泡塑吸附分离萃取光度法测定粉煤灰中的镓

试验了在盐酸介质中聚氨酯泡沫塑料吸附分离镓的性能,将该性能用于粉煤灰分离镓的预处理过程,罗丹明B萃取光度法定量测定镓含量。结果表明,室温条件下,在6 mol/L盐酸溶液中,聚氨酯泡沫塑料对镓有良好的吸附性能,90 m in可达吸附平衡,饱和吸附量为每克泡塑可吸附42 mg镓;被吸附的镓可用0.5 mol/L氯化铵溶液定量洗脱;用罗丹明B萃取光度法测定镓含量时,镓浓度在0~1.0μg/mL服从比尔定律,检出限为0.008 mg/L。测定粉煤灰样品中镓的含量,加标回收率在103%~107%,相对标准偏差(RSD,n=20)为1.5%,富集分离效果明显,选择性高。     

Area-Averaged Surface Fluxes Over the Litfass Region Based on Eddy-Covariance Measurements

Micrometeorological measurements (including eddy-covariance measurements of the surface fluxes of sensible and latent heat) were performed during the LITFASS-2003 experiment at 13 field sites over different types of land use (forest, lake, grassland, various agricultural crops) in a 20 × 20 km² area around the Meteorological Observatory Lindenberg (MOL) of the German Meteorological Service (Deutscher Wetterdienst, DWD). Significant differences in the energy fluxes could be found between the major land surface types (forest, farmland, water), but also between the different agricultural crops (cereals, rape, maize). Flux ratios between the different surfaces changed during the course of the experiment as a result of increased water temperature of the lake, changing soil moisture, and of the vegetation development at the farmland sites. The measurements over grass performed at the boundary-layer field site Falkenberg of the MOL were shown to be quite representative for the farmland part of the area. Measurements from the 13 sites were composed into a time series of the area-averaged surface flux by taking into account the data quality of the single flux values from the different sites and the relative occurrence of each surface type in the area. Such composite fluxes could be determined for about 80% of the whole measurement time during the LITFASS-2003 experiment. Comparison of these aggregated surface fluxes with area-averaged fluxes from long-range scintillometer measurements and from airborne measurements showed good agreement.     

闽南近海中国团扇鳐和林氏团扇鳐肌肉中水分含量、灰分含量及能值的分析

测定了中国团扇鳐和林氏团扇鳐肌肉中的水分含量、灰分含量及能值．中国团扇鳐肌肉水分含量为75．86％,灰分含量为5．15％,能值为21．49MJ/kg;林氏团扇鳐肌肉水分含量为76．66％,灰分含量为5．04％,能值为21．29MJ／kg．中国团扇鳐、林氏团扇鳐的体重与体长有显著的正相关关系;中国团扇鳐、林氏团扇鳐的水分含量随体重的增加而减小,能值随体重的增加而升高;中国团扇鳐肌肉的能值与水分含量之间具有一定的相关递减的趋势,林氏团扇鳐水分含量与灰分含量之间具有一定的相关递增的趋势．此外,中国团扇鳐、林氏团扇水分含量、灰分含量及能值随季节的变化而变化．这与鱼体自身的生物学特性有关。也受到环境因子变化的影响．     

The usability of bottom ash as an engineering material when amended with different matrices

This study aims at investigating the utilization of bottom ash obtained from four different power stations as a construction fill and landfill bottom liner. For the matrix material, commercial powdered bentonite, construction lime and natural clay were used. Compaction tests (Standard Proctor and vibratory hammer) were carried out on the different ratios of bottom ash and matrix material. The optimum water content ranged from 40 to 45% yielding a dry density mostly ca 1 Mg m⁻³. Uniaxial compressive strength of mixtures ranges from 0.1 to 0.5 kgf cm⁻² which showed a 3–20-fold increase when tested on 28-day cured specimens. Triaxial compression tests yield varying rates of shear strength which also showed as high as an 11-fold increase for cured specimens. The hydraulic conductivity of those mixtures was mostly ca 10⁻⁴ cm s⁻¹, which is not considered to be low enough for landfill lining. Leaching tests using deionized water were also performed to investigate the possible effect of leachate produced from the mixtures on the environment. In conclusion a light density and environmentally friendly mixture is determined and proposed as construction filler.     

粉煤灰污泥添加剂对地下水质影响的模拟研究

通过测定土柱和淋洗液中重金属的含量,研究石灰岩质土壤应用粉煤灰污泥添加剂改良后重金属在土壤剖面上的分布移动特征及对地下水质的影响.结果表明:仅试验层内除As和Ni外,Zn、Cd、Pb、Cu、Cr、Hg含量明显增加,未出现明显向下移动的趋势;同时重金属淋出量明显增加,但未超过地下水Ⅲ级标准.初步认为与添加剂自身、重金属的特性及石灰岩质土壤滤层的截固作用相关.粉煤灰污泥经过合理的配施和预处理应用于石灰岩质矿区退化土壤的改良,短期内不会对地下水的质量产生明显的影响.     

