves and the associated mixed layer depth (MLD) variability based on both temperature and density criteria at 3 hourly intervals are presented in this paper as a case study. At the time-series location (13‡N, 87‡E) wind varied between 6 and 16m/s and the predominant direction was southwesterly. The significant wave height and period varied from 1.9 to 3.7m and 8 to 13 s respectively. Some of the available statistical predictive methods for the determination of MLD by forced mixing are utilized to test the extent of mechanical mixing within the top layer of water by the local wind and wave activity. The same is extended to formulate a new empirical relation for gross estimation of effective depth within which the sound energy is generally trapped during its transmission in the surface duct. The present analysis aiming for estimation of observed MLD variability (35 to 75 m) using the suggested simple empirical relation reveals that, the mixed layer variability observed during the experiment depends on both local ocean variability as well as remote forcing as reported earlier.     

Radiaxial fibrous calcites as low-magnesian calcite cement precipitated in a marine-meteoric mixing zone

Abstract Radiaxial fibrous calcite (RFC) has previously been interpreted as a marine or replacive cement. Study of the Dongjeom Formation (Early Ordovician), Korea, shows that RFC can form in marine‐meteoric mixing zones as a low‐magnesian calcite (LMC) cement. RFC in the shallow‐marine Dongjeom Formation occurs in arenaceous limestones at the top of a transgressive facies overlying a regressive facies. It shows well‐developed growth zonation, and lighter oxygen isotope values and more radiogenic strontium isotope ratios than those of Early Ordovician marine calcite. Such petrographic and chemical evidence indicates that the RFC was precipitated as a primary LMC cement in a marine and meteoric mixing zone. Owing to the unique environment of formation, the Dongjeom RFC is characterized by growth zonal fabric comprising alternating subzones, which may indicate precipitation from varying fluids. In addition, this study documents the importance of substrate for development of RFC. Early ‘nucleation’ for RFC occurred mainly on microcrystalline skeletal grains and internal sediments, whereas on homogeneously altered substrates, thin‐coated banding structure developed, ultimately forming coarse crystalline spar. This suggests that microcrystalline substrates are preferred sites for nucleation of RFC.     

A New Digestion and Chemical Separation Technique for Rapid and Highly Reproducible Determination of Lu/Hf and Hf Isotope Ratios in Geological Materials by MC-ICP-MS

A new digestion procedure and chemical separation technique has been developed for measurement of Lu/Hf and Hf isotope ratios that does not require high‐pressure bombs or use of HF or HClO₄ acids. Samples are digested in dilute HCl or HNO₃ after flux‐fusion at 110 0 °C in the presence of lithium metaborate. High field strength elements (HFSE) and rare earth elements (REE) are separated from this solution by co‐precipitation with iron hydroxide. The dissolved precipitate (in 2 mol l^?1 HCl) is loaded directly onto a standard cation exchange column which separates remaining sample matrix from the heavy REE (Lu+Yb), and the middle‐light REE and HFSE (Hf). The middle‐light REE and individual HFSE are then separated (10.5, 9 and 6 mol l^?1 HCl) using a miniaturized column containing TEVA spec resin which provides a REE‐, Ti‐ and Zr‐free Hf cut. This chemical separation scheme can also be readily adapted for isotopic analysis of the Sm‐Nd system and/or the other HFSE (Ti, Zr). Total procedural blanks for this technique are < 10 0 pg and < 2 pg for Hf and Lu, respectively, even when digesting large (0.5 g) samples. We present data from replicate digestions of international rock reference materials which demonstrate this technique routinely reproduces Lu/Hf ratios to < 0.2% (2s) and ¹⁷⁶ Hf/¹⁷⁷ Hf isotope ratios to < 30 ppm (2s). Moreover, the technique is matrix‐independent and has been successfully applied to analysis of diverse materials including basalts, meteorites, komatiites, kimberlites and carbonatites. The relative simplicity of this technique, coupled with the ease of digestion (and sample‐spike equilibration) of large difficult‐to‐dissolve samples, and the speed (2 days) with which samples can be digested and processed through the chemical separation scheme makes it an attractive new method for preparing samples for Lu‐Hf isotopic investigation.     

