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Surface Tension Effects of Humic-Like Substances in the Aqueous Extract of Tropospheric Fine Aerosol 总被引:1,自引:0,他引:1
Gyula?KissEmail author Etelka?Tombácz Hans-Christen?Hansson 《Journal of Atmospheric Chemistry》2005,50(3):279-294
Organic aerosol constituents can influence the surface tension of nucleating cloud droplets and thereby modify the critical supersaturation necessary to activate aerosol particles. Model calculations, based on experiments carried out with different surrogates, led to contradictory conclusions on the effect of organic components on activation, indicating that the results depend very much on the surrogate selected. In order to reduce this uncertainty surface tension measurements were performed on real atmospheric aerosol components. Humic-like substances (HULIS) that accounted for 60% of the water-soluble organic carbon present in rural aerosol were isolated from 32 samples covering different seasons. The isolated organic matter present in a concentration of about 1 g L–1, decreased the surface tension of the aqueous solutions by 25–42% as compared to pure water. This effect was further enhanced when humic-like substances were mixed with ammonium sulphate. In order to support model calculations Szyskowski functions were fitted to the data to formulate the surface tension effect as a function of concentration.Finally, natural humic substances (fulvic and humic acids) were investigated under the same conditions. The experiments revealed that the surface tension decreasing effect of atmospheric humic-like substances differed from that of the studied terrestrial and aquatic humic substances: the latter substances decreased the surface tension of the aqueous solution to a lesser extent (7–23%) than atmospheric HULIS. This deviation can be explained with the different composition (e.g. the ratio of aromatic to aliphatic moieties) of the substances investigated. 相似文献
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Jim Mungall 《中国科学D辑(英文版)》2005,48(6):834-839
There are a lot of mafic and ultra-mafic bodies in the earth,but only a few of them include Cu-Ni-PGE deposits.Of interest has been the formation of such deposits as Cu-Ni-PGE sulfide;especially the separa-tion of sulfide liquid from silicate melts.A lot of re-searcher[1—11]have investigated into the tectonic back-ground of Cu-Ni-PGE deposits,the mechanism of the origin and evolution of magma,and the metal element partition coefficient in sulfide liquid and silicate magma.However,the da… 相似文献
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论文以平-阿高速公路K29+024.5~K29+210.5段高边坡病害整治工程为例,介绍其整治工程措施及施工技术。包括预应力锚索框架梁、预应力锚索地梁、护面墙等,并对制作锚索、搭设工作平台、锚索孔成孔、锚索安放入孔、注浆、锚索框架、锚索地梁、张拉锁定、封锚头、拱形护坡、护面墙及排水沟整治施工工艺进行了总结。结果表明,采用以预应力锚索框架梁、地梁为主的边坡整治措施,可使边坡潜在滑坡体的自重力在预应力锚索施工的外力作用下均匀分布在边坡上,从而使边坡处于稳定状态,这种边坡病害整治地形、地质条件适应力强.施工条件易得到满足,具有良好的技术经济效果。 相似文献
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