Utilization of sodium waterglass from sugar cane bagasse ash as a new alternative hardener for producing metakaolin-based geopolymer cement

Sugar cane bagasse ash from SOSUCAM company in Cameroon was used to synthesize sodium waterglass as a new alternative hardener. The new hardener was used to prepare metakaolin-based geopolymer cements. The compressive strength of the resulting geopolymer cement cured at room temperature for 28 days was 32.9 MPa. Samples soaked for 28 days in water in parallel experiments revealed a strength of 31.4 MPa. This shows that exposure of water does not lead to any weakening. The value of water absorption was 7.1% in the water-soaked cements, indicating the presence of fewer pores and voids than in the dry cements. However, in SEM micrographs, the microstructure of geopolymer cement appears rather homogeneous and compact without any change by water soaking. It can thus be concluded that sodium waterglass from sugar cane bagasse ash can be used as an alternative hardener or reactive ingredient for producing geopolymer cement with a high degree of cross-linking geopolymer framework. The use of this low-value silica-rich waste for producing sodium waterglass results in environmental benefits including a significant reduction of CO₂ emission and energy consumption compared to the production of commercial sodium waterglass.     

Characteristics of phosphate adsorption onto granulated coal ash in seawater

The deterioration of sediments is a serious environmental problem. Controlling nutrient release fluxes from sediments is important to alleviating eutrophication and to reducing terrigenous nutrient loads. The purpose of this study was to evaluate the phosphate removal performance of granulated coal ash (GCA) from seawater, which is produced from coal thermal electric power generation. Batch experiments were carried out to investigate the removal kinetics of phosphate from seawater under both oxic and anoxic conditions. Phosphate was removed well from seawater under both oxic and anoxic conditions. The adsorption isotherm for phosphate revealed that GCA could remove phosphate effectively from seawater above a concentration of 1.7 μmol L⁻¹. GCA can reduce the concentration of phosphate in seawater effectively under anoxic conditions where iron type adsorbents cannot be applied. Therefore, GCA could potentially be used to adsorb phosphate in the organically-enriched sediment, which generally occurs under highly reductive conditions.     

长白山地区火山碎屑粒度特征研究

长白山地区全新世火山活动活跃,发育了良好的火山空降、火山碎屑流、火山涌流和火山泥石流堆积物。这些堆积物交错堆积,野外区分较为困难。在火山碎屑地层剖面调查基础上,系统采集了各种类型的火山碎屑堆积物样品。在实验室通过粒度参数和概率累积曲线分析,对堆积物成因类型进行了判别,讨论了火山空降堆积物和火山碎屑流堆积物随着与火口距离变化的规律。首次对研究区内粒度范围为62.5～0.02μm的细火山灰进行了粒度分析,对火山碎屑流和火山碎屑涌流中细火山灰端元分布特征和地质意义进行了分析和讨论     

Liquefaction behaviour of loose and compacted pond ash

Most of the ash produced all over the world is primarily disposed off by wet disposal method onto the ash ponds, which are occupying huge valuable lands. This disposal problem can be minimized by utilizing ash in large geotechnical earthworks. However, its use in earthquake prone areas requires thorough understanding of its liquefaction resistance and nature of development of excess pore pressures under dynamic loading conditions. Investigations have been carried out in this paper on the liquefaction behaviour of pond ash by conducting cyclic triaxial tests on inflow and outflow ash samples collected from two different ash ponds. Distinctly different liquefaction phenomenon was observed for the ash samples from inflow and outflow points of the same ash pond. Inflow samples exhibited higher cyclic resistance than outflow samples and their strengths were comparable with the natural sands. Further studies revealed that the influence of various factors on liquefaction susceptibility of both the types of ashes is similar to that of natural sands.     

橡胶颗粒改良粉煤灰土的动力特性试验研究

对橡胶颗粒改良粉煤灰土的动强度、动模量、黏聚力和内摩擦角进行了动三轴试验研究,并将试验结果与粉煤灰土的动力特性加以对比,分析表明：粉煤灰土及橡胶颗粒改良粉煤灰土在同一围压下动强度均随破坏周数的增加而减小;在同一破坏周数下动强度随着围压的增加而增加;粉煤灰土的黏聚力为203.73 kPa,内摩擦角为11°;橡胶颗粒改良粉煤灰土的黏聚力为227.26 kPa,内摩擦角为17°,橡胶颗粒改良粉煤灰土的黏聚力增大了23.53 kPa,提高了11.55%;粉煤灰土的初始切线模量及平均动模量高于橡胶颗粒改良粉煤灰土的初始切线模量及平均动模量。研究表明,橡胶颗粒改良后的粉煤灰土具有动强度高、黏聚力和内摩擦角大的特点,从而说明橡胶颗粒改良后的粉煤灰土可以作为季冻区路基冷阻层材料     

