Nitrogen loadings to two small estuaries,Prince Edward Island,Canada: a 2‐year investigation of precipitation,surface water and groundwater contributions

In this research the dissolved inorganic nitrogen (DIN) loadings from direct precipitation, stream flow and groundwater discharge to two small estuaries located in Prince Edward Island (PEI), Canada, were quantified over a 2‐year period. The two estuaries, like many around the world, exhibit deteriorating conditions that are believed to be related to excessive nitrogen transport from adjacent catchments. The significance of the groundwater transport pathway and the temporal variability of the loadings have not been previously investigated. The wet fraction of the atmospheric loading was quantified using available precipitation and DIN concentration records. Stream water entering the estuaries and the discharge from numerous shoreline springs, the predominate form of groundwater discharge, were monitored periodically during the study. The annual DIN loads delivered to both estuaries were dominated by streams, although groundwater discharge provided significant contributions of approximately 15–18%. Temporal variability of DIN loading was large, with monthly loads varying by a factor of 5; this variability was found to be primarily related to the variability of freshwater discharge. Concentrations of nitrate in stream water discharging to the estuaries and shoreline groundwater springs were similar in each catchment, suggesting that there was minimal differential attenuation during transport via these two pathways. The McIntyre Creek estuary had one of the highest normalized loads reported in the literature (1700 kg NO₃‐N/ha estuary/year), more than four‐fold that of the Trout River estuary, and this result appears to be related to the larger percentage of land area used for potato production in the catchment. This study demonstrates that direct groundwater discharge to estuaries in PEI should not be ignored and that seasonal variations in loading may be important for managing DIN delivery to such estuaries. Copyright © 2010 John Wiley & Sons, Ltd.     

Environmental mercury and arsenic sources in fossil hydrothermal systems, Northland, New Zealand

 Northland, New Zealand has been affected by natural hot water spring systems depositing elevated concentrations of mercury and arsenic over the past 5 million years. Due to the different erosion levels of these hot water systems, four principal types of mercury and arsenic occurrences are found: active hot springs; layered surface deposits (sinters) deposited by hot springs; highly fractured rock zones formed immediately beneath hot springs; and chemically altered and mineralized rock from the deeper roots of hot spring systems. Mercury occurs principally as cinnabar and as a minor impurity (<1 wt%) in phosphate minerals and iron sulfides, particularly marcasite. Mercury is irregularly distributed through limonitic cements formed during oxidation. Arsenic occurs as a minor impurity (<1 wt%) in phosphate minerals and iron sulfides, particularly marcasite. Arsenic is also variably dispersed through limonite, but not necessarily with mercury. Decomposition of marcasite constitutes the most significant source of mercury and arsenic pollution from the studied sites. Release of mercury and arsenic into the environment from marcasite, phosphates and limonite is enhanced by acidification of the sites (down to pH of 2), caused by oxidation of iron sulfides. Mercury and arsenic concentrations of up to 100 parts per billion should be expected in waters near the deposits; these concentrations are in excess of recommended drinking water levels. Received: 9 April 1999 · Accepted: 2 August 1999     

The Manawatu aquifers,North Island,New Zealand: Clarification of hydrogeology using a multidisciplinary environmental tracer approach

A recently developed approach to carbon isotope methodology (process recognition via isotope diagrams) is applied in a multidisciplinary study of precipitation‐recharged aquifers of the lowlands–plains area of the Manawatu (south‐west North Island). Urban and rural areas rely on groundwater from the upper levels of a deep basin sequence comprising marine and terrestrial sediments of Pleistocene age. Hydrochemical and isotopic (¹⁸O, ³H, ¹³C and ¹⁴C) data are merged with known details of geology and hydrogeology to reveal two separate confined aquifers within the depth range to 200 m. The shallower of these, below unconfined, locally recharged groundwater, is recharged on the foothills of the Ruahine Range to the north‐east of the study area; flow direction is NE–SW. The deeper confined aquifer is recharged on the Tararua Range to the immediate east; flow direction essentially is transverse (SE–NW) to that in the shallower aquifer. Two processes are identified as dominant contributors to concentration and isotopic composition of dissolved inorganic carbon (DIC), namely addition of CO₂ from decay of organic materials and carbonate dissolution. Limitations of carbon isotope methods in determining residence times are illustrated by the data. Although the confined groundwater is essentially tritium‐free, only a few samples showed conclusive evidence of significant ageing on the time‐scale of ¹⁴C. Copyright © 2001 John Wiley & Sons, Ltd.     

