Natural background levels and threshold values of monitored parameters in the Cambrian-Vendian groundwater body,Estonia

The Cambrian-Vendian groundwater body plays an important role in drinking water supply of capital Tallinn and other settlements in northern Estonia. Water quality in this deep-seated confined groundwater body is influenced by the intrusion of present-day seawater and pumping-induced upward migration of deeper saline groundwater. The aim of this study is to evaluate the threshold values applying the methodology worked out within the EU 6th FP project “Background criteria for the identification of groundwater thresholds (BRIDGE)” and to compare the results with the values proposed by local authorities. A database containing 250 monitoring points was completed and used for the calculation of natural background levels (as the 90 and 97.7 percentile) in groundwater. The calculation of threshold values is based on natural background levels and reference values. In case of Cambrian-Vendian groundwater body the receptor is drinking water, thus limit values set by Estonian drinking water standard were used as reference values. The threshold values proposed by local authorities are more or less the same as calculated by BRIDGE methodology. Exceptionally different values are derived in case of chloride and ammonium.     

大亚湾沉积物中重金属元素背景值研究

根据大亚湾的自然条件认为,大亚湾沉积物的物质来源是其周围集水区的岩石风化壳,并计算了其风化壳中重金属元素的平均丰度值;又根据沉积物的粒度和深层沉积物重金属元素的含量资料,列方程计算出湾内沉积物中重金属元素的平均含量,根据这两组数据,确定该区域内重金属元素的平均背景值。再通过粒度关系,计算得出大亚湾内各站沉积物中重金属元素的背景值。应用此结果和大亚湾沉积物重金属元素实测结果,计算了由人为影响带入沉积物中的重金属元素含量,了解其受污染的程度。     

北黄海沉积物中重金属分布及环境背景值

本文讨论了北黄海１１个柱状岩芯样的颗粒物（＜０．０６３ｍｍ）中重金属的分布，采用统计学方法对Ｃｕ，Ｐｈ，Ｚｎ和Ｃｄ进行态性检验，用柱样稳定段（拐点以下）作为背景段，获得重金属环境背景值．     

海水中砷标准物质的研制

本文介绍了海水中砷标准物质的研制过程，其中包括溶液的配制、均匀性和稳定性检验，标样的分析方法。并对标准物质的定值数据进行统计处理，两种浓度的定值结果分别为：１．００μｇ／ｃｍ３±０．０４μｇ／ｃｍ３和５１．０μｇ／ｄｍ３±２．６μｇ／ｄｍ３。两种浓度砷标准物质的稳定期均为一年     

Semi-Probabilistic Evaluation of System Redundancy for Existing Offshore Structures

In this paper, a new definition of structure system redundancy is proposed in view of the various measures for structure redundancy. By introducing the terms of structure system failure at the mechanism level and equivalent reliability index, the safety for existing offshore platforms can be evaluated by the semi-probabilistic method presented in this paper. Some numerical examples are given and satisfactory results have been obtained.     

四阶奇异边值问题无穷多个正解存在性的一个注记

本文考虑四阶奇异边值问题x( 4 ) =λa(t) f (t,x(t) ) ,0 相似文献   

围垦的社会经济价值及其对海洋环境影响的评估

从围垦滩涂与保护湿地的关系着手,针对浙江省的滩涂围垦现状,讨论了沿海滩涂实施围垦工程所创造的社会经济价值,分析了湿地生态的环境特征及其对自然界的贡献,指出并探讨了海岸带资源开发与海岸工程建设所带来的问题,从湿地保护和经济可持续发展的角度提出了相关的建议。     

