碳酸盐岩成岩作用与层序地层学关系研究--以鄂尔多斯盆地寒武系为例

本文从准同生成岩作用、成岩作用类型及其强度、成岩环境演化等方面探讨了成岩作用与海平面升降、层序地层学的关系。研究指出,准同生期成岩作用反映海平面升降、层序界面的形成最敏感;成岩作用的类型及其成岩强度反映了海平面升降幅度、层序边界的类型：体系域的演化控制了成岩环境的演化,不同的体系域其成岩作用类型及其组合不同。成岩作用研究在白云岩地层中对层序边界及其类型的识别、体系域的划分具有重要的意义。     

Research advances,geological implication and application in Ordos Basin of the “pore-size controlled precipitation” in diagenesis of carbonate rock reservoir

Based on the discovery of pore-size controlled mineral precipitation and cementation heterogeneity in carbonate rock reservoirs,the state of art and the geological implications are summarized,referring to the fluid-rock interaction and chemical hydrodynamics in porous media. (1)The pore-size controlled precipitation phenomenon is common in geological environments,as shown by the heterogeneous cementation and eventual features that the large pores are filled while small pores can be preserved. Related studies are mainly divided into three aspects,including pore structure observations at different scales,numerical simulation of fluid-rock interaction and mineral precipitation experiment. (2)The kinetic models related to surface chemistry can be used to explain the heterogeneous precipitation affected by pore-size distribution. The larger interfacial tension and mineral crystal curvature in the micropores result in the much higher effective solubility.Thus the fluids in micropores can maintain a higher supersaturation with no minerals precipitation. (3)The pore-size controlled precipitation leads to the selective preservation of micropores. It means that the much larger pores tend to be cement-filled while the smaller pores are preserved in the case of coexistence of pores at different scales. The impacts of cementation types on the overall permeability of rock are different. The pore-size controlled precipitation phenomenon is also worthy of attention in the research of geothermal development and geologic sequestration of carbon dioxide. In the last part, based on the heterogeneous cementation and porosity distribution of the Majiagou Formation in the Ordos Basin,we study the impacts of diagenetic fluids properties,origin and cementation patterns on the evolution of pore structure and high-quality reservoir distribution.The discovery and emphasis of pore-size controlled precipitation is of great theoretical significance to our understanding of the complex fluid-rock interaction process,which provides a new perspective for reservoir diagenesis and pore preservation.     

Metals and models: Diagenic modelling in freshwater lacustrine sediments

This review aims to distill and synthesize the existing information on the use of models to describe and predict the distribution and movement of metals in lacustrine sediments. As such it examines the causes of metal diagenesis, the origin and form of the equations that govern these phenomena, and the predictability or measurability of the parameters that appear in the models. The paper concludes by highlighting some seminal results from modelling studies, including the determination of the factors controlling the formation of surficial Mn-Fe-enriched zone or layers, the substantial contribution possible from metal reduction to organic matter regeneration, the calculation of mixing-corrected metal input histories to lakes, and the prediction of growth rates and morphologies for both deep-sea and lacustrine ferromanganese nodules.     

罗非鱼放养量对盐碱水微型生态系统浮游生物群落的影响

报道了放养不同密度的尼罗罗非鱼 (orecohromis niloticus)对微型生态系统浮游生物影响的研究结果。罗非鱼的放养量为 5个水平 (0～ 8.12 kg· m-3 )。结果表明 ,随着罗非鱼放养量的增大 ,蓝藻、金藻、轮虫、枝角类、桡足类的量、p H、和 TN:TP比值下降 ;相反 ,绿藻、硅藻、原生动物、浮游植物叶绿素 a含量、浊度、总碱度、电导率、TN和 TP均增加 ;而在生物量上小型硅藻和绿藻占优势使浮游植物小型化。     

A rock magnetic record from Lama Lake, Taymyr Peninsula, northern Central Siberia

An 11 m long sediment core ftorn Lama Lake, Northern Siberia, has been subjected to intense sedimentological, geochemical and rock magnetic analyses. According to a palynologic investigation the recovered sediments cover the whole Holocene and the late Pleistocene reaching back to about 17 ka. IRM acquisition experiments, hysteresis loop and back field as well as thermomagnetic measurements revealed magnetite in the pseudo-single domain range as the only remanence carrier. Sharp rock magnetic boundaries occur at 20 and 745 cm sub-bottom depth that are clearly linked to shifts in the median grain size of the magnetite. These boundaries are close to the present boundaries that bracket an anoxic zone between the subrecent and a late Pleistocene oxic section of the sediments. Within the anoxic section, magnetites are characterized by significantly larger median grain sizes but within a very narrow grain size range. The shift from fine grained magnetite within the oxic sediments to coarse grained magnetite is interpreted as the result of dissolution of the finest magnetite grains within the anoxic sediments. A significant shift of the Ti/Fe-ratio of the bulk sediment at a sub-bottom depth of 735 cm does not correspond to thermomagnetic properties, i.e. Curie-temperatures do not follow the variable Ti-content of the sediment.     