An ecological and hydrochemical study of three springs in NE Iran with the emphasis on diatom diversity

Springs are complex and taxa rich ecosystems. Diatom assemblages have received very little attention in spring ecosystems in Iran; hence, the diatom assemblage in three selected springs in northeast Iran, were investigated using multivariate analysis together with hydro chemical measures. For this purpose, water and diatom samples collected during four seasons of 2019. Hydrochemistry results revealed that water-rock interaction is the most important factor in changing the water chemistry of studied springs and their waters produced from carbonate reservoir rocks (mainly calcite). As a result, Ca-HCO₃ is predominate water type in all three springs. In this study, 75 diatom taxa identified, from which 55 were included in the analysis. Cluster analysis based on diatoms relative abundance, clustered samples in two major groups and third small group. Results of the indicator species analysis for groups and DCA analysis were in the absolute conformity. Results revealed that the diatom assemblage dominated by combination of early colonizer taxa, spring indicator taxa and cosmopolitan taxa; most of them also reported from different spring types. The results also showed that the spring’s diatom composition influence by size and morphology of the springs.     

Was there ice along the shore of the Sea of Galilee during the last 12,000?—Reply to a comment by Prange et al. (2007) and a comment by Friedman (2007)

Prange et al. (2007) question our reconstruction of the Sea of Galilee (Lake Kinneret) paleoclimate and argue that a “careful” analysis of the paleoclimatic analysis leads to much smaller cooling events than we have considered. By and large, their “careful” analysis is based on correlating the paleotemperatures of the Lake with those of the northern Red-Sea that (geographically) is much closer to the Lake than the two Mediterranean cores that we used. Ironically, their argument contradicts Friedman’s (2007) statements (the second comment on our original paper), which are based on still-closer cores and support our larger cooling choices. This issue alone would be enough to dismiss the uniqueness of PAL argument but there is another issue with their work that we wish to comment on. In support of their own small cooling argument, PAL present winter correlation maps that indeed show a stronger correlation of the northern Red-Sea SST to the lake SST than the correlation of Mediterranean SST with the lake SST. This seemingly correct correlation argument of PAL is totally false (for both daily and millennial time scales) because it has no climatological basis. On the daily time scale, all the storms that reach the Lake originate in the Mediterranean Sea (to the west of the lake), not the Red-Sea (which lies 700 km south of the lake). Also, although the lake and the Red-Sea are only 700 kilometers apart, their climates are very different because they are subject to two totally different air masses. While the climate of the Red-Sea region is desert-like, the climate of the region surrounding the lake is a typical wet Mediterranean climate. Seasonal correlation maps (and even monthly maps) such as those presented by the authors filter out the storms that control the winter climate in the lake region because these storms occur on a daily scale. With this filtering, all that one is left with is the low frequency first baroclinic mode, which merely reflects the Rossby radius scale (measured from the lake). On the millennial time scale, cold events in the lake regions (from an earlier period) have been attributed to Bond cycles and Heinrich events both of which are global and not local processes. As such, they are probably forced by variability in the solar radiation rather than a local process implied by PAL. Overall, all that the PAL correlation shows for both daily and millennial time scales is that changes in the temperature in the Red-Sea occur at the same time as they do in the Lake. But this does not say anything about the dynamics in question and does not imply that it is better to use records from the Red-Sea (which does not lie within the path of the zonal winds reaching the Lake). Neglecting this issue (as proposed by PAL) distorts the physics and reminds us of the classical statistical example for the limitations involved in the interpretation of correlation—the incidence of lung cancer is strongly correlated with the incidence of carrying matches in ones pocket even though the matches do not cause the cancer and the cancer does not force one to carry matches.     

