The Upper Devonian to Carboniferous Mt Eclipse Sandstone is a basin-wide host to uranium mineralisation in the Ngalia Basin, NT. The fluvial depositional architecture and diagenesis of the Mt Eclipse Sandstone at the Bigrlyi uranium deposit on the northern margin of the basin are deduced from hyperspectral mineral results captured from 200 drill holes, combined with core and outcrop observations across a ~10 km strike length. The succession hosting the uranium mineralisation is interpreted to be deposited in the lower parts of a mature alluvial fan system with low slope angle and dominated by immature, kaolinised, medium-grained subarkosic sandstones and patchy calcite cement. This study reveals the fluvial channel sequence is estimated to be 3 km wide, 100–200 m thick and sourced from the north. This multidisciplinary study also uncovers the complex interaction and codependencies between fluvial/groundwater activity, evaporation, oxidation, fluctuating pH and detrital mineralogy controlling early diagenetic processes in the alluvial fan sediments. Carbon isotope data identify calcite cements as groundwater calcrete, while strontium isotope data suggest limited prolonged water–rock interaction prior and during calcite cementation. The petrographic data reveal the importance of early calcite cement occluding all pore space and preserving detrital minerals from later diagenetic processes. The hyperspectral results highlight the intermittent distribution of the calcite cement and the commonly repetitive mineralogical zonation throughout the 200 drill holes, including the inverse spatial correlation between kaolinite ± goethite ± gypsum vs white mica ± hematite dominated zones. X-ray diffraction and the hyperspectral data reveal the scarcity of early diagenetic clay minerals such as montmorillonite. This paper is the first to report on a systematic mineralogical and sedimentological study for the Mt Eclipse Sandstone. By focusing on the diagenesis and fluvial architecture of this stratigraphic unit, a framework to support exploration for sediment-hosted uranium deposits is established. 相似文献