Stormflow concentration–discharge dynamics of suspended sediment and dissolved phosphorus in an agricultural watershed

Concentration–discharge (C-Q) relationships are an effective tool for identifying watershed biogeochemical source and transport dynamics over short and long timescales. We examined stormflow C-Q, hysteresis, and flushing patterns of total suspended sediment (TSS) and soluble reactive phosphorus (SRP) in two stream reaches of a severely impaired agricultural watershed in northeastern Wisconsin, USA. The upper watershed reach—draining a relatively flat, row crop-dominated contributing area—showed predominantly anti-clockwise TSS hysteresis during storms, suggesting that particulate materials were mobilized more from distal upland sources than near- and in-channel areas. In contrast, the incised lower watershed reach produced strong TSS flushing responses on the rising limb of storm hydrographs and clockwise hysteresis, signalling rapid mobilization of near- and in-channel materials with increasing event flows. C-Q relationships for SRP showed complex patterns in both the upper and lower reaches, demonstrating largely non-linear chemodynamic C-Q behaviour during events. As with TSS, anti-clockwise SRP hysteresis in the upper reach suggested a delay in the hydrologic connectivity between SRP sources and the stream, with highly variable SRP concentrations during some events. A broad range of clockwise, anti-clockwise, and complex SRP hysteresis patterns occurred in the lower watershed, possibly influenced by in-channel legacy P stores and connection to tile drainage networks in the lower watershed area. Total suspended sediment and SRP responses were also strongly related to precipitation event characteristics including antecedent precipitation, recovery period, and precipitation intensity, highlighting the complexity of stormflow sediment and phosphorus responses in this severely impaired agricultural stream.     

Late Triassic E-MORB-like basalts associated with porphyry Cu-deposits in the southern Yidun continental arc,eastern Tibet: Evidence of slab-tear during subduction?

It is generally believed that andesite–dacite–rhyolite suites and contemporary porphyry Cu deposits are related to subduction in active continental margin settings. However, it is still unclear which tectonic events result in the generation of porphyry Cu deposits and whether asthenospheric mantle material is involved in this process. Widespread andesitic–dacitic felsic intrusions associated with porphyry Cu deposits and rarer basalts have been identified in the Late Triassic southern Yidun arc (SYA) of eastern Tibet. However, few geochronological and geochemical data are available for these basalts, thereby hampering the development of geodynamic models for this magmatic event and the formation of related porphyry Cu deposits in the region. Here we present the first geochemical and SIMS (secondary ion mass spectrometry) zircon U–Pb data of Xiaxiaoliu basalts in the SYA. The age of the Late Triassic Xiaxiaoliu basalts (216.1 ± 2.8 Ma) is consistent with the timing of emplacement of voluminous porphyritic intrusions and the formation of Cu deposits within the SYA (peaking at 215–217 Ma). The Xiaxiaoliu basalts have E-MORB-like trace element patterns that are free of negative Nb–Ta anomalies, and have high ¹⁴³Nd/¹⁴⁴Nd_(t) values, suggesting they were sourced from asthenospheric mantle without any arc-type influence. These observations, combined with the fact that some Late Triassic mineralized porphyritic intrusions within the SYA have adakitic affinities, suggest that the basalts and other igneous rocks and associated porphyry Cu deposits within the SYA were produced by tearing of a westward-dipping slab, triggering the upwelling of asthenospheric mantle material during subduction of the Garze–Litang Ocean crust.     

中条山地区郭家沟基性-超基性岩体的岩石成因及地质意义

文章通过对中条山地区郭家沟基性-超基性岩体的岩石学、矿物学和岩石地球化学方面的分析研究,讨论了该岩体的形成时代、岩石成因、及其地质意义。郭家沟岩体侵入时代为元古代,可能与绛县群形成时代较为相近(2200Ma左右)。郭家沟岩体具有岩相分带现象,边缘相为辉长岩,向内渐变过渡为含长辉石岩、变余辉石岩(角闪石岩)等,在岩体的中心发育着磁铁透闪石岩;岩石中Mg O与其他主量元素线性相关,各类岩石地球化学特征较为相似,显示出岩石受分离结晶作用的影响,具有岩浆同源演化的趋势;岩石总体显示出低硅、低镁、高铁、高钛、高钙的特征,相对富集LREE和LILE,而亏损HREE和Nb、Ta、Zr、Y等高场强元素,轻重稀土分馏明显,具有较弱的Eu异常,V含量较高,具有阿拉斯加型侵入岩体和与火山弧相关的岩浆特征。从岩石组合及地球化学特征结合区域构造演化,认为岩体形成于大陆边缘弧的构造环境,从侧面也说明绛县群的形成环境应该是大陆边缘俯冲后的伸展环境,而非陆内裂谷。     

U–Th–Pb monazite dating and the timing of arc–continent collision in East Timor

The Timor Orogen represents one of the youngest arc–continent collisions exposed on the Earth. It has the potential to provide some of the key parameters about how this style of orogeny evolves. However, the metamorphic age of the highest-grade rocks formed in the collision remains controversial. Using U–Th–Pb dating of monazite from amphibolite-grade sillimanite and garnet-bearing schists we show the peak metamorphism occurred at 5.5–4.7 Ma. The young age of the monazite and the presence of significant amounts of common Pb required the development of a new protocol to simultaneously account for the ²³⁰Th disequilibrium and the ²⁰⁷Pb common Pb correction. The new estimate of metamorphic age is consistent with the estimates based on plate reconstructions for the initiation of arc–continent collision in East Timor. The metamorphic event is a result of this collision.     