塔里木盆地轮南地区下奥陶统碳酸盐岩储层的控制因素分析

轮南地区下奥陶统潜山是一个具有良好勘探前景的油气富集区 ,但该区碳酸盐岩储层的不均一性及其预测的难度制约了该区勘探的进展 ,这也是碳酸盐岩地区油气勘探的难题之一。从影响碳酸盐岩储层发育的基本地质条件入手 ,对该区的构造特征、沉积环境及成岩作用分别进行了探讨 ,同时结合近年来的钻探成果进行了分析。结果表明 ,该区储层的储集性主要与次生孔隙有关 ,即主要受构造作用和成岩作用控制 ,而与沉积环境没有直接的关系 ,这一分析为该区碳酸盐岩储层的预测和评价提供了依据     

Alkaline Intrusives at the East Foot of the Taihang-Da Hinggan Mountains: Chronology, Sr, Nd and Pb Isotopic Characteristics and Their Implications

Based on the Rb-Sr isochron dating results, this paper suggests that the alkaline intrusive belt at the east foot of the Taihang-Da Hinggan Mountains were formed between 135 and 122 Ma. And the alkaline intrusives in the north and south sections of this belt have entirely different Sr, Nd and Pb isotopic characteristics, i.e., all the rocks in the south section have positive εSr(t) and negative εNd(t) values and all those in the north have the opposite values. On the εSr(t) versus εNd(t) correlation diagram, the samples from the south are concentrated along the enriched mantle evolution trend lines and nearby, while those from the north fall along the depleted mantle trend lines and nearby. On the Pb isotope composition diagram, most of the samples from the south section fall on the mantle Pb evolution line and nearby, while those from the north lie between the Pb evolution lines of the mantle and the erogenic belt. The above-stated isotopic characteristics not only indicate that the source rocks of     

Interstitial water – sediment geochemistry of N, P and Fe and its response to overlying waters of tropical estuaries: a case from the southwest coast of India

 The concentrations of N, P and Fe in surface sediments and interstitial and overlying (bottom and surface) waters of the Ashtamudi estuary located in the southwest coast of India are reported along with the various chemical species of N (NO₂–N, NO₃–N, NH₃–N and total N) and P (organic P, inorganic P and total P) in interstitial and overlying waters and discussed in terms of the physico-chemical environment of the system. The interstitial water exhibits higher salinity values compared to bottom and surface waters, indicating the coupled effects of salt-wedge phenomena and gravitational convection of more saline-denser marine water downward through surface sediments. N, P and Fe as well as their chemical forms are enriched in the interstitial water compared to bottom and surface waters. However, the dissolved oxygen (DO) shows an opposite trend. The marked enrichment of NH₃–N in the interstitial water and its marginal presence in bottom and surface waters, together with the substantial decrease in the DO concentrations of bottom water and consequent increase in the concentrations of NO₂–N and NO₃–N in interstitial and bottom waters, points to the nitrification process operating in the sediment-water interface of the Ashtamudi estuary. The enrichment of total N, P and Fe in the interstitial water compared to the overlying counterparts and the positive correlation of sediment N, P and Fe with mud contents as well as organic carbon indicate that these elements are liberated during the early diagenetic decomposition of organic matter trapped in estuarine muds. Received: 5 Oktober 1998 · Accepted: 9 February 1999     

A comparative study of iron and manganese diagenesis in continental slope and deep sea basin sediments off Uruguay (SW Atlantic)

Pore water and solid phase from surface sediments of the continental slope off Uruguay and from the Argentine Basin (southwestern Atlantic) were investigated geochemically to ascribe characteristic early diagenetic reactions of iron and manganese. Solid-phase iron speciation was determined by extractions as well as by Mössbauer spectroscopy. Both methods showed good agreement ( <6% deviation) for total-Fe speciation. The proportion of easy reducible iron oxyhydroxide relative to total-Fe oxides decreased from the continental slope to the deep sea which is attributed to an increase in crystallinity during transport as well as to a general decrease of iron mobilization. The product of iron reoxidation is Fe oxyhydroxide which made up less than 5% of total Fe. In addition to this fraction, a proportion of smectite bound iron was found to be redox reactive. This fraction made up to 10% of total Fe in sediments of the Argentine Basin and was quantitatively extracted by 1?N HCl. The redox reactive Fe(+II) fraction of smectite was almost completely reoxidized within 24?h under air atmosphere and may therefore considerably contribute to iron redox cycling if bioturbation occurs. In the case of the slope sediments we found concurrent iron and manganese release to pore water. It is not clear whether this is caused by dissimilatory iron and manganese reduction at the same depth or dissimilatory iron reduction alone inducing Mn(+IV) reduction by (abiotic) reaction with released Fe²⁺. The Argentine Basin sediment showed a significant manganese solid-phase enrichment above the denitrification depth despite the absence of a distinct pore-water gradient of Mn. This implies a recent termination of manganese mobilization and thus a non-steady-state situation with respect to sedimentation or to organic carbon burial rate.     

Diagenetic Dissolution of Biogenic Magnetite in Surface Sediments of the Benguela Upwelling System

Intense primary biologic productivity in the surface waters of the Benguela upwelling system provides a high supply of organic matter to the sea floor at the continental slope off Namibia and sustains extreme concentrations of magnetite producing bacteria in the top sediment layers. Biogenic magnetite is thus by far the dominant carrier of the magnetic signal in these deposits also because of a very minor input of terrigenous ferrimagnetic minerals. Reducing conditions in the sediment column cause a selective dissolution of the bacterial magnetite fraction just a few centimeters below the main mineralization horizon. This diagenetic process is documented in detail by high-resolution rock magnetic analyses and transmission electron microscopy. Concentration dependent and grain-size sensitive magnetic parameters, such as susceptibility, laboratory imparted remanences, and hysteresis data, reveal a significant drop in ferrimagnetic mineral content within the upper 10 cm of the sediments accompanied by a gradual downward coarsening of the ferrimagnetic mineral assemblage from primarily magnetic single-domain particles in the top centimeters to multi-domain grains in deeper strata. Electron microscope observations enable both an unequivocal identification of bacterial magnetite on the basis of shape and grain-size and to trace dissolution effects on the biogenic magnetic mineral component to depth. Received: 9 November 1998 / Accepted: 10 October 1999