Calibration of Infrared Absorption Coefficients for Structural Hydroxyl in Garnet by a Combined Study of Isotope Ratio Spectrometry and Vibrational Spectroscopy

An accurate determination of water content in garnet is critical to quantify the transport of water to the deep mantle by the subducted oceanic crust beyond the breakdown of hydrous phases. Fourier transform infrared spectroscopy (FTIR) is the most widely used approach to determine the species and contents of water in garnet. Accurate quantification of OH in garnet requires independent calibration using an external method, as OH absorbance is mineral and composition specific. To obtain the infrared absorption coefficients of structural hydroxyl in garnet, a combined study of spectrometric analyses by FTIR and a method combining a thermal conversion elemental analyser with isotope ratio mass spectrometry (TC/EA-MS) was carried out for fourteen gem-quality natural garnet crystals with variable compositions. The obtained molar absorption coefficients were 9322 ± 338 and 240 ± 26 l mol⁻¹ cm⁻² for grossular- and spessartine-rich garnet and pyrope-almandine garnet, respectively. These results are within the range of previous studies. A new molar absorption coefficient of 689 ± 177 l mol⁻¹ cm⁻² was obtained for pyrope-spessartine garnet. The large variation in the absorption coefficient indicates it is controlled by both garnet composition and OH-absorption bands. The obtained absorption coefficients are only appropriate for certain types of eclogitic garnet, and more studies should be carried out on eclogitic garnets.     

新疆及邻区体波震级初步分析研究

依据《地震震级的规定（GB 17740—2017）》,分析了2009—2017年新疆地震台网所记录的新疆及邻区476次中深源地震事件,测定了13601个m_b（短周期体波震级）和12035个m_B（BB）（宽频带体波震级）的数据样本,回归分析m_b和m_B（BB）得到回归方程及量规函数,结果显示m_b和m_B（BB）相关系数为0.966,表明两者显著相关。因此,建议对于中强型中深源地震可以直接从原始速度型宽频带数字地震记录上测定长周期体波震级m_B（BB）,提高地震速报测定的速度和精度。通过震级偏差统计和台站场地响应计算,分析新疆地震台网中的XKR、HTA、ATS和KSZ等地震台站震级偏差较大的原因为砂岩、灰岩、砂土层等类型的台基放大了场地响应,说明台基类型对体波震级偏差的影响较大。与NEIC测定的体波震级对比时,发现新疆地震台网测定体波震级平均偏大0.42级,且偏差随着震源深度的增加有增大的趋势。     

Advances and limitations in establishing a contiguous high-resolution atmospheric radiocarbon record derived from subfossil kauri tree rings for the interval 60–27 cal kyr BP

Radiocarbon dating is the most widely applied and reliable dating technique for providing chronological control during Marine Isotope Stage 3 (MIS3; ∼60–27 cal kyr BP). Past variations in the atmospheric concentration of radiocarbon mean a calibration curve is required. IntCal20 and SHCal20 calibration curves covering MIS3 are presently largely based on non-atmospheric records which, in combination with larger radiocarbon (¹⁴C) dating uncertainties, results in significant smoothing and reduced resolution in calibration curve structure. Floating tree ring radiocarbon chronologies that are wiggle-matched to other palaeo records (particularly to Hulu Cave speleothems) have the potential to provide detailed structure to the MIS3 portion of extant calibration curves. New Zealand subfossil kauri (Agathis australis) trees are long-lived and are useful for constructing temporally-floating MIS3 atmospheric radiocarbon datasets. This paper presents extant and emerging data from several important Northland subfossil kauri locations (Omaha, Babylon Coast, Bream Bay, Kai Iwi Lakes, Mangawhai). We show the span of seven floating MIS3 kauri sequences (individual trees and chronologies) from which sequential radiocarbon series covering a total of 7556 years is now in development (representing 23% of the period 60–27 cal kyr BP). We also report radiocarbon dates for an additional 34 ancient kauri from MIS3 that can provide additional coverage. After these floating subfossil wood sequences have been produced, close to 40% of MIS3 (12,420 years) will be covered by contiguous subfossil kauri radiocarbon measurements. Based on our findings, we discuss the prospects and limitations for obtaining a highly resolved and precise atmospheric radiocarbon calibration curve comprehensively covering MIS3 using subfossil kauri.     