Fluid-dynamics driving saline water in the North East German Basin

In several areas of the North German Basin, saline water comes close to, or even reaches the surface. Available data from wells indicate that brine stratification is under unstable conditions in the deeper underground. In order to analyse the possible transport mechanisms, 3D thermohaline simulations have been carried out for two different scenarios. The 3D regional model (230×330 km) indicates that salty water is driven to the surface by hydrostatical forces from the surrounding highlands. In addition, a smaller scale model (10×10 km) has been constructed with a grid resolution accounting for possible convective flow. The results indicate that convective flow may play a dominant role in areas with minor topography. In summary, the complex pattern of near surface occurrences of saline water probably results from the interaction of hydrostatic and thermal forces.     

Geologic controls of submarine groundwater discharge: application of remote sensing to north Lebanon

Typical of Mediterranean countries, the Lebanese shoreline is well known for its littoral and offshore groundwater discharges, the so-called submarine springs. The tectonic framework of the terrain explains its interruption by dense geologic structures, i.e., fracturing, faulting, karstic routes, as well as acute dips of rock strata seaward. All of these structures serve as hydrologic agents transporting groundwater to the sea. The study aims to locate these groundwater discharges, and to interpret their geologic controls on land. For this purpose, two major lines of approach were followed. The first is an airborne thermal infrared (TIR) survey using radiometers to identify thermal anomalies, thereby determining the exact location of submarine groundwater discharges (SGDs). The second line of approach is the analysis of satellite images (Landsat 7ETM⁺) to delineate the geologic features that govern the mechanism of water flow, thereby determining their sources on land. Twenty-seven major SGDs were identified, 10 of these being offshore springs, the others littoral springs. The springs show a large variety of discharge configurations and extents, mainly parallel or perpendicular to the shoreline or rounded. Three major structural controls were identified to contribute to the transport of groundwater to the sea. These are karstic galleries, faults, and tilted rock strata, their contributions being 48, 37, and 15%, respectively. The SGDs associated with linear passageways, i.e., karstic galleries and faults, are connected with land aquifer formations several kilometers away from the shoreline. Moreover, the presence of impervious rock formations at many localities along the coastline results in a confined hydrologic system, promoting the flow of SGDs into the sea.     

追远古地史,溯济南泉源

古生物的化石形成了岩石,沉积的岩层由于地壳沉降,形成了褶皱、断裂,燕山运动奠定了现代地形地貌和济南的泉水蓄水构造的基本框架.本文从地质构造方面叙述了泉水形成的历史成因.     

中国东北地区地热资源及热结构分析

在我国东北地区，盆地的热流高而在山区和地台区（额尔古纳和佳木斯地台）热流较低，通过对该区的研究发现，在地壳和上地幔中莫霍面埋深，高导层埋深和热流值之间存在着密切的联系，通过对该区热流数据分析我们可以得到这样的结论：该区的地壳和上地幔的热结构引起了热流分布的变化。计算结果还表明，该区地台的地幔热流，地壳中10km以下和10km以上的热流对地表热流的贡献不同。该区松辽盆地中广泛分布着传导型中低温地热资源，对松辽盆地地热资源的开发利用有着广泛的前景。最后结合已有的地质和物探资料，还给出了长白山天池火山地区长白温泉地热系统的概念性模型。     

娘子关泉群岩溶水系统西部子系统径流特征研究

根据娘子关泉群系统西部控水构造、含水层段、水动力场等水文地质条件，重新划定了娘子关岩溶水系统西部边界(兴道-大方山-郭家沟-线构造带)，则东山区成为娘子关的一个补给径流区。在此基础上，对西部子系统岩溶水径流特征提出了新的见解。