中国油气页岩分布与存储潜能和前景分析

基于当今化石油气能源的需求还在扩展,它的紧缺势态波及全球,而我国的确需要更多的页岩油气.为此,非常规油气能源,特别是页岩油气的勘探、开发和利用就必然地提到社会进步和经济发展的议程上,并得到世界各个国家的高度重视.因此,页岩油气现已成为我国能源界和科技界及政府部门的热门话题.在经过了一段时间的"热炒"和依据尚不充分的评估后,本文通过对中外有关资料的分析和讨论认为:1)必须在了解世界各国、特别是北美页岩油气赋存与开发的条件下,认识我国页岩的分布状态和页岩油气潜能;2)在理解其它国家页岩属性、页岩油气的前景和勘查及储存背景下,在我国较全面的进行页岩和页岩油气存储的勘探和对其进行要素匹配,并选择远景好的典型地区进行示范研究与探索;3)集理念与实践综合研究制定页岩油气在我国的发展方案和路线图.     

水泥-粉煤灰浆液在水电站隧洞灌浆中的应用

针对三叉水电站引水隧洞Ⅳ标段围岩地质条件,详细分析了水泥-粉煤灰浆液在该工程引水隧洞灌浆中的应用情况。从应用情况综合分析可以得出,隧洞灌浆采用水泥-粉煤灰浆液是可行的,完全能满足设计要求,在保证灌浆质量的前提下,可以降低部分施工成本,具有较好的推广应用价值。     

基于力学思想的空间聚类有效性评价

从力学的角度来考虑空间聚类问题,并结合地理学基本规律提出了一种基于力学思想的空间聚类有效性评价指标(简称SCV)。实验分析表明,本文提出的评价指标能够更准确、高效地对二维地理空间数据的硬聚类结果进行有效性评价。     

The chemical composition including the Rare Earth Elements of the three major glass types of Europe and the Orient used in late antiquity and the Middle Ages

Sets of 20 soda ash glasses, 16 soda lime glasses and 23 wood ash glasses mainly from excavations in Europe (additional soda ash glasses from Egypt) were analysed on 61 chemical elements. Average SiO₂ is about 62% in soda glasses and 50% in wood ash glasses. The three groups of glasses contain on average 13% Na₂O, 18% Na₂O and 13% K₂O as fluxes to lower the melting temperature of quartz at their production. The starting materials beside quartz were halophytic plant ash for soda ash glass, trona (Na₃H(CO₃)₂·2H₂O) and lime (clamshells) for soda lime glass and beech ash for wood ash glass. Each of the three major glass types contains specific Rare Earth Element (REE) concentrations mainly contained in quartz and its intergrown minerals. 50 Paleozoic and Mesozoic sandstones from Central Europe represent the quartz composition. The REE pattern of these glasses apparently indicates major compositional stages of the Continental Earth's Crust. The boron to lithium and sodium to potassium ratios as in seawater suggest reactions of materials for soda glass with seawater. Negative Ce anomalies in the three glasses are caused by reactions of quartz with seawater.     

Block‐and‐ash flow deposit of the Narcondam Volcano: Product of dacite–andesite dome collapse in the Burma–Java subduction complex

Narcondam Island in the Andaman Sea represents a dacite–andesite dome volcano in the volcanic chain of the Burma–Java subduction complex. The pyroclasts of andesitic composition are restricted to the periphery of the dome predominantly in the form of block‐and‐ash deposits and minor base surge deposits. Besides pyroclastic deposits, andesitic lava occurs dominantly at the basal part of the dome whereas dacitic lava occupies the central part of the dome. The pyroclasts are represented by non‐vesiculated to poorly vesiculated blocks of andesite, lapilli, and ash. The hot debris derived from dome collapse was deposited initially as massive to reversely‐graded beds with the grain support at the lower part and matrix support at the upper part. This sequence is overlain by repetitive beds of lapilli breccia to tuff breccia. These deposits are recognized as a basal avalanche rather than lahar deposit. This basal avalanche was punctuated by an ash‐cloud surge deposit representing a sequence of thinly bedded units of normal graded unit to parallel laminated beds.