Sediment–water interactions of natural oestrogens under estuarine conditions

The natural human female hormones oestrone and 17β-oestradiol have been implicated in the disruption of endocrine systems in some wildlife adjacent to sewage effluents. The sorption behaviour of these two compounds under estuarine conditions was studied by spiking either 2.55 μg of oestrone or 2.65 μg of 17β-oestradiol in kinetic experiments. In equilibrium experiments, 3 ng of oestrone or 3.2 ng of 17β-oestradiol was added in each of the centrifuge tubes. Sorption onto sediment particles was relatively slow, with sorption equilibrium being reached in about 70 and 170 h for oestrone and 17β-oestradiol, respectively. The effects of a variety of environmental parameters on sorption were studied including salinity, sediment concentration (SC), the presence of a third phase, particle size and, also, surfactant concentrations. Results show that although salinity did not induce any statistically significant effect on the sorption of 17β-oestradiol, it did statistically enhance the sorption of oestrone, and a salting constant of 0.3 l mol⁻¹ was derived. The partition coefficient for both compounds decreased with increasing sediment concentration, a phenomenon that has been widely reported and attributed to the presence of colloids (which could enhance dissolved concentrations). In this paper, the true partition coefficients for sediment particles (K_p^true) and colloidal particles (K_c^true) have been calculated, and a K_p^true value of 141 and 102 ml g⁻¹ was obtained for oestrone and 17β-oestradiol, respectively. In addition, K_c^true values for oestrone (222×10² ml g⁻¹) and 17β-oestradiol (135×10² ml g⁻¹) were two orders of magnitude higher than their respective K_p^true values, suggesting that the colloidal particles are significantly stronger sorbents for natural oestrogens than sediment particles. Particles of different sizes were found to have different partition coefficients due to the strong relationships between partition coefficients for the two compounds and particulate organic carbon (POC) contents and specific surface areas (SSAs). The presence of a surfactant was shown to reduce the partition coefficients for the two compounds, although its concentrations being used were higher than those normally found in the natural environment.     

东太平洋多金属结核分布的二维趋势面分析

对规则网的 469个测站的多金属结核丰度和 93个测站的 Mn、 Cu、 Co、 Ni元素进行趋势面分析 ,经 F检验 ,各变量的变异性显著 ,拟合度较低 ,表明多金属结核丰度及 Mn、Cu、Co、Ni金属元素的控制因素比较复杂。趋势面分析结果与相关分析结果一致 ,Mn、Cu、Ni元素有极相似的趋势特征 ,有两个轴向分布 ,一个为东西向轴 ,高值区在东部 ,另一个为北西向轴 ,高值区在北西部 ;结核丰度与 Co也有极相似的趋势特征 ,高值区在西部。应用逐次趋势面分析的结果将结核丰度的地质特征分解成各种简单控制因素的叠加 ,使对多金属结核的控矿因素、分布规律和物质来源的研究方法多样化     

Composition and distribution of phytoplankton with size fraction results at southwestern east/japan sea

Abundance and distribution of phytoplankton in seawater at southwestern East/Japan Sea near Gampo were investigated by HPLC analysis of photosynthetic pigments during summer of 1999. Detected photosynthetic pigments were chlorophyll a, b, c₁₊₂ (Chl a, Chl b, Chl c₁₊₂), fucoxanthin (Fuco), prasinoxanthin (Pras), zeaxanthin (Zea), 19’-butanoyloxyfucoxanthin (But-fuco) and beta-carotene (β-Car). Major carotenoid was fucoxanthin (bacillariophyte) and minor carotenoids were Pras (prasinophyte), Zea (cyanophyte) and But-fuco (chrysophyte). Chl a concentrations were in the range of 0.16-8.3/land subsurface chlorophyll maxima were observed at 0-10m at inshore and 30–50 m at offshore. Thermocline and nutricline tilted to the offshore direction showed a mild upwelling condition. Results from size-fraction showed that contribution from nano+picoplankton at Chl a maximum layer was increased from 18% at inshore to 69% at offshore on average. The maximum contribution from nano+picoplankton was found as 87% at St. E4. It was noteworthy that contribution from nano+picoplanktonic crysophytes and green algae to total biomass of phytoplankton was significant at offshore. Satellite images of sea surface temperature indicated that an extensive area of the East/Japan Sea showed lower temperature (<18 °C) but the enhanced Chl a patch was confined to a narrow coastal region in summer, 1999. Exceptionally high flux of low saline water from the Korea/Tsushima Strait seemed to make upwelling weak in summer of 1999 in the study area. Results of comparisons among Chl a from SeaWIFs, HPLC and fluorometric analysis showed that presence of Chl b cause underestimation of Chl a about 30% by fluorometric analysis but overestimation by satellite data about 30-75% compared to HPLC data.