Latitudinal variation of measured O3 photolysis frequencies J(O1D) and primary OH production rates over the Atlantic Ocean between 50° N and 30° S

The latitudinal variation of the photolysis frequency of ozone to O(¹D) atoms, J(O¹D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O¹D) noon values exhibited a maximum of 3.6×10^-5 s^-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O¹D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O¹D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9![J({text{O}}^| {text{D) }} = {text{ exp { }} - 8.02 - 8.8x10^{ - 3} {text{ x }}S + 3.4x10^{ - 6} S^2 } {text{(s}}^{ - 1} )] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O¹D) measurements and simultaneously recorded O₃ and H₂O mixing ratios. While the latitudinal distribution of J(O¹D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH.     

一种快速地球大气效果3维绘制方法

介绍了地球大气模型,并回顾了国内外大气的3维绘制算法。在此基础上提出了一种基于简化模型的快速大气效果绘制算法。该算法综合利用Billboard与图形学雾化效果,逼真模拟出了地球大气的可视化效果。实验结果表明,该算法简单有效,避免了复杂的物理计算,大大提高了绘制效率。     

北斗三号系统进展及性能预测: 试验验证数据分析

网络实时动态测量(real-time kinematic, RTK)技术可为大范围区域用户提供实时高精度的定位服务,然而目前该技术对卫星导航定位(satellite navigation and positioning,SNAP)基准站网密度要求较高。为了满足稀疏大尺度SNAP基准站网区域的高精度定位服务需求,提出了一种基于虚拟大气约束（virtual atmosphere constrait, VAC）的网络RTK服务方法,首先构建非组合双差观测值模型,快速解算并固定SNAP基准站基线模糊度;然后提取基线大气延迟,分别建立斜路径电离层和天顶对流层误差模型;最后将内插的大气延迟及其精度信息作为虚拟观测值,提升终端RTK的定位性能。采用中国西北的SNAP基准站网数据(平均站间距为205.1 km)和网内外6个流动站数据进行RTK验证,结果表明,所提方法可以满足大尺度参考网下用户的高精度定位需求,相比传统的虚拟基准站技术,VAC服务模式下的终端定位精度、初始化速度平均分别提升61.64%和9.96%,该模式下测试终端固定解水平和高程方向的平均均方根分别为1.19 cm、2.73 cm;采用多次初始化进行验证,平均88.78%的时段在2个历元内即可完成初始化;VAC服务模式对大尺度SNAP基准站网内外用户均具有较好的适应性。     

大气折光对水平角测量影响及对策研究

通过测量实践和试验,分析了大气折光对特高精度边角测量的影响,指出旁折光是水平角测量误差的主要来源,而对边长的影响甚微;同时,边角网中水平角测量时起始方向的选择十分重要,提出了采用测量机器人作自动观测的一种起始方向确定和质量检查方法;并阐述了特高精度边角网布设和施测中为减少大气折光影响的一些对策。     

The Atmospheric Oxidation of the HS Radical: Reaction with NO2

The atmospheric reaction between HS and NO₂ was theoretically investigated at 298 K and 1 atm of pressure. Our results show that the first reaction step will lead to the formation of HSNO₂ or HSONO, spontaneously and exothermically. HSONO easily decomposes into HSO + NO. On the other hand, HSNO₂ can hardly dissociate in the reactants, and its isomerization to other adducts is much hindered. Production of HNO + SO and SNO + OH was found to be unfavorable. Thus, the main products would be HSO + NO and HSNO₂, and new investigations focusing on the atmospheric fate of HSNO₂ are suggested. A general discussion of the fate of HS under atmospheric conditions is presented. Recent investigations indicate that NO₂, O₂ and N₂O should be the most important oxidants of HS, while the O₃ influence will not be significant.     

中层大气Rossby波与惯性重力波的非线性相互作用（Ⅱ）波包之间的相互激发

进一步讨论了大中尺度Ｒｏｓｓｂｙ波与惯性重力波的非线性相互作用问题．从共振相互作用曲线来看,Ｒｏｓｓｂｙ波和惯性重力波可以在相当广泛的角谱范围内发生共振非线性相互作用．在一定条件下,一个大振幅波包可以激发两个小振幅波包不稳定增长而出现参量不稳定现象,这三个波包可以是同种类型或不同类型的波包．当两个大振幅波包发生相互作用时,非线性过程会产生另一个波包并使它增长,并且增长速度大于仅有一个大振幅波包时的增长速度．大尺度Ｒｏｓｓｂｙ波包税发两个较小尺度惯性重力波的过程是一种重要的能量串级（ｃａｓｃａｄｅ）过程．     

Long-term changes of the upper stratosphere as seen by Japanese rocketsondes at Ryori (39°N, 141°E)

Wind and temperature profiles measured routinely by rockets at Ryori (Japan) since 1970 are analysed to quantify interannual changes that occur in the upper stratosphere. The analysis involved using a least square fitting of the data with a multiparametric adaptative model composed of a linear combination of some functions that represent the main expected climate forcing responses of the stratosphere. These functions are seasonal cycles, solar activity changes, stratospheric optical depth induced by volcanic aerosols, equatorial wind oscillations and a possible linear trend. Step functions are also included in the analyses to take into account instrumental changes. Results reveal a small change for wind data series above 45 km when new corrections were introduced to take into account instrumental changes. However, no significant change of the mean is noted for temperature even after sondes were improved. While wind series reveal no significant trends, a significant cooling of 2.0 to 2.5 K/decade is observed in the mid upper stratosphere using this analysis method. This cooling is more than double the cooling predicted by models by a factor of more than two. In winter, it may be noted that the amplitude of the atmospheric response is enhanced. This is probably caused by the larger ozone depletion and/or by some dynamical feedback effects. In winter, cooling tends to be smaller around 40–45 km (in fact a warming trend is observed in December) as already observed in other data sets and simulated by models. Although the winter response to volcanic aerosols is in good agreement with numerical simulations, the solar signature is of the opposite sign to that expected. This is not understood, but it has already been observed with other data sets.