硅酸钡铜的光吸收谱和EPR谱

本文报道水热合成硅酸钡铜(BaCuSi_4O_(10))的光吸收谱和EPR谱。EPR测量表明,在硅酸钡铜中,Cu~(2 )离子位置有轴对称性。在这种对称性下,一般只能观察到三条Cu~(2 )离子的吸收谱带,但在BaCuSi_4O_(10)的吸收谱中却观察到了四条。这一矛盾用~2Eg激发态的动态Jahn-Teller效应来解释。本文提出的~2Eg和~2A_1g能级的相对次序与文献[2]的相反,文中对这一问题作了详细的分析。跃迁频率和g因子的计算值在实验误差范围内与观测值一致。     

A study on the sensitivity of the radar scattering coefficient to oceanic winds

Sensitivity of the radar scattering coefficient to the oceanic wind vector in the midangular range for frequencies from L- to Ku- band is studied. This is based on computations of scattering coefficient via the two-scale scattering theory employing a semi-empirical model for the ocean spectrum suggested by Fung and Lee and the slope distribution by Cox and Munk. Higher frequency and incident angles of over 45 degrees seem to yield better wind sensitivity.     

Least squares parameter estimation in chaotic differential equations

A recent least squares algorithm, which is designed to adapt implicit models to given sets of data, especially models given by differential equations or dynamical systems, is reviewed and used to fit the Hénon-Heiles differential equations to chaotic data sets.This numerical approach for estimating parameters in differential equation models, called theboundary value problem approach, is based on discretizing the differential equations like a boundary value problem,e.g. by a multiple shooting or collocation method, and solving the resulting constrained least squares problem with a structure exploiting generalized Gauss-Newton-Method (Bock, 1981).Dynamical systems like the Hénon-Heiles system which can have initial values and parameters that lead to positive Lyapunov exponents or phase space filling Poincaré maps give rise to chaotic time series. Various scenarios representing ideal and noisy data generated from the Hénon-Heiles system in the chaotic region are analyzedw.r.t. initial conditions, parameters and Lyapunov exponents. The original initial conditions and parameters are recovered with a given accuracy. The Lyapunov spectrum is then computed directly from the identified differential equations and compared to the spectrum of the true dynamics.presently at IWR, Universität Heidelberg, Im Neuenheimer Feld 368, D-6900 Heidelberg, Germany     

Experimental Study of Mechanical Behaviour of Rock Joints Under Cyclic Loading

Summary Evaluation of the effects of small repetitive earthquakes on the strength parameters of rock joints in active seismic zones is of interest of the designers of underground constructions. In order to evaluate these effects, it is necessary to study the behaviour of rock joints under dynamic and cyclic loadings. This paper presents the results of a systematic study on the behaviour of artificial rock joints subjected to cyclic shearing. More than 30 identical replicas have been tested using triaxial compression devices under different conditions of monotonic and cyclic loading. At the first stage a few samples have been tested in monotonic loading modes under various confining pressures and rate of displacement. In the second series of tests, small cyclic loads were applied on the samples for increasing number of cycles, frequency levels and stress amplitudes. These were then followed by monotonic loading again. The variations of maximum and residual shear strengths for each test have been studied. The results show increase of shear strength as a result of the increase in confining pressure and they display decrease of shear strength due to the increase of rate of loading, number of cycles, frequency levels and stress amplitudes.     

塔河油田叠后地震资料高保真处理技术

塔河油田岩溶储集体(洞穴、礁滩、孔洞、裂缝或裂隙等)的地震波场特征是弱反射背景之上的强弱不同的绕射波,因此,绕射波准确归位成像和振幅保持是研究岩溶储集体的基础。笔者从塔河油田地震资料高保真处理实践中,总结出了一套适应该区碳酸盐岩储层预测要求的以叠后高精度偏移算法和振幅保持处理为主的叠后高保真处理技术,取得显著的效果。     

刺猬沟金矿石英包体成矿溶液电导度和红外光谱找矿标型

石英是刺猬沟金矿重要的脉石矿物,也是金的主要载体.借助于成矿溶液电导度和红外光谱方法对刺猬沟金矿石英进行了分析,结果表明,成矿溶液电导度和红外光谱测定的DCO₂与石英中金含量呈正相关关系,成矿溶液电导度大于5.7 μS,DCO₂大于0.2矿化好.这对该找矿和矿床评价具有指导意义.     

Geomagnetic diurnal-variation anomalies and their relation to strong earthquakes

The diurnal-variation anomalies of the vertical-component in geomagnetic field are mainly the changes of phase and amplitude before strong earthquakes. On the basis of data recorded by the network of geomagnetic observatories in China for many years, the anomalous features of appearance time of the minima of diurnal variations (i.e, low-point time) of the geomagnetic vertical components and the variation of their spatial distribution (i.e, phenomena of low-point displacement) have been studied before over 30 strong earthquakes with M _S≥6.6 such as Kunlunshan M _S=8.1 earthquake on November 14, 2001; Bachu-Jashi M _S=6.8 earthquake on February 24, 2003; Xiaojin M _S=6.6 earthquake on September 22, 1989, etc. There are good relations between such rare phenomena of geomagnetic anomalies and the occurrence of earthquakes. It has been found that most earthquakes occur in the vicinity of the boundary line of sudden change of the low-point displacement and generally within four days before and after the 27th or 41st day counting from the day of appearance of the anomaly. In addition, the anomalies of diurnal-variation amplitude near the epicentral area have been also studied before Kunlunshan M _S=8.1 earthquake and Bachu-Jiashi M _S=6.8 earthquake. Foundation item: National Science Technology Tackle Key Project during the Tenth Five-year Plan (2001BA601B01-05-04)     

The Use of Field Dependence of Magnetic Susceptibility for Monitoring Variations in Titanomagnetite Composition - A Case Study on Basanites from the Vogelsberg 1996 Drillhole,Germany

In high Ti basanites from the Vogelsberg 1996 drillhole distinct variations in the field dependence of AC magnetic susceptibility correlate with compositional variations of titanomagnetite, as determined by temperature dependence of magnetic susceptibility. Curie temperatures for the basanites are in the range of 240 to 525°C. The field dependence reaches up to 20% for measurements in 30 A/m and 300 A/m AC field amplitude. It is demonstrated that two-field magnetic susceptibility measurements can prevail information about compositional changes of titanomagnetite and therefore support the interpretation of magnetic susceptibility logs from drillcores of basaltic rock suites.     

基于GPS技术的大桥自振频率测量研究

以GPS快速静态相对定位技术对武汉白沙洲长江大桥进行自振频率测试,采用GPS动态监测的方法,通过对悬索桥关键点的点位测量和三维位移进行动态实时监测以及对测量数据的分析,得出点位时程图,经频谱分析得出长江三桥的自振特征要素。     

利用SAR图像计算内波深度和振幅的可行性研究

根据星载合成孔径雷达(SAR)内波成像机理,建立了包括KdV方程、作用量谱平衡方程和Bragg散射模型在内的内波深度和振幅探测模型,更为严谨地推导出用SAR图像计算内波深度的方法,并首次推导出内波振幅的计算方法.利用该方法对台湾东北部海域的两幅ERS-1 SAR内波图像进行了实例研究,结果表明,该方法是合理且可行的.