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21.
Makoto Haruna Takahiro Hanamuro Kaoru Uyeda Hirokazu Fujimaki Hiroshi Ohmoto 《Resource Geology》2003,53(2):75-88
Abstract. The petrography, chemical, fluid inclusion and isotope analyses (O, Rb-Sr) were conducted for the shale samples of the Mount McRae Shale collected from the Tom Price, Newman, and Paraburdoo mines in the Hamersley Basin, Western Australia. The Mount McRae Shale at these mines occurs as a footwall unit of the secondary, hematite-rich iron ores derived from the Brockman Iron Formation, one of the largest banded iron formations (BIFs) in the world. Unusually low contents of Na, Ca, and Sr in the shales suggest that these elements were leached away from the shale after deposition. The δ18 O (SMOW) values fall in the range of + 15.0 to +17.9 per mil and show the positive correlation with calculated quartz/sericite ratios of the shale samples. This suggests that the oxygen isotopic compositions of shale samples were homogenized and equilibrated by postdepositional event. The pyrite nodules hosted by shales are often rimmed by thin layers of silica of varying crystallinity. Fluid inclusions in quartz crystals rimming a pyrite nodule show homogenization temperatures ranging from 100 to 240C for 47 inclusions and salinities ranging from 0.4 to 12.3 wt% NaCl equivalent for 18 inclusions. These fluid inclusion data give direct evidence for the hydrothermal activity and are comparable to those of the vein quartz collected from the BIF-derived secondary iron ores (Taylor et al, 2001). The Rb-Sr age for the Mount McRae Shale is 1,952 ± 289 Ma and at least 200 million years younger than the depositional age of the Brockman Iron Formation of ∼ 2.5 Ga in age. All the data obtained in this study are consistent with the suggestion that high temperature hydrothermal fluids were responsible for both the secondary iron ore formation and the alteration of the Mount McRae Shale. 相似文献
22.
23.
痕量铁和锰的化学发光检测 总被引:5,自引:1,他引:5
评述了国内外有关铁、锰的化学发光分析进展。从发光体系、操作方式、最佳条件、干扰离子、检测限等各个方面对化学发光法测定铁、锰及其它们与其它组分同时测定中的应用进行分类评述。 相似文献
24.
榴辉岩中铁铝榴石的测定方法研究 总被引:3,自引:1,他引:3
对国内主要矿区铁铝石榴子石纯矿物中铁的价态规律进行了研究。证明其所含Fe均以Fe^2+为主,其质量分数在83-94,并将Fe^2+这特征性成分用于某地榴辉岩中铁铝榴石的间接测定,获得结果与焙烧磁化-磁选法一致且精度好,较磁化法简便,快速。 相似文献
25.
水/岩作用实验研究表明,在低温条件下柠檬酸、草酸和酒石酸对岩石中的铁、铜都有很高的淋滤率。这表明,在表生地质作用过程中有机酸对成矿元素有很强的活化能力。实验研究同时发现,有机酸对成矿元素的活化能力受其分解温度的限制,由于大部分有机酸的分解温度都在250℃以下,因而有机酸对成矿元素的活化仅限于低温条件。本次研究还显示,判断一种岩石能否成为矿源层,不能简单的以其中成矿元素的含量高低作为标准,其中更关键的因素是元素在岩石中的存在形式,如果成矿元素在岩石中难以活化的形式存在,那么含量再高也无法提供成矿物质 相似文献
26.
西昆仑山南侧甜水海湖岩芯铁变化的环境记录 总被引:11,自引:0,他引:11
阐述了青藏高原西昆仑山南侧甜水海湖岩芯沉积物中氧化铁的丰度、频率分布和富集系数的变化规律。其丰度值范围FeO0.39%-3.95%,平均值为1.25%;Fe2O30.44%-8.09%,平均值为2.60%;Fe2O3/FeO0.21-3.60,平均比值1.12。说明该彻岩芯沉积物中铁平均丰度值较低,但其变化幅度较宽且清楚,在一定程度上反映了古气候环境具有较大幅度的波动。变异系数值表明,该湖岩芯沉积物中FeO的离散程度较Fe2O3大。大约距今23万年来氧化铁的沉积地球化学特征可划分出7个环境演化阶段,并基本上可与深海氧同位索阶段对比。揭示了甜水海湖演化与青藏高原强烈隆升引起的气候环境改变的密切关系。在距今23一15万年,沉积以河流相或冲积、洪积相为主,沉积环境以氧化环境为主导,气候以温干型波动;在距今15-7.4万年,沉积以湖相为主,沉积环境以还原环境为主导,气候以温湿型为主;在距今74万年以来,湖盆沉积环境多样化,沉积物以湖相和近源冲积、洪积相交替出现。气候出现冷湿、冷干、温湿和温干多种波动模式。这些资料分析初步认为甜水海古湖大约形成于距今15万年,即青藏高原第三成湖期,这也与青藏高原在距今15万年左右的再次构造隆升有关。 相似文献
27.
Sébastien J. Stemmler Stéphanie Loyaux-Lawniczak Jacques Berthelin 《Comptes Rendus Geoscience》2004,336(13):1171-1179
Iron-reducing activity of autochthonous bacteria from two temporary hydromorphic soils is evaluated by the study of iron reductive dissolution, as a function of water content. The release of ferrous iron in solution is coupled to the mineralization of soil organic carbon. Water soil saturation is not necessary for iron reductive dissolution, since the highest dissolution is obtained for a wet, but not water-saturated soil (100% of water holding capacity WHC), and dissolution is also very high in a soil at 75% WHC. To cite this article: S.J. Stemmler et al., C. R. Geoscience 336 (2004). 相似文献
28.
Global dust trajectories indicate that signi?cant quantities of aeolian‐transported iron oxides originate in contemporary dryland areas. One potential source is the iron‐rich clay coatings that characterize many sand‐sized particles in desert dune?elds. This paper uses laboratory experiments to determine the rate at which these coatings can be removed from dune sands by aeolian abrasion. The coatings impart a red colour to the grains to which previous researchers have assigned variable geomorphological signi?cance. The quantities of iron removed during a 120 hour abrasion experiment are small (99 mg kg?1) and dif?cult to detect by eye; however, high resolution spectroscopy clearly indicates that ferric oxides are released during abrasion and the re?ectance of the particles alters. One of the products of aeolian abrasion is ?ne particles (<10 µm diameter) with the potential for long distance transport. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
29.
Simultaneous in situ immobilisation of uranium (U) and radium (226Ra) by injectible amounts of grey cast iron (gcFe), nano-scale iron (naFe) and a gcFe/MnO2 mixture (1:1) was studied in batch and column tests. Both 0.5 g/L naFe and gcFe are effective in 226Ra and U removal from mine water, whereas MnO2 addition clearly increased the efficiency of gcFe for 226Ra and U immobilisation. In a column test with 0.6 wt% gcFe/MnO2 mixture (1:1), neither 226Ra nor U was detected in the effluent after replacement of 45 pore volumes. A sequential extraction under flow condition revealed 226Ra to be mostly occluded in manganese oxides. Uranium was mostly sorbed onto poorly crystalline iron hydroxides, but a significant part was found to be occluded in manganese oxides also. The results of this study suggest that MnO2 promotes iron hydroxide formation under slightly reducing environmental conditions resulting in an increased pollutant retention capacity. 相似文献
30.
辽宁省的鞍山、本溪两市为我国重要的钢铁基地,各矿山长期生产遗留的铁尾矿问题越来越引起人们的重视,如污染环境、诱发地质灾害等,如何解决已成为地质、环保、水工界的关注。 相似文献