“多元聚合分类”在预报上的初步应用

“多元聚合分类”是作者提出的旨在解决‘“相对最优分类”的一种可行的客观分类方案[1]。作者通过对南昌1990－1994年6月份资料的分析，说明该分类方法应用于预报有较好的效果。     

Utilization of fly ash for stabilization/solidification of heavy metal contaminated soils

Pozzolanic-based stabilization/solidification (S/S) is an effective, yet economic remediation technology to immobilize heavy metals in contaminated soils and sludges. In the present study, fly ash waste materials were used along with quicklime (CaO) to immobilize lead, trivalent and hexavalent chromium present in artificially contaminated clayey sand soils. The degree of heavy metal immobilization was evaluated using the Toxicity Characteristic Leaching Procedure (TCLP) as well as controlled extraction experiments. These leaching test results along with X-ray diffraction (XRD), scanning electron microscope and energy dispersive X-ray (SEM–EDX) analyses were also implemented to elucidate the mechanisms responsible for immobilization of the heavy metals under study. Finally, the reusability of the stabilized waste forms in construction applications was also investigated by performing unconfined compressive strength and swell tests. The experimental results suggest that the controlling mechanism for both lead and hexavalent chromium immobilization is surface adsorption, whereas for trivalent chromium it is hydroxide precipitation. Addition of quicklime and fly ash to the contaminated soils effectively reduced heavy metal leachability well below the nonhazardous regulatory limits. Overall, fly ash addition increases the immobilization pH region for all heavy metals tested, and significantly improves the stress-strain properties of the treated solids, thus allowing their reuse as readily available construction materials. The only potential problem associated with this quicklime–fly ash treatment is the excessive formation of the pozzolanic product ettringite in the presence of sulfates. Ettringite, when brought in contact with water, may cause significant swelling and subsequent deterioration of the stabilized matrix. Addition of minimum amounts of barium hydroxide was shown to effectively eliminate ettringite formation. Overall, due to the presence of very high levels of heavy metal contamination along with sulfates in the solid matrices under study, the results presented herein can be applied to the management of incinerator and coal fly ash, boiler slag and flue gas desulfurization wastes.     

粉煤灰扰动样现场取样问题初步探讨

本文结合福州电厂粉煤灰室内试验结果分析,探讨粉煤灰扰动样现场取样及试验控制干密度等问题。该电厂粉煤灰的沉积规律与其它电厂有所不同,灰料颗粒粗细分布和距排灰口远近基本无关,取样也不能按以往经验进行。     

不同固化材料垫层在黄土中隔水能力及其垂直扩散特性

黄土作为地基材料时由于其湿陷性容易出现失稳现象,利用固化剂垫层改良黄土地基水稳性和强度的技术被广泛使用。本文主要通过在黄土中分别加入石灰、水泥和粉煤灰固化剂垫层的方法进行加固,测定了在垂直方向上各处的含水率、密度、干密度、土颗粒比表面积(SSA)及阳离子交换能力(CEC)的变化。试验表明石灰、水泥和粉煤灰垫层可以影响10～15cm范围内相邻土层含水率、密度、比表面积和阳离子交换能力,改变土质结构,提高土体的水稳性。改性后的土体越靠近固化剂垫层,含水率、SSA和CEC越小而密度越大。其中,石灰垫层效果最好,它能将黄土中含水率减小超过4%,密度增加1.0～1.5g cm-3,粉煤灰作用次之,水泥最弱。此外,试样土颗粒比表面积(SSA)与阳离子交换能力(CEC)存在线性递增的关系,本次试验中,3个试样中SSA与CEC之比均稳定于6.5～7.5之间。     

黔西晚二叠世煤地球化学性质变异及特殊组构的火山灰成因

运用仪器中子活化分析(INAA)、电感耦合等离子体原子发射光谱(ICP—AES)、X射线衍射(XRD)、带能谱仪的扫描电镜(SEM—EDX)及光学显微镜等手段，对黔西晚二叠世煤地球化学性质变异及其特殊组构的火山灰成因进行了研究。结果表明，贵州西部织金矿区9煤层中异常高含量的Fe(4．24％)、Cu(369．90μg／g)、U(49．6μg／g)、Mo(63．10μg／g)、Zn(33．97μg／g)等是来源于同沉积基性火山灰降落到泥炭沼泽中所致；高含量的Fe、Cu并非以通常意义的煤中硫化物状态存在；除煤中有机质和陆源碎屑外，发现了由火山灰、有机质和陆源碎屑所形成的煤层中的特殊组构，暂定名为沉碳质火山胶凝物，它是一种有机—无机高度混合物质，根据沉碳质火山胶凝物的形态特征和物质组成，厘定出6种组构类型，分别是：网状组构、细屑组构、基质组构、孔腔组构、均质组构和碎屑组构。