Origin of the alkali tonsteins from southwest China: Implications for alkaline magmatism associated with the waning stages of the Emeishan Large Igneous Province

A unique type of Nb–Zr–REE–Ga-enriched alkali tonstein of pyroclastic origin occurs exclusively within the late Permian coal measures of southwest China. The alkali tonsteins are located within the lowest Xuanwei or Longtan formations of Wuchiapingian age, indicating that their age is later than the main episode of Emeishan Large Igneous Province (ELIP) magmatism. The alkali tonsteins have intermediate–felsic Al₂O₃/TiO₂ values (12.6–34.2, mean 22.0), light rare earth element-enriched chondrite-normalised patterns, negative δEu and incompatible element ratios similar to those of ELIP alkaline Nb–Ta-enriched syenites. All available evidence shows that the alkali tonsteins from southwest China originated from coeval ELIP alkaline magmatism. The enrichment of Nb–Zr–REE–Ga in alkali tonsteins is derived from the ELIP alkaline Nb–Ta-enriched volcanic ashes and may represent the last stage of mineralisation associated with the Emeishan mantle plume activity.     

Re-conceptualizing the Anthropocene: A call for collaboration

Since it was first proposed in 2000, the concept of the Anthropocene has evolved in breadth and diversely. The concept encapsulates the new and unprecedented planetary-scale changes resulting from societal transformations and has brought to the fore the social drivers of global change. The concept has revealed tensions between generalized interpretations of humanity’s contribution to global change, and interpretations that are historically, politically and culturally situated. It motivates deep ethical questions about the politics and economics of global change, including diverse interpretations of past causes and future possibilities. As such, more than other concepts, the Anthropocene concept has brought front-and-center epistemological divides between and within the natural and social sciences, and the humanities. It has also brought new opportunities for collaboration. Here we explore the potential and challenges of the concept to encourage integrative understandings of global change and sustainability. Based on bibliometric analysis and literature review, we discuss the now wide acceptance of the term, its interpretive flexibility, the emerging narratives as well as the debates the concept has inspired. We argue that without truly collaborative and integrative research, many of the critical exchanges around the concept are likely to perpetuate fragmented research agendas and to reinforce disciplinary boundaries. This means appreciating the strengths and limitations of different knowledge domains, approaches and perspectives, with the concept of the Anthropocene serving as a bridge, which we encourage researchers and others to cross. This calls for institutional arrangements that facilitate collaborative research, training, and action, yet also depends on more robust and sustained funding for such activities. To illustrate, we briefly discuss three overarching global change problems where novel types of collaborative research could make a difference: (1) Emergent properties of socioecological systems; (2) Urbanization and resource nexus; and (3) Systemic risks and tipping points. Creative tensions around the Anthropocene concept can help the research community to move toward new conceptual syntheses and integrative action-oriented approaches that are needed to producing useful knowledge commensurable with the challenges of global change and sustainability.     

长江中下游庐枞火山岩盆地南侧钾质侵入岩带的成因

庐枞火山岩盆地南侧的钾质侵入岩带由正长岩-石英正长岩-正长花岗岩组成,以石英正长岩为主。它们的形成时间介于123"130 Ma之间,峰值约为126 Ma,其中正长岩和石英正长岩的形成时间稍早,而正长花岗岩的形成时间略晚。整个钾质侵入岩带的侵位时间晚于庐枞盆地内的橄榄玄粗质火山作用约4"7 Ma,也是长江中下游地区除最东段的宁镇地区外中生代最晚的岩浆活动产物之一。地球化学上,该钾质侵入岩带以高钾、富碱、富集Rb、Th、U、K等强不相容元素和轻稀土元素、亏损高场强元素Nb、Ta和Ti为特征。它们的母岩浆主要是由富集型上地幔部分熔融形成的,从正长岩经石英正长岩到正长花岗岩的演化主要受矿物的分离结晶作用控制,地壳物质同化所起的影响不大。但与同样来自富集型上地幔部分熔融的庐枞盆地内火山杂岩的母岩浆相比,前者的母岩浆来源深度可能更大些或其中包含了更多来自软流圈地幔的组分。两者的演化路径也完全不同,钾质侵入岩带的母岩浆除经历过高压下的分离结晶作用外,晚期在低压下还经历过长石为主,可能还有黑云母的分离结晶,甚至上地壳物质一定程度的混染作用;而盆地内火山杂岩的母岩浆低压下矿物的分离结晶作用及上地壳物质的混染都不明显。庐枞盆地南缘的富钾侵入岩与盆地内的火山杂岩一样,地球化学上都具有明显的大陆弧的特征,暗示它们的岩浆源区可能形成于俯冲带环境,意味着扬子地块北缘先前(推测为古元古代晚期)曾发生过俯冲作用,上地幔的交代富集可能就与这次的俯冲作用有关。     