海南岛晚中生代壳幔岩浆混合作用--来自闪长质淬冷包体的证据

对海南岛屯昌花岗闪长岩中的闪长质淬冷包体进行了较详细的研究。岩石和岩石地球化学特征均显示包体是由来自地幔的高温镁铁质岩浆注入地壳长英质岩浆混合而成，是深部壳幔岩浆混合作用的岩石学记录。它表明海南岛自中晚侏罗世以来发生的岩石圈伸展—减薄—双峰式构造岩浆作用于白垩纪达到了鼎盛阶段。     

西秦岭温泉花岗岩岩石化学特征及岩浆混合信息

西秦岭温泉岩体是壳幔混浆的产物。寄主岩石以贫CaO富FeOtot为特征 ,ANKC值大于 1 1 ,NK A值均小于 0 9,属铝过饱和钙碱性系列岩石 ,系上地壳碎屑岩类熔融而成。基性端元暗色微细粒镁铁质包体及基性岩墙 ,高Na2 O及K2 O ,而贫FeOtot。两类岩浆混合形成的混浆花岗岩 ,岩石地球化学介于两个端元并有显著的过渡特征和依从关系反映了重要的岩浆混合信息     

Geochemical－Sequence Stratigraphy and Its Application Prospects in Lake Basins

As a useful approach for hydrocarbon exploration,the sequence stratigraphy has been commonly accepted.The concepts of sequence and parasequence provide a state-of -the-artframe-work for studying the distribution and characters of depositional system,and analyzing the occurrence,distribution,characteristics of source,reservoir and seal-play elements.The newly-developed geochemical -sequence stratigraphy focuses mainly on the occurrence,distribution and characters of source rocks and reservoir hydrocarbons within a chronostratigraphic framework,Integrated with sequence wtratigraphy,geochemistry can be used to study the surce rock potential within a sequence wtratigraphic framework and to describe the characteristics of hydrocarbons accumulated in reservoirs,which were predicted by way of sequence stratigraphy.The concept of geochemical-sequence wtratigraphy was proposed by Peters et al.(2000).Constructing a reliable sequence stratigraphic framework is the basis of geochemical-sequence wtratigraphic study although it is not the main goal.High-resolution biomarker analysis is critrical to the construction of a geochemical-sequence stratigraphic model.The geochemical-stratigraphic study involves mainly:(1) the distribution and geochemical characteristics of source rocks with relative sea (lake)-level change;(3) to prodict if these reservoirs bear hydrocarbons and their geochemical features;(4) to be used to construct the time-stratigraphic framework.This paper also summarizes the lake basin types,and introduces their facies associatons,source potential and organic geochemical features.At the end,the authors offer some suggestions about how to carry out geochemical-sequence stratigraphic study in ladcustrine strata.     

岩石中铅和锌的分离与测定

将KHSO4加入在小体积(1mL)试液中,以K2SO4·PbSO4复盐形式沉淀分离Pb,再用NH4Ac溶液热提Pb,1mgPb的平均回收率为100.66%;滤液再蒸至1mL小体积,加入NaCl NaOH小体积两次沉淀分离Fe、Ti、Mn等干扰元素,存在于滤液中的Zn平均回收率为100.5%。分离所得的含Pb2+和Zn2+的溶液用EDTA分别进行滴定,测定范围(质量分数,w)由0.5%下延至0.01%;测定结果与极谱法相一致;精密度(RSD,n=10)试验Pb为2.6%,Zn为1.4%。     

论盐矿化学分析项目的合理选择

盐矿化学分析 ,对研究盐矿组分全貌 ,分析盐类沉积阶段 ,评价盐矿质量 ,制订采卤工艺等方面都是极其重要的手段。依据多年来从事探盐找钾工作的实践经验 ,对盐矿所含易溶、难溶两种盐类组分 ,提出了水溶和酸溶两个系统的分析 ,并针对不同类型盐矿的化学分析项目进行了合理选择     

内蒙古乌审旗板户梁方沸石岩矿特征及开发应用前景

内蒙古乌审旗板户梁方沸石岩矿赋存在下白垩统志丹群洛河组二段二亚段紫红色泥岩和方沸石泥岩中,矿体呈近水平层状产出,为内蒙古地区乃至国内少见的大型矿床。方沸石是沸石族矿物的一种,具有独特的理化特征,可被广泛应用于工业、农业、建筑业、化工业、废水处理等方面。