海洋环境下粉煤灰混凝土的抗冻性与抗氯离子渗透性的耦合

针对海洋环境条件,重点研究了粉煤灰混凝土的抗冻性和氯离子渗透性能的相互关系.试验分别研究了水胶比、粉煤灰等量取代水泥掺量大小、引气剂掺量等因素对抗冻性和抗氯离子渗透性能的影响,并与普通混凝土进行了对比.结果表明,粉煤灰不增加混凝土的抗海水冻融耐久性;粉煤灰增加混凝土的抗氯离子渗透性能,但是掺量超过30%,抗氯离子渗透性能下降;粉煤灰对混凝土抗冻性和抗氯离子渗透性的耦合影响在30%左右存在一个最佳掺量.为评估混凝土的抗冻性和氯离子扩散性的耦合性能,提出了新的评价方法--冻渗比(R值方法),并进行了试验验证.SEM和MIP微观分析与R值方法评价的结果是吻合的.     

Distance law and formation of satellite systems

In the solar system satellite systems of Jupiter, Saturn and Uranus are typical ones. The distribution of the semi-major axis of satellite orbits in each system may be expressed by an empirical formula corresponding to the Titius-Bode law. We found that it can be written as a_n = B′ · Bⁿ, where B′ and B are constants. Values of B′ and B depend on formation conditions of each system. Satellites should be formed in the gas-satellitesimal disk around a planet and by aggregation of satellitesimals. The gas is the major component in the disk and its damping effect must play an important role in the process of aggregation of satellitesimals. It may be proved that radial small perturbation in the disk can cause the gravitational instability and the formation of gaseous rings with increased density, where satellitesimals can easy aggregat into satellites.     

改性粉煤灰性质及其封堵油层大孔道效果

粉煤灰是燃煤火力发电厂的废弃物,由大小不等、结构疏松的非晶质玻璃相球形颗粒组成,其主要化学成分是铝硅酸盐,具有来源广和成本低等特点。在水热条件下,Holler和Wirsching首先利用粉煤灰与碱（NaOH或KOH）作用合成了沸石。针对油田封堵油层孔隙即改善注水井吸水效果的实际需求,在总结和吸取粉煤灰和沸石颗粒封堵油层孔隙矿场施工成功经验和不足基础上,探索了水热条件下粉煤灰部分转化为沸石的配方组成和工艺条件,研究了改性粉煤灰组成和外观结构特征,评价了改性粉煤灰的封堵效果,分析了改性粉煤灰封堵作用机理。研究结果对改善油层孔隙封堵效果、提高油田注水效率具有重要应用价值。     

利用高铝粉煤灰制备莫来石微晶玻璃的实验研究

以高铝粉煤灰为主要原料,采用粉末烧结法制备出莫来石微晶玻璃。X射线衍射分析显示,经1350~1550℃热处理后,制得的微晶玻璃的主晶相均为莫来石。扫描电镜分析表明,较高的温度下热处理有利于晶体的生长。微晶玻璃的理化性能如吸水率、气孔率、体积密度、抗折强度和化学稳定性,随热处理温度的不同而发生相应的变化。1500℃热处理2 h制得的微晶玻璃具有优良的理化性能,在工程和结构领域具有潜在的应用前景。     

攀钢发电厂麻地湾灰场初期坝及堆积灰体工程地质特征研究

分级分期灰渣筑坝是近年发展起来的山谷贮灰场建设的一种新型技术,是为了满足燃煤电厂贮灰年限和调节洪水的要求的一种新型设计.为满足分级分期灰渣筑坝的设计要求,分析评价初期坝的稳定性与先期粉煤灰灰体堆积特征是构筑分级子坝的重要基础.本文通过水文地质及工程地质调查与岩土工程勘察探讨了麻地湾灰场子坝加高所涉及的相关岩土体的工程地质特征与场地水文地质特征,据此对分级子坝加高的工程地质条件进行了适宜性评价,并通过对堆积灰体物理力学试验分析了粉煤灰灰体的堆积特征与压实程度,为子坝加高设计提供了可靠参数.     

Valency Study of Vanadium in Stone Coal Ash of Jiangxi Province

Vanadium-bearing stone coal is a new vanadium resource;recovery ofV_2O_5 from the coal has been investigated.It has been found that a satisfactoryextraction of V_2O_5 depends on both the oxidation of V and its reaction with so-dium salt.V in the coal ash of Yushan mainly exists in two oxidation states:98％V(Ⅲ)and2％V(Ⅳ).The distribution of valency of V shows that organicmatter determines V valency at low temperatures,at about470℃,V(Ⅲ)iscompletely oxidized to V(Ⅳ);above500℃,the temperature is the most impor-tant factor for the oxidation of V .At higher temperatures no more V is oxidizedto V(Ⅴ);an equilibrium is established after92％of V is oxidized to V(Ⅴ).The roles of NaCl in the recovery of V_2O_5 from the coal ash were discussed.The best conditions for roasting are temperature750-800℃for1 h.underthe oxidation-chlorination atmosphere.When the ore:NaCl=100:10 by weight,η_roast reaches85.5％.According to the results,a flowsheet for V_2O_5 extrac-tion from coal ash has been proposed.     

Emission spectrographic estimation of gold

A procedure for estimating minute quantities (parts per billion) of gold is described, based on dissolution of the sample in aqua regia, adsorption on activated charcoal, arcing of the charcoal ash, and measurement of the intensity of the emitted spectra.     

The gas content and buoyancy of strombolian ash plumes

Plinian plumes erupt with a bulk density greater than that of air, and depend upon air entrainment during their gas-thrust phase to become buoyant; if entrainment is insufficient, the column collapses into a potentially deadly pyroclastic flow. This study shows that strombolian ash plumes can be erupted in an initially buoyant state due to their extremely high initial gas content, and in such cases are thus impervious to column collapse. The high gas content is a consequence of decoupled gas rise in the conduit, in which particles are ultimately incidental. The relations between conduit gas flow, eruption style and plume density are explored here for strombolian scenarios and contrasted with conventional wisdom derived from plinian eruptions. Considering the inherent relation between gas content and initial plume density together with detailed measurements of plume velocities can help unravel ambiguities surrounding conduit processes, eruption styles and hazards at poorly understood volcanoes. Analysis of plume dynamics at Santiaguito volcano, Guatemala adds further support for a model involving decoupled gas rise in the conduit.     

复杂系统模糊模式识别动态规划模型研究

将模糊识别集合算子和非结构决策分析方法引入模糊动态规划中,推导出了两种求解复杂系统多目标多阶段决策问题的方法:级别特征值最小法和阶段模糊识别递推法。这两种方法具有不同的递推方程,可以应用于不同的情况,从而形成了模糊模式识别动态规划模型。此模型可以有效地获取和集成决策者的经验知识和偏好。此模型已应用到实践中,并取得良好效果。     

黄磷电炉烟尘中各种磷化合物的化学物相分析

对黄磷电炉烟尘中各种形态的磷化合物进行了化学物相分析，得出元素磷、水溶性低价磷化合物、水溶性高价磷化合物、酸溶性高价磷化合物、酸溶性低价磷化合物、酸不溶性磷化合物在黄磷电炉烟尘中的含量，并对黄磷电炉烟尘的综合利用提出了建议。