Preservation of coal-waste geochemical markers in vegetation and soil on self-heating coal-waste dumps in Silesia,Poland

Occurrence and distributions of geochemical markers on vegetation and in soils covering two self-heating coal waste dumps were investigated with gas chromatography-mass spectrometry (GC–MS) and compared with those of bitumen expelled on the coal waste dump surface. Presence of biomarkers, alkyl aromatic hydrocarbons, polycyclic aromatic hydrocarbons (PAHs), and such polar compounds as phenols indicate that components of self-heating coal wastes indeed migrate to soils and plants surface and their characteristic fingerprints can be applied in passive monitoring to investigate migration of contaminants from self-heating coal wastes. Moreover, results allow to discriminate between the Upper- and Lower Silesian coal basins, notwithstanding value shifts caused by heating. Mechanisms enabling the migration of geochemical compounds into soils include mixing with weathered coal-waste material, transport in gases emitted due to self-heating and, indirectly, by deposition of biomass containing geochemical substances. Transport in gases involves mostly lighter compounds such as phenols, methylnaphthalenes, methylbiphenyls, etc. Distributions and values of geochemical ratios are related to differences in their boiling temperatures in the case of lighter compounds but preserve geochemical features in the case of heavier compounds such as pentacyclic trierpanes.     

Petrogenesis and geodynamic evolution of the Kajan Neogene subvolcanic rocks,Nain, Central Iran

Kajan subvolcanic rocks in the Urumieh–Dokhtar magmatic arc (UDMA), Central Iran, form a Late Miocene-Pliocene shallow-level intrusion. These subvolcanics correspond to a variety of intermediate and felsic rocks, comprising quartz diorite, quartz monzodiorite, tonalite and granite. These lithologies are medium-K calc-alkaline, with SiO₂ (wt.%) varying from 52% (wt.%) to 75 (wt.%). The major element chemical data also show that MgO, CaO, TiO₂, P₂O₅, MnO, Al₂O₃ and Fe₂O₃ define linear trends with negative slopes against SiO₂, whilst Na₂O and K₂O are positively correlated with silica. Contents of incompatible trace elements (e.g. Ba, Rb, Nb, La and Zr) become higher with increasing SiO₂, whereas Sr shows an opposite behaviour. Chondrite-normalized multi-element patterns show enrichment in LILE relative to HFSE and troughs in Nb, P and Ti. These observations are typical of subduction related magmas that formed in an active continental margin. The Kajan rocks show a strong affinity with calc-alkaline arc magmas, confirmed by REE fractionation (La_N/Yb_N = 4.5–6.4) with moderate HREE fractionation (Sm_N/Yb_N = 1.08–1.57). The negative Eu anomaly (Eu/Eu* <1), the low to moderate Sr content (< 400 ppm) and the Dy/Yb values reflect plagioclase and hornblende (+- clinopyroxene) fractionation from a calc-alkaline melt Whole–rock Sr and Nd isotope analyses show that the ⁸⁷Sr/⁸⁶Sr initial ratios vary from 0.704432 to 0.705989, and the ¹⁴³Nd/¹⁴⁴Nd initial ratios go from 0.512722 to 0.512813. All the studied samples have similar Sr-Nd isotopes, indicating an origin from a similar source, with granite samples that has more radiogenic Sr and low radiogenic Nd isotopes, suggesting a minor interaction with upper crust during magma ascent. The Kajan subvolcanic rocks plot within the depleted mantle quadrant of the conventional Sr-Nd isotope diagram, a compositional region corresponding to mantle-derived igneous rocks.     

Multiple statistical approaches for the discrimination of mangrove species of Rhizophoraceae using transformed field and laboratory hyperspectral data

This study aims at discriminating eight mangrove species of Rhizophoraceae family of Indian east coast using field and laboratory spectra in spectral range (350–2500 nm). Parametric and non-parametric statistical analyses were applied on spectral data in four spectral modes: (i) reflectance (ii) continuum removed, (iii) additive inverse and (iv) continuum removed additive inverse. We introduced continuum removal of inverse spectra to utilize the advantage of continuum removal in reflectance region. Non-parametric test gave better separability than parametric test. Principal component analysis and stepwise discriminant analysis were applied for feature reduction and to identify optimal wavelengths for species discrimination. To quantify the separability, Jeffries–Matusita distance measure was derived. Green (550 nm), red edge (680–720 nm) and water absorption region (1470 and 1850 nm) were found to be optimal wavelengths for species discrimination. The continuum removal of additive inverse spectra gave better separability than the continuum removed spectra.