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91.
92.
Norbert R. Nowaczyk Stefanie Harwart Martin Melles 《Geophysical Journal International》2001,145(1):300-306
93.
94.
Plagioclase dissolution related to biodegradation of oil in Brent Group sandstones (Middle Jurassic) of Gullfaks Field, northern North Sea 总被引:1,自引:0,他引:1
Brent Group sandstones from the north side of the Gullfaks Oilfield contain mostly 5–8% albitic plagioclase, whereas plagioclase is almost absent in the same strata in the southern part of the field. Absence of plagioclase throughout the entire vertical extent of the Brent Group in the southern wells seems to rule out provenance as the principal explanation for differing plagioclase content, which is therefore interpreted as the result of diagenesis. Hypotheses for the nature of the inferred leaching event include epigenetic meteoric diagenesis and mesogenetic release of acid components from clay minerals or kerogen, but these explanations are unable to account for the observed spatial distribution of the plagioclase-bearing and plagioclase-free sandstone intervals. However, overall correspondence between the area lacking plagioclase and oil compositions having both anomalously high CO2 and organic geochemical indications of advanced biodegradation suggest a link between plagioclase dissolution and biodegradation of the present oil column. It is, therefore, proposed that acid components from biodegradation selectively reacted with albitic plagioclase to form kaolin, releasing sodium bicarbonate into the residual water. The plagioclase-free sandstones contain more kaolin than the plagioclase-bearing sandstones, as would be expected due to aluminium conservation. However, the wide and overlapping ranges of kaolin content in both groups suggest that most of the kaolin originated from processes other than biodegradation-driven plagioclase alteration, potentially including both epigenetic and mesogenetic dissolution, as well as deposition of detrital kaolin and kaolin precursors. 相似文献
95.
Cryptic sequence boundaries in braided fluvial successions 总被引:2,自引:0,他引:2
In braided fluvial deposits, consisting of monotonous successions of sandstone or conglomerate, it may be difficult to distinguish regionally significant bounding surfaces (sequence boundaries) from autogenic channel-scour surfaces. Major surfaces may be characterized by erosional relief and draped by lag deposits, but not all sequence boundaries show these characteristics. Other clues to the presence of a major surface are sharp changes in detrital composition, shifts in regional palaeocurrent trends and evidence of early diagenesis of the sandstones immediately below the sequence boundary. Examples of these attributes of cryptic sequence boundaries are illustrated from three Mesozoic units in the Colorado Plateau area of the United States. In the Chinle Formation (Triassic), near Moab, Utah, angular intraformational unconformities overlie sandstones showing evidence of early diagenesis. In the Castlegate Sandstone (Upper Cretaceous) of east-central Utah, a cryptic sequence boundary can be discriminated from other erosion surfaces by the evidence of detrital petrography and early diagenesis. Palaeocurrent data indicate changes in regional palaeoslope at two sequence boundaries within this unit. Evidence of early diagenesis is also present at a sequence boundary in the Kayenta Formation (Jurassic) of westernmost Colorado. 相似文献
96.
P. N. Shukla N. Bhandari Anirban Das A. D. Shukla J. S. Ray 《Journal of Earth System Science》2001,110(2):103-110
We report here an unusually high concentration of iridium in some alkali basalts and alkaline rocks of Deccan region having
an age of about 65Ma, similar to the age of the Cretaceous-Tertiary boundary. The alkali basalts of Anjar, in the western
periphery of Deccan province, have iridium concentration as high as 178pg/g whereas the alkaline rocks and basalts associated
with the Amba Dongar carbonatite complex have concentrations ranging between 8 and 80 pg/g. Some of these values are more
than an order of magnitude higher than the concentration in the tholeiitic basalts of Deccan, indicating the significance
of alkaline magmatism in the iridium inventory at the Cretaceous-Tertiary boundary. Despite higher concentration, their contribution
to the global inventory of iridium in the Cretaceous-Tertiary boundary clays remains small. The concentration of iridium in
fluorites from Amba Dongar was found to be <30 pg/g indicating that iridium is not incorporated during their formation in
hydrothermal activity. 相似文献
97.
98.
99.
鄂尔多斯盆地下奥陶统白云岩成因类型及其地球化学特征 总被引:5,自引:0,他引:5
鄂尔多斯盆地天然气藏的主要储集层段,下奥陶统白云岩,按成因可分为准同生、成岩和深埋藏三种类型,它们在岩石结构、X射线衍射、阴极发光、稳定同位素、微量元素特征以及白云石化机理上均有较大差别。 相似文献
100.
Hans G. Machel 《Hydrogeology Journal》1999,7(1):94-107
This article provides a critical synopsis of the effects of groundwater flow on mineral diagenesis. Emphasis is placed on
those aspects and processes that change porosity and permeability in carbonate aquifers, because they are of particular importance
to human societies as sources of supplies of water for human consumption (drinking, irrigation) and of crude oil and natural
gas.
Diagenetic settings in carbonates as well as clastics are generally ill defined. This paper proposes a new comprehensive classification
of diagenetic settings into near-surface, shallow-, intermediate-, and deep-burial diagenetic settings; hydrocarbon-contaminated
plumes; and fractures. These settings are defined on the basis of mineralogy, petroleum, hydrogeochemistry, and hydrogeology.
This classification is applicable to all sedimentary basins.
Diagenesis is governed by various intrinsic and extrinsic factors that include thermodynamic and kinetic constraints, as well
as microstructural factors that may override the others. These factors govern diagenetic processes, such as dissolution, compaction,
recrystallization, replacement, and sulfate–hydrocarbon redox-reactions. Processes such as cementation, dissolution, and dolomitization
require significant flow of groundwater driven by an externally imposed hydraulic gradient. Other processes, such as stylolitization
and thermochemical sulfate reduction, commonly take place without significant groundwater flow in hydrologically nearly or
completely stagnant systems that are geochemically "closed."
Two major effects of groundwater flow on mineral diagenesis are enhancement and reduction of porosity and permeability, although
groundwater flow can also leave these rock properties essentially unchanged. In extreme cases, an aquifer or hydrocarbon reservoir
rock can have highly enhanced porosity and permeability due to extensive mineral dissolution, or it can be plugged up due
to extensive mineral precipitation.
Received, April 1998 · Revised, July 1998 · Accepted, September 1998 相似文献