5000 m新型能源勘探智能钻探装备与技术研究

结合我国地下新型能源勘探工作的重大需求,开展了“5000 m新型能源勘探智能钻探装备与技术”的研究,取得了5000 m多功能交流变频电动钻机、多参数孔底自动监测装置、高温环保泥浆及泥浆性能自动测量装置、取心和无心钻进不提钻互换钻具等系列成果,填补了国内空白,推动了新型能源深部钻探技术向智能化方向发展。     

自动电位滴定技术精确测定铜矿石中高含量铜的方法研究

铜矿石中百分含量铜的分析通常采用手动目视滴定法,该方法借助化学指示剂判定终点,存在终点判断和人为操作等误差,精密度、可靠性相对较差。基于此,本文建立了精确测定铜矿石中高含量铜的分析方法,采用智能型自动电位滴定仪自动判定终点,高分辨加液器精确控制硫代硫酸钠标准溶液加入量至0.001 m L,并且通过加大碘化钾用量使得滴定中产生的碘化亚铜被高浓度的I-溶解,消除对碘的吸附影响。本法应用于铜含量为24.2%~59.09%的铜精矿、黄铜矿、铅黄铜国家标准物质分析,相对标准偏差(RSD,n=10)0.3%,极差仅为0.13%、0.21%、0.29%,优于手动目视滴定法。本法提高了铜矿石分析的自动化程度,适用于精确测定铜含量大于0.5%尤其是10%以上的铜矿石。     

渤海湾西岸全新世海面变化

在讨论海面标志点基本定义的基础上,从渤海湾西岸534个原始数据中获得了136个指示高水位、潮间带或低水位的海面变化标志点,并重建了它们的相对海平面时空分布,进而获得了渤海湾西岸全新世相对海平面变化带.约10cal.ka B.P.时,相对海平面变化带达到-25m,以约6m/1000a(即约6mm/a)的平均速率上升,在6cal.ka B.P.前后达到现代海面的高度;6cal.ka B.P.至今,变化带的高度介于+1m～-2m之间,未发现中全新世相对高海面.再搬运海相贝类和陆相泥炭类样品的14C年龄,分别存在约600年和660年的驻留时间.经过驻留时间校正的新海面变化年代学序列,将渤海湾相对海平面达到现代高度的时间点确定为约6cal.ka B.P.,从而与全球海面变化的对比更为准确.渤海湾盆地的长期稳定下沉和沉积自重压实的共同作用,可能抵消了冰川均衡调整(GIA)引起的中全新世数米高的相对高海面.     

无地面控制点卫星摄影测量探讨

为解决无地面控制点的卫星摄影测量(简称无控定位)这一国际难题,对国外具有代表性的几个"全球连续覆盖模式"光学摄影测量卫星的主要技术参数特征以及无控摄影测量模式、技术措施等方面进行了系统归纳,尽管各系统在无控定位上作了种种努力,但与美国1∶50 000比例尺制图标准(水平位置误差12m,垂直高程误差6m)相比,都存在一定距离,该文认为其不足的关键在于对星敏感器测姿误差的处理上。该文还特别介绍了天绘一号卫星工程达到这一标准的主要学术与技术措施,并列举了国内外检查点检测精度一致性的实例。     

地面检校场的非量测型数码相机检校

由于相机检校作为非量测型数码相机应用于摄影测量前的必经步骤,其精度直接决定着后续测图的精度,因此针对传统的相机检校方法不能较真实地反映相机的物理状态、检校精度不高的问题,该文给出了基于地面检校场进行检校的流程,并以和静县数据为例,将该方法的检校精度与基于室内三维检校场以及基于纯平液晶显示器的检校精度进行了对比。实验表明:经该方法检校出来的相机参数精度更高,能够满足大比例尺测图要求。     

大视场面阵数字航摄仪检测关键技术探讨

针对常规室内检校场无法满足大视场面阵数字航摄仪检测的问题,文章提出了一种适合此类航摄仪检校的野外检校场的建立方法,通过对检校场控制点布设方案设计、适合影像识别的地标形状设计和地标点三维坐标的精确测定方案研究,实现了检测场内控制点的高精度测量:建立适合大面阵数字航空摄影仪几何误差改正的数学模型,并通过多摄站拍摄足够数量的检校场影像,自动识别并测定每幅影像上全部地标点的影像坐标,用最小二乘平差计算间接求出相机的内方位元素和各项畸变参数,最后通过多组检测参数对比,验证了数学模型及其参数的可靠性与稳定性。     

GPS-RTK无验潮测深精度影响因素分析

针对目前GPS-RTK联合单波束无验潮测深虽然从理论上消除了潮位模型误差的影响,但未顾及测量船受风浪、海流、潮汐等作用引起的姿态影响、GPS与测深仪信号不同步的影响、测深仪信号延迟和水中声速变化的影响等问题,为了提高海洋测深成果的精度,文章在分析这些影响因素产生机理的基础上,结合当前常用的外业作业设备,仿真模拟了各种测深作业状况,并分别定量计算了各种状况下上述因素引起的定位和测深误差,然后依据分析计算结果,给出了相应的解决办法,可为测深外业作业人员区分误差量级,进而优化作业方案提供参考。